SAHU JAIN DEGREE

COLLEGE
NAJIBABAD

PRESENTED TO PRESENTED BY
VISHWKARMA SIR NISHA
ANIL SIR
 PRESENTATION TOPIC

NON AROMATIC
HETEROCYCLES
​
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INTRODUCTION
A cyclic ring having at least two different elements as
members of a ring and violating the criteria of Aromaticity are
called non aromatic heterocycles…
A cyclic ring having two or more hetero atom within the ring
are called non aromatic heterocyclic compounds.
The most common hetero atoms found on a cyclic ring are
Oxygen (O),
Nitrogen (N) and Sulphur (S). N;O;S
COMMON EXAMPLE
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TYPES OF STRAIN IN
A RING
CONSEQUENCE OF STRAIN
IN SMALL RING
HETEROCYCLES
1* BASICITY
Aziridine is less basic than 2 degree amines. Less basicity of aziridine is due to bond angle strain and can
be explain by considering the hybridization of lone pair present at nitrogen atom .
The B.A.S in aziridine results increase in s-character of lone pair and hybridization of lone pair lies in
between sp2 and sp3.

% S-character α 1/donar ability α 1/basicity α 1/ring sizeα B.A.S

CONJUGATIV EFFECT
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• Confirmation of double bond character

• B.A.S. in small ring heterocycles • UV spectra of aziridine shows
results in rehybridization of the ring
evidence for transmission of
atom giving additional p-character
conjugation through small ring and
forming ring bond . Thus the ring
substituted aziridine shows λ max at
bonds behaves in some respect like
higher wavelength .
double bond .
CONFERMATION OF 6 MEMBER
HETROCYCLES HAS FOLLOWING POINT…

1,3-DIAXIAL INTERACTION
The steric interaction that accurs between axial substituents with
arbitrary group in a chair confirmation is known as 1,3-diaxial
interaction or syn axial interaction .
 N- CONTAINING 6 MEMBER RINGS ON FLEXIBLE IN NATURE
CAN UNDERGOES TWO TYPE OF CHANGES

1) PYRAMIDAL INVERSION
(UMBRELLA INVERSION)
In this inversion there is only change
in configuration of substituent and lone
pair of nitrogen atom .
In pyramidal inversion
SUBSTITUENTS AND LONE PAIR
present on
N–atom do sigma rotation and up
become down and down become up .
2) RING INVERSION
During the ring inversion
CONFIRMATION of ring is going to
be change known as FLIP FLOP
PROCESS and during the
confirmation change axial become
equatorial and vice- versa.
Whole ring get inverted and inversion
converts the ring into its mirror image .
THANK YOU
Nisha
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MEET OUR TEAM

TAKUMA HAYASHI MIRJAM NILSSON FLORA BERGGREN​ RAJESH SANTOSHI​

President Chief Executive Officer Chief Operations Officer VP Marketing
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MEET OUR EXTENDED TEAM

TAKUMA HAYASHI MIRJAM NILSSON FLORA BERGGREN​ RAJESH SANTOSHI​

President Chief Executive Officer Chief Operations Officer VP Marketing

GRAHAM BARNES ROWAN MURPHY ELIZABETH MOORE ROBIN KLINE

VP Product SEO Strategist Product Designer Content Developer
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PLAN FOR PRODUCT LAUNCH 

PLANNING MARKETING DESIGN STRATEGY LAUNCH

Deploy strategic
Disseminate Foster holistically
Synergize scalable Coordinate e- networks with
standardized superior
e-commerce business applications compelling e-
metrics methodologies
business needs
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TIMELINE

SEP 20XX NOV 20XX JAN 20XX MAR 20XX MAY 20XX

Synergize scalable Disseminate standardized Coordinate e- Foster holistically Deploy strategic

e-commerce business applications superior methodologies networks with
metrics compelling e-
business needs
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Presentation title
HOW WE GET THERE
ROI
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enabled technologies
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deliverables
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SUPPLY CHAINS
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ideas
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schemas
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SUMMARY
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THANK YOU