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CHM131 - Chapter 3 - Chemical Bonds
CHM131 - Chapter 3 - Chemical Bonds
CHM131 - Chapter 3 - Chemical Bonds
CHM 131
OBJECTIVES
• Define Chemical Bond, Valence Electrons, Noble Gases and
Octet Stability
• Draw Lewis Electron Dot Symbols, Structure and Formal
Charge
• Explain Octet Rule and It Exceptions
• Explain Ionic Bond, Covalent Bond and Dative Covalent Bond
• Sketch and determine molecular Shape
• Explain Dipole Moment and Bond Polarity
• Identify intermolecular forces between molecules
• Identify the effect of intermolecular forces on melting and
boiling point of substance.
LEWIS
ELECTRON DOT
SYMBOL (LEWIS
STRUCTURE):
Important In Drawing Correct
Molecular Structure
LEWIS ELECTRON DOT
SYMBOL (Lewis Structure)
• Lewis electron dot symbol /Lewis structure
• Consist of the chemical symbol of an element
• Surrounded by dots representing the
valence electron in an atom of the element.
LEWIS ELECTRON DOT
SYMBOL (Lewis Structure)
• Example of Lewis Structure for ions:
CHEMICAL
BONDS
CHEMICAL BONDS
• Chemical bond is a strong attractive force
that exists between atoms in a substance.
• Four types of chemical bonds:
IONIC BOND
The electrostatic force that holds ions together
in an ionic compound.
FORMATION OF IONIC
COMPOUND
Show the formation of NaCl of using Lewis dot
structure.
FORMATION OF
IONIC COMPOUND
Show the formation of MgCl2 of using Lewis
dot structure.
COVALENT BOND
Covalent compound: Compounds that
contains only covalent bonds.
A covalent bond is a chemical bond in which
two or more electrons are shared by two
atoms.
FORMATION OF COVALENT
COMPOUND
Show the formation of F2 compound of using
Lewis dot structure.
FORMATION OF COVALENT
COMPOUND
Show the formation of F2 compound of using
Lewis dot structure.
FORMATION OF COVALENT
COMPOUND
Show the formation of HBr, H2S and N2
compound of using Lewis dot structure.
TYPE OF
COVALENT BOND
DECREASING STRENGTH
Bonding pair
PROPERTIES OF IONIC AND
COVALENT COMPOUNDS
DATIVE COVALENT
BOND
A co-ordinate bond(also called a dative covalent
bond) is a covalent bond (a shared pair of
electrons) in which both electrons come from the
same atom.
DRAWING
LEWIS
STRUCTURE
DRAWING LEWIS DOT
STRUCTURE
• The Lewis structure is a simple two-dimensional
representation of the positions of electron pairs
around a central atom of a molecule.
• Valence electrons are distributed as:
• bond pairs : (bonding electrons)
• lone pairs : (non bonding electrons)
4 bonds
C 4 0 C C C C
N 3 1 N N N 3 bonds
O O 2 bonds
O/S 2 2
F/
1 3 Cl 1 bond
Cl/Br
H 1 0 H 1 bond
FORMAL
CHARGE
FORMAL CHARGE
• Formal charge is the charge assigned to individual
atoms in a Lewis structure.
• To determine the best Lewis structure.
• Formal charge is calculated as follows:
FORMAL CHARGE
H1 N H2 H3
Valence
Electron 1 5 1 1
- Electron
owned 1 5 1 1
Formal
Charge 0 0 0 0
CALCULATING FORMAL
CHARGE 1
H1 H2 C O
Valence
Electron 1 1 4 6
- Electron
1 1 4 6
owned
Formal
Charge 0 0 0 0
CALCULATING FORMAL
CHARGE 1
2 4
F1 F2 F3 F4 B
Valence
Electron 7 7 7 7 3
- Electron
7 7 7 7 4
owned
Formal
Charge 0 0 0 0 1
FORMAL CHARGE AND
LEWIS STRUCTURE
•The best Lewis structure…
1. Smaller formal charges (either positive or
negative)
2. A more negative formal charge is assigned to
the most EN atom.
3. Avoid like charges (+ + or - - ) on adjacent
atoms
RESONANCE AND
FORMAL CHARGE
EXAMPLE:
NCO- has 3 possible resonance forms. Choose
the most possible structure.
N C O N C O N C O
A B C
• First: Determine Formal Charges
-2 0 +1 -1 0 0 0 0 -1
N C O N C O N C O
A B C
H O H
o c o O
H C N O N O
MOLECULAR
SHAPE
VSEPR MODEL
• Valence Shell Electron Pair Repulsion
theory.
• Most important factor in determining
geometry is relative repulsion between
electron pairs.
Surrounding atom
ABx
Central atom
Cl Be Cl
Molecular Geometry :
Linear
• AB3 : Boron Trifluoride (BF3)
• Lewis Structure:
Molecular Geometry :
Trigonal planar
• AB4 : Methane(CH4)
• Lewis Structure:
Molecular Geometry :
Tetrahedral
• AB5 : Phosphorous Pentachloride(PCl5)
• Lewis Structure:
Molecular Geometry :
Trigonal bipyramidal
• AB6 : Sulfur Hexafluoride (SF6)
• Lewis Structure:
Molecular Geometry :
Octahedral
MOLECULES WITH LONE PAIR
(CENTRAL ATOM)
• More complicated
• Three types of repulsion:
lone- pair : lone-pair > lone-pair : bonding pair
> bonding pair > bonding pair
Surrounding atom
ABxEy
Central atom Lone pair on A
bent
Molecular Geometry :
Bent
AB3E: Ammonia, NH3
Lewis structure:
trigonal
pyramidal
Molecular Geometry :
Trigonal pyramidal
AB2E2: Water, H2O
Lewis structure:
bent
distorted
tetrahedron
Molecular Geometry :
distorted
tetrahedron/seesaw
GEOMETRY OF MOLECULES
WITH MORE THAN ONE
CENTRAL ATOM
H F
POLARITY OF THE
MOLECULE
EXAMPLE : CO2
NH3 is polar
EXERCISE
Determine which molecule is polar and show the
direction of bond dipoles if any.
1. CF4
2. BF3
3. CH3Cl
4. H2S
5. COS
6. CCl2H2
CF4 Non-polar CH3Cl polar
Consider BF3:
1s 2s 2p 3s 3p 3d 4s 4p 4d 4f
INTERMOLECULAR
FORCES
TYPE OF FORCES
INTERMOLECULAR INTRAMOLECULAR
INTRAmolecular
INTERmolecular
Intermolecular vs Intramolecular
• 41 kJ to vaporize 1 mole of water (inter)
• 930 kJ to break all O-H bonds in 1 mole of water
(intra)
INTERMOLECULAR
FORCES
London dispersion
forces
DIPOLE-DIPOLE FORCES
• Dipole-dipole forces is attractive forces between
the positive end of one polar molecule and the
negative end of another polar molecule.
• Between polar molecules
• Examples: Interaction between HCl, HBr, NF3,
CH3Cl
• The strengths of intermolecular attractions
increase with increasing polarity.
HYDROGEN BOND
The hydrogen bond is a special interaction between
they hydrogen atom in a polar N-H, O-H, or F-H
bond and an electronegative O, N, or F atom.
A H… B or A H… A
A & B are N, O, or F
• The strength of intermolecular forces increase
with an increase in molar mass or molecule size.
• Larger atoms have larger electron clouds which
are easier to polarize.
• Molecular size and mass generally parallel each
other, so the dispersion forces tend to increase
in strength with increasing molecular weight as
well.
• Hydrogen bond is stronger than
van der Waal forces
• B.p of NH3, H2O and HF are high
compared to those of the hydrides
of group 15, 16 and 17.
• H2O has b.p higher than HF
although F is more electronegative
than O.
• Each H2O atom is able to form 2
hydrogen bond
• Each HF atom only can form
1hydrogen bond