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Vaporpressure
Vaporpressure
http://hyperphysics.phy-astr.gsu.edu/Hbase/Kinetic/vappre.html
The varying boiling points depending on
pressure are used in real life for pressure
cookers and central cooling systems
http://media3.washingtonpost.com/wp-dyn/content/
graphic/2007/02/20/GR2007022000797.gif
Clausius-Clapeyron Equation
Questions
11.37 Explain how each of the following affects the vapor pressure of a
liquid:
A) Volume of liquid No Affect
B) Surface area No Affect
C) Intermolecular attractive forces When forces increase vp decreases
D) Temperature Vp increases with temp. increase
11.40 PCl3 and AsCl3 are similar substances, with similar geometries
and bonding modes.
b) Which substance would you expect to have the higher boiling point?
11.43
a) Use the vapor-pressure curve in Figure 11.22 to estimate the boiling
point of diethyl ether at 400 torr. Approximately 17º C
11.45 Mt. Denali in Alaska is the tallest peak in the United States (20,320 ft).
a) If the barometric pressure at the top of the mountain is 340 torr, at what
temperature will water boil there? Refer to Appendix B. 75º C
b) What can you say about the average kinetic energies of the water molecules
at the boiling point in Reno as compared with those at the boiling point in
Chicago, where the barometric pressure is 752 mm Hg? If you believe the
average kinetic energies are different, explain how it is that boiling of water can
occur at two different average kinetic energies of the water molecules.
Works Cited
Nave, Rod. "Vapor Pressure." Hyperphysics. Aug. 2000. Georgia State University.
3 Dec. 2008 <http://hyperphysics.phy-
astr.gsu.edu/hbase/kinetic/vappre.html>.