Atomic Structure Theory 2017

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History and

Models of the
Atom
Democritus 460 BC
► Greek Philosopher
► Suggested world was made of
two things – empty space and
“atomos”
 Atomos – Greek word for
uncuttable
► 2 Main ideas
 Atoms are the smallest
possible particle of matter.
 There are different types of
atoms for each material.
2
John Dalton’s Atomic Theory 1804

1. All matter is made of


atoms.
2. Atoms of one element are
all the same.
3. Atoms cannot be broken
down into smaller parts
4. Compounds form by
combining atoms
Dalton’s Early Atomic Model
► “Billiard Ball” model
► he envisioned atoms as solid, hard spheres,
like billiard(pool) balls, so he used
wooden balls to model them
J.J. Thomson

1897
Discovered the electron.

He was the first scientist to show the atom was


made of even smaller things.
JJ Thomson
►Used the Cathode ray tube to discover
electrons
Thomson’s Experiment
Voltage source
- +

Vacuum tube

Metal
Disks
Thomson’s Experiment
Voltage source
- +
Thomson’s Experiment
Voltage source
- +
Thomson’s Experiment
Voltage source
- +

 Passing an electric current makes a


beam appear to move from the
negative to the positive end
Thomson’s Experiment
Voltage source
- +

 Passing an electric current makes a


beam appear to move from the
negative to the positive end
Thomson’s Experiment
Voltage source
- +

 Passing an electric current makes a


beam appear to move from the
negative to the positive end
Thomson’s Experiment
Voltage source
- +

 Passing an electric current makes a


beam appear to move from the
negative to the positive end
Thomson’s Experiment
Voltage source

►By adding an electric field


Thomson’s Experiment
Voltage source

-
 By adding an electric field
Thomson’s Experiment
Voltage source

-
 By adding an electric field
Thomson’s Experiment
Voltage source

-
 By adding an electric field
Thomson’s Experiment
Voltage source

-
 By adding an electric field
Thomson’s Experiment
Voltage source

-
 By adding an electric field
Thomson’s Experiment
Voltage source
+

-
-
 Adding an electric field cause the beam to
move toward the positive plate.
 Thomson concluded the beam was made of
negative moving pieces.
Thomson’s “Plum Pudding” Atom Model
Nuclear Model
Ernest Rutherford discovered a huge flaw
in the previous concept of the atom during
his now famous gold foil experiment
Rutherford

► Discovered the
Nucleus and the
Positive Protons
► Surmised atoms are
made of mostly
empty space
► Didn’t know about
the Neutrons
► Famous Gold Foil
Experiment
Ernest Rutherford - 1913

• discovered the
nucleus of a
gold atom with
his “gold foil”
experiment
Using J.J Thomson’s Plum Pudding
atomic model, Rutherford predicted the
alpha particles would pass straight
though the gold foil. That’s not what
happened.
Gold Foil Experiment Results
most alpha particles go straight through
the gold foil
A few alpha particles are sharply deflected
Rutherford’s Conclusion
►The atom is mostly
empty space.
►There is a small,
dense center with a
positive charge.
►Rutherford
discovered the
nucleus in atoms
Rutherford’s Contribution to the
Atomic Theory
►The atom is
mostly empty
space.
►The nucleus is
a small, dense
core with a
positive charge.
Gold Foil video
Rutherford’s Atomic Model
Structure of the Atom
► Atom – smallest particle of an element that can
exist alone
 Two regions of an atom
►Nucleus
 Center of atom
 Protons and neutrons
►Electron “cloud”
 Area surrounding nucleus
containing electrons
Structure of the Atom
► Proton
– Positive charge (+), 1 atomic
mass unit (amu); found in the nucleus
 amu -Approximate mass of a proton or a
neutron
► Neutron – Neutral charge (0), 1 amu;
found in the nucleus
► Electron – Negative charge (-), mass is
VERY small
Counting Atoms
► Atomic Number
 Number of protons in nucleus
 The number of protons determines identity
of the element!!

► Mass Number (Atomic Mass)


 Number of protons + neutrons
Counting Atoms
► Isotopes
 Atoms of the same element with varying
number of neutrons
 Different isotopes have different mass numbers
because the number of neutrons is different
Composition of the atom video

Start at 3:25
Counting Atoms
 Nuclear Symbol Notation
Atoms
► Protonshave a positive (+) charge and
electrons have a negative (-) charge

► In
a neutral atom, the number of protons
equals the number of electrons, so the
overall charge is zero (0)

 Example/ Helium, with an atomic number of 2,


has 2 protons and 2 electrons when stable
Ions
► In a neutral atom
 Atomic number = # of protons = #of electrons

► Sometimes atoms will gain or lose electrons


and form IONS
► Because an electron has a negative charge:
 When an atom GAINS electrons it becomes
NEGATIVE
 When an atom LOSES electrons it becomes
POSITIVE
Ions

Cation = a positive ion

Anion = a negative ion


Let’s Practice
► Aluminum (Al) (no periodic table)
 Protons = 13
 Electrons =
 Neutrons = 14
 Atomic Number =
 Atomic Mass =
Let’s Practice w/ nuclear symbol
notation
► NuclearSymbol notation
(no periodic table)
 Protons =
108
Ag
 Electrons =
 Neutrons =
47
 Atomic Number =
 Atomic Mass =
Let’s Practice w/ isotopes
► use the periodic table


Protons =
Uranium-235
Electrons =
 Neutrons =
 Atomic Number =
 Atomic Mass =
Let’s Practice with Ions
Use the periodic table

K
 Charge = 39 1+

 Protons =
 Electrons =
 Neutrons =
 Atomic Number =
 Atomic Mass =

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