1. The developer solution contains reducing agents like hydroquinone and phenidone that produce black densities and shades of grey. Sodium carbonate and sulfite control the pH and prevent oxidation. Bromides and iodides restrain developer activity to only exposed silver crystals.
2. The fixer solution contains thiosulfate as the fixing agent to remove undeveloped silver bromide. Acetic acid provides an acidic pH to stop development and hardeners help stiffen the emulsion.
3. Both solutions include buffers, sequestering agents, preservatives and water as the solvent to dissolve the chemicals at the proper concentrations for processing film.
1. The developer solution contains reducing agents like hydroquinone and phenidone that produce black densities and shades of grey. Sodium carbonate and sulfite control the pH and prevent oxidation. Bromides and iodides restrain developer activity to only exposed silver crystals.
2. The fixer solution contains thiosulfate as the fixing agent to remove undeveloped silver bromide. Acetic acid provides an acidic pH to stop development and hardeners help stiffen the emulsion.
3. Both solutions include buffers, sequestering agents, preservatives and water as the solvent to dissolve the chemicals at the proper concentrations for processing film.
1. The developer solution contains reducing agents like hydroquinone and phenidone that produce black densities and shades of grey. Sodium carbonate and sulfite control the pH and prevent oxidation. Bromides and iodides restrain developer activity to only exposed silver crystals.
2. The fixer solution contains thiosulfate as the fixing agent to remove undeveloped silver bromide. Acetic acid provides an acidic pH to stop development and hardeners help stiffen the emulsion.
3. Both solutions include buffers, sequestering agents, preservatives and water as the solvent to dissolve the chemicals at the proper concentrations for processing film.
1. The developer solution contains reducing agents like hydroquinone and phenidone that produce black densities and shades of grey. Sodium carbonate and sulfite control the pH and prevent oxidation. Bromides and iodides restrain developer activity to only exposed silver crystals.
2. The fixer solution contains thiosulfate as the fixing agent to remove undeveloped silver bromide. Acetic acid provides an acidic pH to stop development and hardeners help stiffen the emulsion.
3. Both solutions include buffers, sequestering agents, preservatives and water as the solvent to dissolve the chemicals at the proper concentrations for processing film.
Components of The Developer Solution & Their Functions
COMPONENT CHEMICAL FUNCTION
1. DEVELOPING AGENT HYDROQUINONE - 60F Reducing agent, produce black densities (Reducers) (Q DEVELOPER) slowly Principal component, controls “shoulder” Amplifier Metallic Silver of characteristic curve; upper scale density (Dmax) Sensitive to oxygen that result to developer oxidation Provides upper scale density; creating OD above 1.2-2.0/2.4 OD in the image Slowly reduces silver Sensitive to light Contrast Indicator Difference density
PHENIDONE - 75F Reducing agent, produces shades of grey
(P DEVELOPER) rapidly; secondary component (METHOL & ELON) - MANUAL Controls “toe” of characteristic curve (Dmin) Provide increase concentration of solution Provide intermediate densities Quickly reduces silver; cannot reduced heavily exposed areas Speed Indicator 1.2 OD Midrange density Sensitive to temperature 2. ACTIVATOR SODIUM CARBONATE Retard the activity of developers agent (Buffering Agent) SODIUM HYDROXIDE to a control limit POTASSIUM CARBONATE Helps swell gelatin; produces alkanity; POTASSIUM HYDROXIDE controls PH SODIUM METABORATE Buffering Agent Nutralizes PH and stops developer action. Best Alkalizer PH (10 - 10.5) PH (9.6 - 10.6) PH - Alkalinizer 3. RESTRAINER POTASSIUM BROMIDE Starter solution - decrease developer (Regulator) SODIUM BROMIDE activity (Anti Foggant) SODIUM IODIDE Anti foggant agent (Starters) POTASSIUM IODIDE Reducer - controls activity of reducing BENZOTHIOSULFATE agent -Decrease activity of Developing Agent. Protects unexposed crystal from chemical attack Added to the developer to limit its activity to only the exposed silver crystals Fog increases when low in developer 4. PRESERVATIVE SODIUM SULFITE Control oxidation; decreases oxidation (Anti Aging) POTASSIUM SULFITE of solution (Anti Oxidants) Helps maintain the proper development rate Makes the developer to remain clear Stabilizer - maintains balance among developer components 5. HARDENER GLUTARALDEHYDE Controls emulsion swelling and (Tanning Agent) DIALDEHYDE enhances ahival quality Maintain uniform thickness “Tanning Agent” Ensure film is transported properly through washand dry section Prevent Pick Off Emulsion Artifact
developing agent Forms stable complexes with these metallic ions and salts Prevents precipitation of a calcium sludge
7. SOLVENT WATER (Distilled) Dissolves chemicals for use
Use to dilute the concentration of the proper strength of the chemicals Liquid in which various solids and powders can be dissolve Components of The Fixer Solution & Their Functions COMPONENT CHEMICAL FUNCTION
1. ACTIVATOR ACETIC ACID Provides acidic PH; neutralizes the
(Acidifier) Neutrilizer developer and stops its action Development fog occurs when the BORIC ACID reducing action of the developer is not Buffer stopped Acid PH (4-4.5) / (4.2-4.9)
(Clearing Agent) SODIUM THIOSULFATE - Manual from emulsion -Permanents the image Processing Clearing agent, hypo or thiosulfate Removes unexposed and undeveloped SHC from the emulsion Classically known as “Hypo” Function to clear the film of the unexposed, undevelope AgBrcrystals Thiosulfate - causes a brownish stain
3. HARDENER POTASSIUM ALUM Stiffens and shrinks emulsion
ALUMINUM ALUM Causes emulsion to become more rigid CHROMIUM ALUM or hardened ALUMINUM CHLORIDE Prevents fading of the image Must function in acidic environment Raises temperature at which gelatin softens Potassium Alum - not considered an organic reducing agent 4. PRESERVATIVE SODIUM SULFITE Maintains chemical balance (Stabilizer) CYGON Dissolves silver from the ammonium thiosilversulfate Reduces sulphurization of fixing agent Ensure superaddivity
SODIUM SALTS OF EDTA Removes aluminum ions SODIUM HEXAMETAPHOSPHATE Prevents precipitation of calcium sludge (CALGON) which would show up as chalky deposit on the film