Presentation Shafhal (Final Project)

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ADDITION OF SODIUM BICARBONATE IN

FLUE GAS AREA AS AUXILIARY TO


REDUCE SULFUR CONTENT
AUTHOR BY:
MUHAMMAD SHAFHAL JAMIL
TOPICS

General Process

Background

Research Methodology

Result

Conclusion
FGD
Absorber
Air Heater
FGD Cycle Fly Ash Water – Steam Cycle
ESP
Air Cycle
Sea Intake Pretreated Water Make Up
Chlorination BasinBoiler Pit & Plant HCl & NaOHAsh Leachate
FGD Plant
Sedimentation
Coal Run Off Retention Basin Tank Econ
ESP Hopper Hopper
NaOH
Pond
NaOH + H2SO4 Neutralization Ash Run Off
(WTP) & FGD Make Up & Circulation
+ FeCl3 Tank
FeCl3
Blowdown
Reverse Osmosis Tank Water Flue Gas Cycle
Waste Water Treatment Neutralization
Polymer
Reagent Tank Ash Handling
Fly Ash SBS
Silo Biocide &
H2SO4
Preparation Clarifier Tank Antiscalant pH Adjustment
ROTank
Sludge Sludge
To The Sea
NaOH Dewatering Disposal
H2SO4
Dewatering Brine WWTP
Sedimentation Guard Filter
Pond
Supernatant
Tank Generator Bottom Ash
Neutralization Furnace
FeCl3 Coagulation LP 1,2, 3 WWTP
Crusher
Limestone Coal Polymer (22,8
Tank KV)
Clarifier & Treated
TankHeater Discharge
To The Sea Coal Feeder
HandlingTo The Sea Multi Media Filtered Water
Filter Basin
LP
Electricity SSCC
Turbine
Water Treatment IP TurbineHP HP 5,6,7
Excitation
Seawater Stop Log Bar
Turbine
Travelling
Heater
Screen
Transformer
Chlorine
Screen

Intake - Circulating (890 V) Generator


Water Cycle Bottom Ash Transformer
Bunker (500 KV)
Truck
Unit TransformerTruck
(10 KV)
BACKGROUND

Problem
Emission flue gas result of burning coal
High Sulfur content from flue gas

Problem Solving

Addition or injection NaHCO3 in flue gas area

Goals
Help FGD performance to reduce Sulfur content
To comply with KLHK regulation
RESEARCH
METHODOLOGY

Calculate &
Collect
Start Analysis
Actual Data
Data
COLLECT
ACTUAL DATA
C SO2 (mg/Nm3)
1600
1700
1800
1900
2000 Sulfur Content In Flue Gas (Collect
2100 Actual Data From Performance)
2200
2300
2400 Assuming
2500 Full Load
Condition
CALCULATE &
ANALYSIS DATA
SO2 that needs to
be reduce 𝑚𝑆𝑂2𝑟𝑒𝑚𝑜𝑣𝑎𝑙=%𝑆𝑂2×𝑚𝑆𝑂2
• Description :
• M SO2 removal (Mass Rate of SO2 that needs to be reduced
• %SO2 removal (Percent Mass SO2 that needs to be reduce)
• M SO2 (Mass of SO2)

𝑚𝑆𝑂 2 𝑟𝑒𝑚𝑜𝑣𝑎𝑙
Consumption of 𝑚𝑁𝑎𝐻𝐶𝑂 3=
𝑔 𝑆𝑂 2
NaHCO3 required 1 , 00 ×𝜂 𝑁𝑎𝐻𝐶𝑂 3
𝑔𝑁𝑎𝐻𝐶𝑂 3
• Description:
• M NaHCO3 (Mass of Sodium Bicarbonate required)
• ɳ NaHCO3 ( Effectiveness of utilization Sodium Bicarbonate)
RESULT

SO2 Content Must be Reduced

Mass of NaHCO3 Required

Economic
SO2 CONTENT MUST be REDUCED

SO2 content must be Conversion SO2


reduced removal
C SO2 (mg/Nm3) %so2 removal C SO2 removal (mg/Nm3) C SO2 removal (mg/Nm3) FG dry (m3/menit) C SO2 removal (mg/menit) C SO2 removal (kg/jam)
1600 6% 100 100 45.000 4500000,00 270
1700 12% 200 200 45.000 9000000,00 540
1800 17% 300 300 45.000 13500000,00 810
1900 21% 400 400 45.000 18000000,00 1080
2000 25% 500 500 45.000 22500000,00 1350
2100 29% 600 600 45.000 27000000,00 1620
2200 32% 700 700 45.000 31500000,00 1890
2300 35% 800 800 45.000 36000000,00 2160
2400 38% 900 900 45.000 40500000,00 2430
2500 40% 1000 1000 45.000 45000000,00 2700
MASS of NaHCO3 REQUIRED

C SO2 removal (kg/jam) Ratio Desulfurisasi ɳNaHCO3 (%) C NaHCO3 (kg/h)


270 1 70% 385,71
540 1 70% 771,43
810 1 70% 1157,14
1080 1 70% 1542,86 Mass needs of
1350 1 70% 1928,57 NaHCO3 per 100
1620 1 70% 2314,29 mg/Nm3 are 385,71
kg/h
1890 1 70% 2700,00
2160 1 70% 3085,71
2430 1 70% 3471,43
2700 1 70% 3857,14
ECONOMIC

Purchase Price of NaHCO3 for 1


ton/hr

Price of NaHCO3 Need for NaHCO3 Purchase price of NaHCO3 for 1 hour
Rp/kg kg/jam Rp/jam
Rp10.000,00 1000,00 Rp10.000.000,00
CONCLUSION
• Sodium bicarbonate is effective adsorbent to
1
reduced SO2

• The best injection in area flue gas after Air Heater


2
with a temperature 140-180 oC

 Experiments through laboratory tests need to be


3
carried out to find out the more accurate result.
Thank You

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