Professional Documents
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Nuclear
Nuclear
Tom Holme
Chapter 14
Nuclear Chemistry
2
Chapter Objectives
3
Chapter Objectives
4
Cosmic Rays and Carbon Dating
5
Cosmic Rays and Carbon Dating
• Cosmic rays originate from solar flares on the sun, which can
accelerate highly charged cations until they approach the
speed of light.
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Cosmic Rays and Carbon Dating
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Cosmic Rays and Carbon Dating
decay.
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Radioactive Decay
11
Radioactive Decay
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Radioactive Decay
• A thin sheet of aluminum blocks alpha rays but not beta rays.
In a magnetic field, beta and alpha particles are deflected in
different directions, while gamma rays are undeflected.
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Radioactive Decay
15
Example Problem 14.1
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Beta Decay
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Example Problem 14.2
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Gamma Decay
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Gamma Decay
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Electron Capture and Positron Emission
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Positron Emission
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Kinetics of Radioactive Decay
• 1 Ci = 3.7 × 1010 Bq
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Kinetics of Radioactive Decay
• The half-life, t1/2, is the time required for half the sample to
disintegrate.
• Radioactive decay
always follows first-order
kinetics. The half-life is
constant for any given
isotope.
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Example Problem 14.4
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Radiocarbon Dating
• 14
C is continually formed through the interaction of cosmic
rays with the atmosphere.
29
Example Problem 14.5
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Radiocarbon Dating
• Half-lives of some
radioactive
isotopes. Long
lived isotopes, such
as uranium, can be
used to date
minerals and
geological
formations.
31
Nuclear Stability
• All stable
isotopes lie
in the region
shown with
blue dots.
33
Nuclear Stability
34
Nuclear Stability
35
Nuclear Stability
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Nuclear Stability
39
Binding Energy
• The binding
energy per
nucleon plotted
as a function of
mass number for
elements
hydrogen through
uranium. The
curve reaches a
maximum at 56Fe.
41
Magic Numbers and Nuclear Shells
• Of the more than 260 stable nuclei, most have even numbers
of both protons and neutrons.
42
Magic Numbers and Nuclear Shells
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Transmutation, Fission, and Fusion
44
Transmutation
• 10
B reacts via neutron capture to produce 11B*, an unstable
intermediate nucleus called the compound nucleus, which
decays almost instantly like an activated complex in a
chemical reaction.
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Fission
46
Fission
47
Fission
• Bombarding
enriched
uranium with
neutrons
induces the
fission of 235U,
and each decay
produces
additional
neutrons for
further induced
fission.
48
Fission
49
Example Problem 14.6
50
Nuclear Reactors
reactors.
• Only 0.72% of naturally occurring U is fissile 235U.
• Uranium is enriched to increase the percentage 235U
before it can be used as fuel.
51
Nuclear Reactors
• The uranium oxide fuel is embedded into fuel rods and placed
in a water-covered reactor core.
• The water cools the fuel rods and moderates the reactor,
slowing down fast neutrons.
• The water carries heat released to the steam turbine.
Steam turns the turbine, which generates electricity.
• The chain reaction is initiated by a source of neutrons.
• The chain reaction is regulated via control rods.
• The control rods are inserted between the fuel rods to slow
or stop the chain reaction.
• Control rods are composed of cadmium or boron and
regulate the chain reaction by absorbing extra neutrons to
maintain a steady rate of fission.
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Nuclear Reactors
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Nuclear Waste
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Fusion
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Ionizing and Penetrating Power of Radiation
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Ionizing and Penetrating Power of Radiation
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Ionizing and Penetrating Power of Radiation
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Methods of Detecting Radiation
• Alpha and beta particles enter though a window and ionize the gas
atoms.
• Electrons released by the gas atoms are attracted to the anode,
and ionize more gas as they travel to the anode, releasing more
electrons.
• When the avalanche of electrons reaches the anode, a current
pulse is recorded.
68
Methods of Detecting Radiation
70
Measuring Radiation Dose
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Measuring Radiation Dose
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Modern Medical Imaging Methods
• The function of organs can be examined by selectively introducing
small amounts of an appropriate radioisotope into the target organ.
• Radiation from the isotope is monitored to produce a detailed
image of the organ.
• Structure, as well as function, can be revealed.
74
Modern Medical Imaging Methods
• In the thyroid, the 131I undergoes beta decay.
• Detection of the gamma particles produces an image of the
thyroid gland.
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Modern Medical Imaging Methods
• Each decay of the radioisotope releases a positron.
• Positrons have extremely short lifetimes in the body.
• Positrons travel no more than a couple of millimeters before
encountering an electron.
• The positron and electron undergo matter-antimatter
annihilation.
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Modern Medical Imaging Methods
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