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    Addition - Elimination

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    pacho rosero
    1. The document discusses various organic chemistry reactions including nucleophilic addition-elimination, acyl substitution, biodiesel synthesis, Gabriel synthesis, reduction reactions using agents like NaBH4 and LiAlH4, reactions using organometallic reagents, hydrolysis, and Fischer esterification. 2. Key reaction mechanisms are described including SN1 and SN2 nucleophilic substitution, acid-base catalysis, and the role of kinetics and activation energy in controlling reaction rates and selectivity. 3. Examples and exercises are provided to illustrate organic chemistry concepts and reaction mechanisms.

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    Addition - Elimination

    Uploaded by

    pacho rosero
    13 views71 pages
    1. The document discusses various organic chemistry reactions including nucleophilic addition-elimination, acyl substitution, biodiesel synthesis, Gabriel synthesis, reduction reactions using agents like NaBH4 and LiAlH4, reactions using organometallic reagents, hydrolysis, and Fischer esterification. 2. Key reaction mechanisms are described including SN1 and SN2 nucleophilic substitution, acid-base catalysis, and the role of kinetics and activation energy in controlling reaction rates and selectivity. 3. Examples and exercises are provided to illustrate organic chemistry concepts and reaction mechanisms.

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    addition - elimination

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    1. The document discusses various organic chemistry reactions including nucleophilic addition-elimination, acyl substitution, biodiesel synthesis, Gabriel synthesis, reduction reactions using agents like NaBH4 and LiAlH4, reactions using organometallic reagents, hydrolysis, and Fischer esterification. 2. Key reaction mechanisms are described including SN1 and SN2 nucleophilic substitution, acid-base catalysis, and the role of kinetics and activation energy in controlling reaction rates and selectivity. 3. Examples and exercises are provided to illustrate organic chemistry concepts and reaction mechanisms.

    Copyright:

    © All Rights Reserved
    Download as PPTX, PDF, TXT or read online from Scribd
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    Download as pptx, pdf, or txt
    13 views71 pages

    Addition - Elimination

    Uploaded by

    pacho rosero
    1. The document discusses various organic chemistry reactions including nucleophilic addition-elimination, acyl substitution, biodiesel synthesis, Gabriel synthesis, reduction reactions using agents like NaBH4 and LiAlH4, reactions using organometallic reagents, hydrolysis, and Fischer esterification. 2. Key reaction mechanisms are described including SN1 and SN2 nucleophilic substitution, acid-base catalysis, and the role of kinetics and activation energy in controlling reaction rates and selectivity. 3. Examples and exercises are provided to illustrate organic chemistry concepts and reaction mechanisms.

    Copyright:

    © All Rights Reserved
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    of 71

    Nucleophilic addition - Elimination

    1
    Acids and derivatives

    2
    General Reaction

    3
    General reaction

    4
    General Mechanism

    5
    Acyl Substitution

    6
    The “Ladder”

    7
    Exercise

    8
    Exercises

    9
    Exercise

    10
    Biodiesel

    11
    General Reaction

    12
    Mechanism

    13
    Energy Diagram

    14
    Mechanism

    15
    Saponification

    16
    Main Reasons

    17
    Exercise

    18
    Energy Diagram

    19
    Amide hydrolysis

    20
    Mechanism

    21
    Energy Diagram

    22
    Exercise

    23
    Gabriel Synthesis

    24
    Mechanism

    25
    Polyalkylation

    26
    Exercise

    27
    Exercise

    28
    Haloform

    29
    Mechanism

    30
    Exercise

    31
    Exercise

    32
    Reducing Agents

    33
    Mechanism

    34
    NaBH4 vs LiAlH4

    35
    Selectivity

    36
    Selectivity

    37
    No selectivity

    38
    Carboxylic acid reduction

    39
    Amide Reduction

    40
    Mechanism

    41
    Exercise

    42
    Exercise

    43
    Specialized Reducing Agents

    44
    Specialized Reducing Agents

    45
    Specialized Reducing Agents

    46
    Kinetics

    47
    Kinetics

    48
    Mechanism

    49
    Exercise

    50
    Exercise

    51
    Organometallic Reagents

    52
    Organometallic Reagents

    53
    Organometallic Reagents

    54
    Exercise

    55
    Exercise

    56
    Dialkylcuprates

    57
    Dialkylcuprates

    58
    Weak Nucleophiles

    59
    Mechanism: Hydrolysis

    60
    Mechanism: Alcoholysis

    61
    Exercise

    62
    Exercise

    63
    Rates of Hydrolysis: Derivatives

    64
    Rates of Hydrolysis: Derivatives

    65
    Activation Energy

    66
    Synthesis of Acyl Halides

    67
    Mechanism

    68
    Fischer Esterification

    69
    Mechanism

    70
    Mechanism

    71

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