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Chemistry revision

Atom, protons, neutrons, electrons


What would we find in this table?

Particle Charge Mass Location

Proton

Neutron

Electron

Where is all of the mass of an atom kept?


Therefore, what does the mass number tell you?
Why is the charge of an atom always zero?

Atom, protons, neutrons, electrons


Particle Charge Mass Location

Proton +1 1 Nucleus

Neutron 0 1 Nucleus

Electron -1 0.0005 Outer shells

Atom, protons, neutrons, electrons


How to work out what is in an atom

• Number of protons = Atomic number

• Number of electrons = Number of protons

• Mass number = number of neutrons + protons

• Number of neutrons = Mass number – atomic number

Atom, protons, neutrons, electrons


C4 - Calculations

Complete the table

Element Symbol Mass Atomic Protons Neutrons Electrons


number number
(A) (Z)
Hydrogen H 1 1 1 0 1
6
Ca
Iron
70
Ag
79
Lead

Atom, protons, neutrons, electrons


Peer mark

Element Symbol Mass Atomic Protons Neutrons Electrons


number number
(A) (Z)
Hydrogen H 1 1 1 0 1
Carbon C 12 6 6 6 6
Calcium Ca 40 20 20 20 20
Iron Fe 56 26 26 30 26
Gallium Ga 70 31 31 39 31
Silver Ag 108 47 47 61 47
Gold Au 197 79 79 118 79
Lead Pb 207 82 82 125 82

Atom, protons, neutrons, electrons


Why do these group 1 elements have similar chemical
properties?

Lithium

Sodium

Potassium

Atom, protons, neutrons, electrons


Key point
Elements in the same group have the same number of electrons in
their outer shell.

Due to this
they have
similar
properties.

Atom, protons, neutrons, electrons


Metals and non-metals
Where are metals and non-metals found on the PT?

Atom, protons, neutrons, electrons


Metals

Metals lose electrons to have a full outer shell of electrons.

They have more protons than electrons and therefore become


positive ions.

Atom, protons, neutrons, electrons


Non-metals

Non-metals gain electrons and become negative ions.

An exception to this rule is hydrogen which is a non-metal but


does form a positive ion.

Atom, protons, neutrons, electrons


Copy and complete
Group Number of Number of Ions formed
Number electrons in electrons to
outer shell be gained or
lost
1
2
3
5
6
7

Atom, protons, neutrons, electrons


Group Number of Number of Ions formed
Number electrons in electrons to
outer shell be gained or
lost
1 1 -1 Positive (+1)
2 2 -2 Positive (+2)
3 3 -3 Positive (+3)
5 5 +3 Negative (-3)
6 6 +2 Negative (-2)
7 7 +1 Negative (-1)

Atom, protons, neutrons, electrons


Discuss

● What about group 0 elements?


● What do these have in common?
● What do you think this means in terms of reactivity?

Atom, protons, neutrons, electrons


The Noble Gases

Also known as the group 0 elements.

The noble gases have a full outer shell of electrons making them
very stable.

This full outer shell means they do not want to react with other
elements.

Atom, protons, neutrons, electrons


What makes an element?

An element is defined by the number of protons.

If the number of protons is changed then you have a different


element.

For example the element oxygen has 8 protons, but if you took one
of the protons away how many protons would there be?

You would now have the element nitrogen which has 7 protons.

Atom, protons, neutrons, electrons


What would happen if we changed the number of
electrons?

We can change the number of electrons an atom has and it will still
be the same element as long as we keep the number of protons the
same.

However electrons have a negative charge.

What will change is the charge that that atom has.

Atom, protons, neutrons, electrons


What is a charge on an atom?

Let’s take a look at at a sodium


atom.

Na We know that sodium has 11


protons and 11 electrons.

Sodium has 1 electron in its outer


shell.
11 protons (charge +11) If it can it will give this electron
11 electrons (charge -11) away.
overall charge = 0

Atom, protons, neutrons, electrons


How is a sodium ion formed?

+
loses
1 electron Na

It started with 11 electrons and loses 1 electron.


The sodium ion now has:
10 electrons
But still has 11 protons

Atom, protons, neutrons, electrons


What charge will the sodium ion have?

+
loses
1 electron Na

10 electrons (charge of -10)


But still has 11 protons (charge of +11)
There is more positive protons than negative
electrons so the charge is positive +1
(which is written as +)

Atom, protons, neutrons, electrons


What about an atom that gains electrons?

Let’s look at sulphur.


16 protons
Sulphur has 6
(charge +16)
S electrons in its outer
16 electrons shell and can gain
(charge -16) two electrons.

Atom, protons, neutrons, electrons


What will the charge be on the sulphur ion?

2-
gains
2 electrons
S

16 protons (charge +16)


18 electrons (charge -18)
There is less positive protons than negative
electrons so the charge is negative -2
Atom, protons, neutrons, electrons
What would happen if we changed the number of
neutrons?

Neutrons do not have any charge so the charge on the atom would
stay the same.

Each neutron has a mass of 1, so the mass of the atom would


change.

The number of protons stays the same so it would still be the same
element but would have a different mass number.

We call this an isotope.

Atom, protons, neutrons, electrons


Isotopes

However as they have different number of neutrons their mass


will change and so their physical properties can change (for
example boiling point).

Each element can have different isotopes. The mass number in


the periodic table represents the average mass of the different
isotopes.

Atom, protons, neutrons, electrons


Isotopes

Chlorine has an atomic mass of 35.5. It has the following


isotopes.
Chlorine-35
Chlorine-37
Compare the two chlorine isotopes; Cl-35 and Cl-37

Compare - To describe the similarities and/or differences


between things, not just write about one

Atom, protons, neutrons, electrons


Chlorine has an atomic mass of 35.5. It has the following
isotopes.
Chlorine-35
Chlorine-37
Compare the two chlorine isotopes; Cl-35 and Cl-37

Chlorine-35 has 17 protons, 17 electrons and 18


neutrons which means it has an atomic mass of 35.
Chlorine-37 has the same number of protons and
electrons as chlorine-35, but has more neutrons (20).
This means it has an atomic mass of 37.

Atom, protons, neutrons, electrons


Relative atomic mass

Relative atomic mass is the average mass


of a large number of atoms of that element.

As some elements have different isotopes,


the percentage abundance of each isotope
affects the relative atomic mass.

Atom, protons, neutrons, electrons


Formula for relative atomic mass

Worked example:

Chlorine-35 has a percentage abundance of 75%

Chlorine-37 has a percentage abundance of 25%

What is the relative atomic mass for chlorine?

Atom, protons, neutrons, electrons


Worked example

Chlorine-35: 75% Chlorine-37: 25%

Relative atomic = (35 x 75) + (37 x 25)


mass 100
= 3550
100
= 35.5

Atom, protons, neutrons, electrons


Work out the relative atomic mass

Copper-63: 70% Copper-65: 30%

Relative atomic = (63 x 70) + (65 x 30)


mass 100
= 6360
100
= 63.6

Atom, protons, neutrons, electrons


Work out the relative atomic mass

Lithium-6: 7.6% Lithium-7: 92.4%

Relative atomic = (6 x 7.6) + (7 x 92.4)


mass 100
= 692.4
100
= 6.9

Atom, protons, neutrons, electrons


How many electrons per shell?
Shells nearest the nucleus are filled first.

1st shell holds


a maximum of
2 electrons

2nd shell holds


a maximum of
8 electrons

3rd shell holds


a maximum of
8 electrons

This electron arrangement is written as 2,8,8.


Atom, protons, neutrons, electrons
23
11
Na
How many
electrons?
Atom, protons, neutrons, electrons
Two electrons
in the first
shell
Na
9 left

Atom, protons, neutrons, electrons


Eight
electrons in
the second Na
shell

One left

Atom, protons, neutrons, electrons


The last
electron in the
3rd shell

Na
We can write
this
configuration
as:
2,8,1

Atom, protons, neutrons, electrons


Rules to remember

If you know what group it is in, you know how many electrons are
in the outer shell.

For example:
Magnesium is in group 2 – it has 2 electrons in the outer shell
Chlorine is in group 7 – it has 7 electrons in the outer shell

Atom, protons, neutrons, electrons


Compound formulae

The formula of a compound tells you what elements it contains and


how many atoms of each element are in the compound.

When there is no number against the element’s symbol, it means


there is only one atom of that type present.

Atom, protons, neutrons, electrons


Example question:

The formula for sulphuric acid is H2SO4. How many of each type
of atom is there?

Hydrogen, H – 2
Sulphur, S – 1
Oxygen, O - 4

Atom, protons, neutrons, electrons


Some important compounds to remember:

Hydrochloric acid – HCl


Sulfuric acid – H2SO4
Nitric acid – HNO3
Sodium carbonate – Na2CO3
Copper (II) carbonate - CuCO3
Calcium carbonate - CaCO3
Hydrogen – H2
Carbon dioxide – CO2
Copper (II) oxide – CuO
Zinc oxide – ZnO
Sodium hydroxide - NaOH
Atom, protons, neutrons, electrons
Example question:

How many of each type of atom is there in copper (II) carbonate?

CuCO3

Copper, Cu - 1
Carbon, C – 1
Oxygen, O - 3

Atom, protons, neutrons, electrons


Example question:

How many of each type of atom is there in sodium carbonate?

Na2CO3

Sodium, Na – 2
Carbon, C - 1
Oxygen, O - 3

Atom, protons, neutrons, electrons


Example question:

How many of each type of atom is there in sodium hydroxide?

NaOH

Sodium, Na – 1
Oxygen, O – 1
Hydrogen, H - 1

Atom, protons, neutrons, electrons


Elements

An element is made up of only one type of atom. There are 92


elements in the periodic table.

Atom, protons, neutrons, electrons


Compounds

A compound is formed by two or more elements that have reacted


and joined together. The elements are joined together by chemical
bonds.

Atom, protons, neutrons, electrons


Mixtures

A mixture is made when two or more elements or compounds are


combined together but are not joined together by chemical bonds.
This means the chemical properties of the elements or compounds
do not change in a mixture.

Atom, protons, neutrons, electrons


Don’t get confused about molecules
A molecule is made up of two or more atoms joined together by
chemical bonds. The atoms may be the same, like in the element
oxygen, or different, as in the compound carbon dioxide.

Atom, protons, neutrons, electrons


Question: describe the difference between a
mixture and a compound

A mixture is where two substances are mixed


together but are not joined by chemical bonds. A
compound is where two or more atoms react and
are joined together by chemical bonds

Atom, protons, neutrons, electrons


Acid, bases and alkalis

All substances can be put into 1 of 3 categories: acid, base or


neutral. Some bases dissolve in water to make alkalis. An
indicator can be used to show if a substance is acidic, alkaline or
neutral.

Atom, protons, neutrons, electrons


The pH scale

Atom, protons, neutrons, electrons


Acids
• Acids have a pH of less than 7

• Stronger acids have a lower pH

• Strong acids turn universal


indicator red and weaker acids
turn it orange or yellow

• An acid turns blue litmus paper


red

Atom, protons, neutrons, electrons


Neutral
• Neutral solutions have a pH of 7

• Neither acidic or alkaline

• Turns universal indicator green

• Does not change the colour of litmus


paper

Atom, protons, neutrons, electrons


Alkalis
• Alkalis have a pH of more than 7

• Stronger alkalis have a higher pH

• Strong alkalis turn universal


indicator purple and weaker
alkalis turn it blue-green

• An alkali turns red litmus paper


blue

Atom, protons, neutrons, electrons


A base or an alkali?

A base is a substance that can react with an acid to neutralise it.


Most bases, like copper oxide (CuO), will not dissolve in water.

An alkali is a type of base – it has all the properties of a base (it


can neutralise an acid), however an alkali can dissolve in water.

Atom, protons, neutrons, electrons


Flashcard time!

Compare a base and an alkali

A base is a substance that can neutralise an acid. It cannot dissolve


in water. An alkali is a type of base, however it can dissolve in
water.

Atom, protons, neutrons, electrons


Neutralisation reactions

It is possible to neutralise an acid or base by carrying out a


neutralisation reaction.

When you add an acid to a base, they can react to produce a neutral
substance. However, you need the right amounts.

Too much acid or too little base —> no neutralisation


Correct amount of acid + correct amount of base —> neutralisation
Too little acid or too much base —> no neutralisation

Atom, protons, neutrons, electrons


Products of neutralisation reaction

A neutralisation reaction usually produces a SALT and WATER.

Acid + Base —> Salt + water

Atom, protons, neutrons, electrons


Atom, protons, neutrons, electrons
Reactions of acids with carbonates

Metal carbonates react with acids to form three products


• A salt
• Carbon dioxide
• Water

The only carbonates you need to know about are


• Sodium carbonate
• Copper carbonate
• Calcium carbonate

Atom, protons, neutrons, electrons


Tests for hydrogen and carbon dioxide

Reactions of acids with metals produce hydrogen gas, and


reactions of acids with a carbonate produce carbon dioxide.

How can we check that one of these reactions has occurred?

Atom, protons, neutrons, electrons


Test for hydrogen gas

To test for hydrogen, places lighted splint into a test tube


containing the gas. If hydrogen is present, there is a “squeaky pop”
sound.

Atom, protons, neutrons, electrons


Test for carbon dioxide

To test for carbon dioxide, bubble the gas produced in a reaction


through limewater.

Atom, protons, neutrons, electrons


Hazard symbols

Many substances can be harmful, so these are given symbols that


are recognised all over the world. This is so that people from
different countries who speak different languages will be able to
recognise the hazard symbols and know to be careful.

Atom, protons, neutrons, electrons


Corrosive

Avoid contact with the skin as it attacks and destroys living tissue.
Strong acids and strong bases are both corrosive

Atom, protons, neutrons, electrons


Toxic

Can cause death or damage to health if swallowed, breathed in or


absorbed by skin.

Atom, protons, neutrons, electrons


Flammable

These substances catch fire easily and should be stored in flame-


resistant cupboards.

Magnesium is flammable.
Hydrogen gas is flammable.

Atom, protons, neutrons, electrons


Moderate hazard

This substance is not corrosive but is harmful if inhaled or will


cause irritation to the skin, eyes or inside the body.

Dilute acids and dilute sodium hydroxide are irritants.


Copper oxide is harmful.

Atom, protons, neutrons, electrons


Environmental hazard

These substances could cause immediate or delayed harm to


ecosystems.
Copper oxide is hazardous to the environment.

Atom, protons, neutrons, electrons


How can we apply neutralisation reactions?

Day to day, substances can naturally be too acidic or alkaline. In


these cases, neutralisation reactions can be used to adjust the
acidity or alkalinity of the substance.

Let’s look at some example!

Atom, protons, neutrons, electrons


Neutralisation of acidic soil

Some plants grow well in acidic soil but many do not.

Farmers add a base, such as lime (calcium oxide) or powdered


chalk (calcium carbonate) to acidic soil, which helps to reduce the
acidity.

Atom, protons, neutrons, electrons


Indigestion remedies

Your stomach produces hydrochloric acid to


help digest your food. If too much acid is
produced, this can cause indigestion.

Indigestion is usually treated by taking antacids,


as these can help to neutralise the excess acid.

Many antacids contain the bases calcium


carbonate and magnesium carbonate.

Atom, protons, neutrons, electrons


Neutralising acidic waters

Gases that are produced from burning


fuels can mix with clouds and produce
acid rain.
Acid rain falls into streams and lakes and
can result in the water becoming acidic.
This acidic water can harm the organisms
that live in the water.
Lime can be added to water to make the
water less acidic.

Atom, protons, neutrons, electrons


Paper is out of 54

● 2019: 41% to pass, 57% to merit, 74% to


distinction

● 2020: 37% to pass, 56% to merit, 74% to


distinction

Atom, protons, neutrons, electrons

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