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Chapter 4 Bohr's Model of The Atom
Chapter 4 Bohr's Model of The Atom
α particle scattering
N: the number of atoms that deflect an α particle
θ: the angle of deflection in passing through one atom
Θ: the net deflection in passing through all the atoms
( 2 )1 / 2
N ( 2 )1 / 2
2 I 2 / 2
N ( )d 2
e d is the number of particle scattered
within the angular range to d
r 10 10 m 10 -4 rad by Thomson' s model prediction
Chapter 4 Bohr’s model of the atom
6
Ex: In a typical experiment, α particles were scattered by a gold foil 10 m
2 1/ 2 o 2
thick. The average scattering angle was found to be ( ) 1 2 10 rad
Calculate ( 2 )1 / 2
(a) the number of atoms N 106 m/1010 m 104
2 1/ 2( 2 )1 / 2 2 10 2
( ) 2
2 10 4 rad
N 10
agree with the Thomson' s atom estimation
o
N( 90 ) / I N( )d / I e ( 90 ) 10 3500
90o
All the positive charge of the atom, and consequently essentially all its mass, are
assumed to be concentrated in a small region in the center called the nucleus
rnuleus 10 14 m
d d
dN Ind : differential cross section
d d
d 2 sin d
1 2 zZe 2 2 1
N ( )d dN ( ) ( 2
) 4
Ind
4 0 2 Mv sin ( / 2)
Rutherford scattering differenti al cross section :
d 1 2 zZe 2 2 1
( ) ( )
d 4 0 2 Mv 2 sin 4 ( / 2)
Chapter 4 Bohr’s model of the atom
4.3 The stability of the nuclear atom
An apparatus for
measuring atomic spectra
Chapter 4 Bohr’s model of the atom
n2
Balmer (1885) : 3646 2 ex : n 3( H ), n 4( H )
n 4
1 1 1
Ryberg (1890) : RH ( 2 2 ) n 3,4..
2 n
RH 1.097 107 m -1 : Ryberg constant for H
For alkali elements (Li, Na, K,...) :
1 1 1
κ R[ ]
λ ( m a )2 ( n b)2
Chapter 4 Bohr’s model of the atom
4.5 Bohr’s postulate
mM m2 m m R
RM R
m M 2m 2 mm 2
RM hcZ 2 R hcZ 2
E positroniu m
n2 2n 2
1 R 1 1
Z 2( 2 2 )
c 2 n f ni
the electron - positron separator D in ground state is :
4 0 n 2 2 4 0 n 2 2
Dpositroniu m 2 2rhydrogen
Ze 2 mZe 2
Chapter 4 Bohr’s model of the atom
Ex: A muonic atom contains a nucleus of charge +Ze and a negative muon μ-
move about it, The μ- is an elementary particle with charge –e and a mass that
is 207 times as large as an electron mass. (a) Calculate the muon-nucleus
separation, D, of the first Bohr orbit of a muonic atom with Z=1. (b) Calculate
the binding energy of a muonic atom with Z=1. (c) What is the wavelength of
the first line in the Lyman series for such an atom?
(a) m 207me , M 1836me
207me 1836me
186me
207me 1836me
4 0 2 1 11 3
o
Dn1 2
5.3 10 m 2.8 10 A
186me e 186
me e 4
(b) E 186 186 13.6 eV 2530 eV
(4 0 ) 2 2 2
is the ground state energy. The binding energy is 2530 eV.
1 1 1 1 o
(c) RM ( 2 2 ) 186 R (1 ) 139.5 R 6.5 A
n f ni 4
Chapter 4 Bohr’s model of the atom
Ex: Ordinary hydrogen contains about one part in 6000 of deuterium, or heavy
hydrogen. This is a hydrogen atom whose nucleus contains a proton and a
neutron. How does the doubled nuclear mass affect the atomic spectrum?
R 109737 cm 1
RH R 109678 cm 1
m (1 m / M ) (1 1 / 1836)
R 109737 cm -1
RD R 109707 cm -1
m (1 m / M ) (1 1/2 1836)
RD RH D H D H
The spectral lines of the deuterium atom are shifted
to slightly shorter wavelength s compared to hydrogen.
Chapter 4 Bohr’s model of the atom
4.8 Atomic energy states
9.8 eV
Hg 4.9 eV
Energy level
of Hg vapor
V : accelerating potential
Vr : retarding potential
Chapter 4 Bohr’s model of the atom
4.8 Interpretation of the quantization rules
Some Mysteries:
Bohr’s quantization of the angular momentum?
Planck’s quantization of the energy?
dx( t )
x ( t ) A cos t A sin t v ( t )
dt
dv ( t )
a(t ) 2 A cos t
dt
k
F a( t )m kx ( t ) 2 m k 2
m
p x2 kx 2 p x2 x2
E K V 1
2m 2 2mE 2 E / k
p x2 x 2
1 for b 2mE , a 2 E / k
b2 a 2
p dx ab
x 2mE 2 E / k 2E /
E / n x h nh E nh
E E ( n 1) E ( n) ( n 1)h nh h
h 0 E 0 continuous energy
Chapter 4 Bohr’s model of the atom
4 0 n 2 2 n 1 2 Z 2 e 4
a 2
,b a E ( )
Ze n 4 0 2n 2 2
: reduced mass nr : radial quantum number
n : azimuthal quantum number
n nr n principal quantum number
(1) n n circular orbit
(2) n nr elliptical orbit
For the same n, but different nr and n energy is degenerate.
Chapter 4 Bohr’s model of the atom
Z 2 e 4 2Z 2 1 3
E 2 2 2
[1 ( )]
(4 0 ) 2n n n 4n
1 e2 1
fine structure constant
4 0 c 137
Selection rule:
ni nf 1
Chapter 4 Bohr’s model of the atom
4.11 The correspondence principle
Bohr (1923):
(1) In a limit of very large quantum number, the prediction of quantum
theory corresponds to that of classical theory.
(2) Any selection rule hold true in the quantum theory, which also apply in
the classical limit (very large quantum number).
Transitions are observed to occur between states of low n, in which the old
quantum theory cannot always be made to agree with experiment.
Chapter 4 Bohr’s model of the atom