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18met302 MTD L1 (1.1-1.2) 2-7-2020
18met302 MTD L1 (1.1-1.2) 2-7-2020
9MET304.1 1
Objectives
9MET304.1 3
Introduction
Thus Thermodynamics is
9MET304.1 4
Introduction cont.,
9MET304.1 5
Applications
9MET304.1 6
Applications (contd…)
3) A + B = C +D
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Applications in Metallurgy
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Applications in Metallurgy
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Perfect Gas
• Is a hypothetical gas
9MET304.2 10
Perfect Gas cont.,
• Additionally,
9MET304.2 11
Ideal Gas Equation
• The statement:
PV=nRT
Where P---pressure
V---Volume
n---no. of moles of ideal gas
R--- Universal gas constant
T--- Absolute Temperature of ideal gas.
9MET304.2 12
Derivation of Ideal Gas Equation
V α 1/P
• According to Charles’ Law
VαT
9MET304.2 13
Derivation Of Ideal Gas Equation Cont.,
Or
• Where K is a constant.
9MET304.2 14
Derivation Of Ideal Gas Equation Con.,
• K value can be found as follows
9MET304.2 16
Derivation Of Ideal Gas Equation Cont.,
• Now the ideal gas equation takes the following form for
1-mole of gas
P V
= R
T
9MET304.2 17
Real Gas
• In Real gases
• Volume is ≠0
9MET304.2 18
Real Gas cont.,
• There fore
• Real gases
9MET304.2 19
Numerical Problems
• Problem No.1
9MET304.2 20
Solution to Problem No.1
• V1/T1 = V2/T2
9MET304.2 21
Solution to Problem No.1 cont.,
or
V1T2 = V2T1
V1T2
V2 =
T1
(752 mL)(323 K)
V2 =
(298 K)
= 815 mL
9MET304.2 22
Numerical Problems
Problem No.2
9MET304.2 23
Solution to Problem No.2
• P1v1 = p2v2
• P2 = ? V2 = 144 ml
9MET304.2 24
Solution to Problem No.2
P1 V1
V2
There fore p2 =
0.947 150
144
There fore p2 =
= 0.986 atm
9MET304.2 25
Numerical Problems
Problem No.3
9MET304.2 26
Solution to Problem No.3
P1V1 P2 V2
=
T1 T2
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Solution to Problem No.3 cont.,
• Given Data
• V1 = 50.0L V2 = ?
9MET304.2 28
Solution to Problem No.3 cont.,
• Writing for V2
P1V1T2
V2 =
T1P2
9MET304.2 29
Solution to Problem No.3 cont.,
1.08×50.0×283
V2 =
293×0.855
= 60 L
9MET304.2 30
Summary
• We have discussed about
• What is Thermodynamics ?
• Applications of Thermodynamics.
1) Thermodynamics is used to
a) Construct phase diagrams
9MET304.1 32
Quiz
d) None
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Quiz
a) Pressure in atm.
b) Volume in lit.
c) Temperature in kelvin.
d) No. of moles.
9MET304.2 34
Quiz
a) 1.98.
b) 8.314.
c) 0.0821.
d) None.
9MET304.2 35
Quiz
a) CO2.
b) CO.
c) SO2.
9MET304.2 36
Frequently Asked Questions
2) Write the Ideal gas equation and label the terms 1 Mark
4) Derive the Ideal gas equation for ‘n’ moles of ideal gas
5 Marks
9MET304.2 37