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Ferrous Metallurgy

Postgraduate
Prof. Dr. Mohamed Mraikab , Dr. Sanaa Abd Almoaamen Diploma

‫الي عالم اخضر مستدام‬

… Vision 2050 …

Green – Lean - Clean


Master's student
‫ الي تصنيع أخضراء مستدام‬... ‫والتحول‬ 1
Eng. Dr. Hesham Saad
Ferrous Metallurgy
Postgraduate
Prof. Dr. Mohamed Mraikab , Dr. Sanaa Abd Almoaamen Diploma

Reactions Kinetics

‫الي عالم اخضر مستدام‬

… Vision 2050 …

Green – Lean - Clean


Master's student
‫ الي تصنيع أخضراء مستدام‬... ‫والتحول‬ 2
Eng. Dr. Hesham Saad
Ferrous Metallurgy
Postgraduate
Prof. Dr. Mohamed Mraikab , Dr. Sanaa Abd Almoaamen Diploma

Concentration
of reactants
State of
reactants and system Temp.
their ability to & Pressure
meet

‫الي عالم اخضر مستدام‬


Chemical Factors
… Vision 2050 …
nature of Affecting Catalyst
reactants RoR*

* RoR : Rate of Reaction


Green – Lean - Clean
Master's student
‫ الي تصنيع أخضراء مستدام‬... ‫والتحول‬ 3
Eng. Dr. Hesham Saad
Ferrous Metallurgy
Postgraduate
Prof. Dr. Mohamed Mraikab , Dr. Sanaa Abd Almoaamen Diploma

Titrimetric

Reactions
Initial rate colorimetr
method
mix. ic
analyzing

‫الي عالم اخضر مستدام‬

… Vision 2050 …

Conducti
metric

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Master's student
‫ الي تصنيع أخضراء مستدام‬... ‫والتحول‬ 4
Eng. Dr. Hesham Saad
Ferrous Metallurgy
Postgraduate
Prof. Dr. Mohamed Mraikab , Dr. Sanaa Abd Almoaamen Diploma

COLLISION
THEORY

Theories of reactions rate


TRANSITION STATE
THEORY

DETAILED DYNAMICAL
THEORY
‫الي عالم اخضر مستدام‬

… Vision 2050 …
THEORIES OF REACTIONS
IN SOLUTION

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Master's student
‫ الي تصنيع أخضراء مستدام‬... ‫والتحول‬ 5
Eng. Dr. Hesham Saad
Ferrous Metallurgy
Postgraduate
Prof. Dr. Mohamed Mraikab , Dr. Sanaa Abd Almoaamen Diploma

For a reaction to take place spontaneously,


the free energy of the products must be lower than
the free energy of the reactants.
i.e. ∆G must be negative.
We know that

∆G = ∆H – T∆S
Where,

∆G = Change in free energy


‫الي عالم اخضر مستدام‬ ∆H = Change in enthalpy
∆S = Change in entropy
… Vision 2050 …

T = temperature
To be ∆G negative, there should be
Green – Lean - Clean
decrease in enthalpy and increase in entropy of the system.
Master's student
‫ الي تصنيع أخضراء مستدام‬... ‫والتحول‬ 6
Eng. Dr. Hesham Saad
Ferrous Metallurgy
Postgraduate
Prof. Dr. Mohamed Mraikab , Dr. Sanaa Abd Almoaamen Diploma

‫الي عالم اخضر مستدام‬

… Vision 2050 …

Green – Lean - Clean


Master's student
‫ الي تصنيع أخضراء مستدام‬... ‫والتحول‬ 7
Eng. Dr. Hesham Saad
Ferrous Metallurgy
Postgraduate
Prof. Dr. Mohamed Mraikab , Dr. Sanaa Abd Almoaamen Diploma

Products

Reactants

‫الي عالم اخضر مستدام‬


The change of concentration in a system can generally be acquired in
… Vision 2050 … two ways:
By monitoring the depletion of reactant over time, or
By monitoring the formation of product over time
Green – Lean - Clean
Master's student
‫ الي تصنيع أخضراء مستدام‬... ‫والتحول‬ 8
Eng. Dr. Hesham Saad
Ferrous Metallurgy
Postgraduate
Prof. Dr. Mohamed Mraikab , Dr. Sanaa Abd Almoaamen Diploma

‫الي عالم اخضر مستدام‬

… Vision 2050 …

Green – Lean - Clean


Master's student
‫ الي تصنيع أخضراء مستدام‬... ‫والتحول‬ 9
Eng. Dr. Hesham Saad
Ferrous Metallurgy
Postgraduate
Prof. Dr. Mohamed Mraikab , Dr. Sanaa Abd Almoaamen Diploma

Change in concentration = final concentration – initial concentration


Rate of reaction = change of concentration / change in time

‫الي عالم اخضر مستدام‬

… Vision 2050 …

Green – Lean - Clean


Master's student
‫ الي تصنيع أخضراء مستدام‬... ‫والتحول‬ 10
Eng. Dr. Hesham Saad

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