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18 Chapter 18 Solubility
18 Chapter 18 Solubility
Solubility and
Complex-Ion Equilibria 18
PHILIP DUTTON
UNIVERSITY OF WINDSOR
DEPARTMENT OF CHEMISTRY AND BIOCHEMISTRY
Molar solubility.
The molarity in a saturated
aqueous solution.
Related to Ksp
EXAMPLE 18-2
PbI+(aq) + I−(aq)
−I− −I−
PbI42−(aq) PbI3 −(aq) PbI2 (s) Pb2+(aq) + 2 I−(aq)
+I− +I−
PbI2 (aq)
FIGURE 18-4
Fractional precipitation-Example 18-7 illustrated
Mg(OH)2
Milk of Magnesia.
FIGURE 18-5
Complex-ion formation: dissolution of AgCl(s) in NH3
[[Ag(NH3)2]+]
Kf = = 1.6×10 7
[Ag+][NH3]2
Ksp 3×10−28
Kspa = = = 3×10−7
Ka1×Kw 1.0×10−7 ×1.0×10−14