Professional Documents
Culture Documents
Soda Ash Pres
Soda Ash Pres
Soda Ash Pres
OF
SODA ASH
1
Scope of presentation
2
TATA CHEMICALS LIMITED
* Leading manufacturer of inorganic chemicals and
fertilizers in India
* Part of the US$ 11 billion Tata Group
* Operates the largest inorganic chemicals complex
in India and a state-of-the-art fertiliser plant.
* The largest producer of soda ash and vacuum
evaporated iodized salt in India
* Soda ash, salt, marine based chemicals as also
cement manufactured at the Mithapur chemicals
complex.
* Fertilizer Division in Babrala, UP 2250 TPD, A
Modern urea plant benchmarked for energy and
environmental performance.
3
Tata Chemicals Ltd, Chemicals Division - Mithapur
4
TATA CHEM Soda Ash
6
THE PROCESS
The process can be represented by the following simplified equation :
7
THE PROCESS
8
THE TECHNOLOGY
9
THE TECHNOLOGY
The solvay ammonia soda process is shown schematically in the attached block
diagram.
The main operational stages are shown in the numbered bold rectangles.
10
Soda Ash Process Flow Diagram
SALT
(NaCl)
BRINE AMMONIA
SALT AMMONIA
PREPARATION
WATER DISSOLVERS ABSORBER
& PURIFICATION
LIMESTONE
MILK OF LIME
PRODUCT SODA ASH (Na2CO3) EFFLUENT CONTAINING CaCl2
Stage 1: Brine preparation and purification.
This section is subdivided in to,
13
3. Purification of Brine
Purification of brine, which should be as near saturation as possible to achieve optimum
Na+ utilization, is carried out by the lime - soda process. Magnesium ions are precipitated as
hydroxide, and calcium ions as carbonate.
14
Stage 2: Limestone burning and Lime slaking.
Limestone must be of high purity.
SiO2 : less than 3%
Fe2O3 + Al2O3 : less than 1.5&
Desired size : 50 mm to 100 mm
Both CO2 for carbonation stage and calcium oxide for the distillative recovery of ammonia are
produced by calcination of limestone with coke.
In the system CaCO3 ===> CaO + CO2, the equilibrium pressure of CO2, (Partial pressure of
CO2) varies logarithmically with absolute temperature.
15
Stage 3: Ammonia absorption
Gases from the distillation stage contains NH3 and CO2 and is saturated with water vapor. In
the absorption stage this gas is absorbed by purified brine..
The required amount of Sulphide gas is dozed in the ammoniated brine to give a proper
sulphide coating to all the succeeding equipment to impair white colour to the product.
16
Stage 4: Precipitation of Bicarbonate
The precipitation of Sodium bicarbonate is an exothermic process in which ammoniacal
brine from the absorption tower is reacted with carbon dioxide from the lime kiln (Stage 2) and
from the calcination stage (Stage 6). Cast iron columns are used for this reaction.
17
Stage 5: Filtration of Bicarbonate
Bicarbonate is separated from the mother liquor in continuous rotary vacuum filters.
Mother liquor adhering to the bicarbonate crystals is washed off with water.
The quantity of washing water required depends on the particle size of the precipitated
Bicarbonate.
18
Stage 6: Calcination of Bicarbonate
Thermal decomposition of crude bicarbonate to carbonate liberates carbon dioxide,
ammonia and water vapor.
The heat requirement for calcination in Steam tube dryer is 3.7 GJ/ton of Soda ash and is
supplied by 28 Kg/cm² steam.
19
Stage 7: Recovery of Ammonia
Ammonia present in the filtrate as ammonium carbonate, hydrogen carbonate, sulphate and
chloride is recovered by distillation followed by absorption.
Distillation gas, which contains, NH3 and CO2, is cooled to approx.. 65 ºC, In still condenser and
still pre heater
20
Waste Disposal in Soda Ash Plant
Solids originated mainly from impurities in the limestone and coke, and include uncalcined
or dead-burnt limestone.
The effluent liquor is passed through effluent treatment plant and finally at cement plant where
solids are used as a raw material to produce clinker, and pumped in to large settling ponds. The
clear liquor is diluted using sea water and discharged directly in to sea.
21
Quality Specification
The product obtained by the solvay process is Light Soda ash has a bulk density of 0.6 to 0.7
Kg/l.; Dense Soda ash 1.05 to 1.1 Kg/l.
The difference in particle-size distribution between light and dense soda ash is shown by the
following value:
22
Storage and Transportation
Soda ash is hygroscopic, gradually taking moisture and carbon dioxide during
transportation and storage. This converts the surface of sodium carbonate to the bicarbonate
and leads to a weight increase of up to 1.5 % with in 30 minutes at 96 % R.H. Due to this reason
we have 100% of our packing done in HDPE bags.
23
MANUFACTURING
OF
SODIUM BICARBONATE
24
Manufacturing of Sodium Bicarbonate
Precipitate of Sodium Bicarbonate is obtained by reacting Soda solution with CO2 gas in the
tower.
Precipitate of NaHCO3 is separated and washed off in semi batch type centrifuge and dried by
fluidization with hot air.
25
26
Manufacture of Dense Soda ash
27
Manufacturing of Dense Soda Ash
Dense ash is mainly used in manufacturing of glass.
Chemical composition of Dense ash is same as of Light Soda ash. The difference is in bulk
density and particle size.
Operating stages:
Plant Capacity:
28
New Dense Ash Plant (Mechanical Process)
Compacting:
Crushing:
Screening:
Oversize from upper deck of double deck screen is recycled to the disintegrator. Oversize of
the bottom screen is packed as Dense ash in HDPE bags.
29
Mono Hydrate Plant (chemical Process)
Hydration
Drying
Screening
Oversize from upper deck of double deck screen is recycled and crushed
mechanically. Oversize of the bottom screen is packed as Dense ash in HDPE
bags.
30
31
THANK YOU
32