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Ch05 Sulu Çözeltiler+
Ch05 Sulu Çözeltiler+
Ch05 Sulu Çözeltiler+
Philip Dutton
University of Windsor, Canada
Prentice-Hall © 2002
A strong electrolyte:
MgCl2(s) → Mg2+(aq) + 2 Cl-(aq)
A weak electrolyte:
2) H2O + O2 + 4 e- → 4 (OH) -
EN 12473:2000 Standards
General principles of
cathodic protection in sea
water
Slide 11 of 43 General Chemistry: Chapter 5 Prentice-Hall © 2002
Notation for Concentration
In 0.0050 M MgCl2:
Stoichiometry is important.
Aluminum Concentration:
• Precipitation occurs.
AgCl(s), AgI(s)
e) Pb(NO
Pb(NO33))2(aq)
2 and Na
+ Na 2SO
2SO 4 → PbSO4(s) + 2 NaNO3(aq)
4(aq)
Slide 25 of 43 General Chemistry: Chapter 5 Prentice-Hall © 2002
5-3 Acid-Base Reactions
HCN
HF
Slide 27 of 43 General Chemistry: Chapter 5 Prentice-Hall © 2002
Bases
• Bases provide OH- in aqueous solution.
Strong bases
• Strong bases: NaOH
KOH
NaOH(aq) → Na+(aq) + OH-(aq)
H2O
• Weak bases:
NH3(aq) + H2O(l) ←
→ OH-(aq) + NH4+(aq)
Weak bases
NH3, CH3NH3
Slide 28 of 43 General Chemistry: Chapter 5 Prentice-Hall © 2002
Recognizing Acids and Bases.
Mg(OH)2(s) + 2 CH3CO2H(aq) →
Mg2+(aq) + 2 CH3CO2-(aq) + 2 H2O(l)
• Oxidation
– O.S. of some element increases in the reaction.
– Electrons are on the right of the equation
• Reduction
– O.S. of some element decreases in the reaction.
– Electrons are on the left of the equation.
S4+ → S+6 + 2 e-
5 e- +Mn+7 → Mn2+
1 mol Fe 1 mol Fe 2
nH 2O 0.1568 g Fe
55.847 g Fe 1 mol Fe
1 mol MnO4 1 mol KMnO4 4
2
5 . 615 10 mol KMnO4
5 mol Fe 1 mol MnO4
Determine the concentration:
5.615 104 mol KMnO4
[ KMnO4 ] 0.02140 M KMnO4
0.02624 L
A) OH - : 2; H2O: 3
B) OH - : 3; H2O: 2
C) OH - : 2; H2O: 2
D) OH - : 2; H2O: 1
E) OH - : 1; H2O: 2
Slide 54 of 43 General Chemistry: Chapter 5 Prentice-Hall © 2002
Chapter 5 Questions
Determine the oxidation states:
reduced
+7 -1 +4 +5
MnO4-(aq) + Br -(aq) → MnO2(s) + BrO3- (aq)
oxidized
Write the half-reactions:
x2 Mn+7 + 3e - → Mn+4
Br - → Br+5 + 6e-
2MnO4-(aq) + Br -(aq) → 2MnO2(s) + BrO3- (aq)
-3 -1
+ 2OH-
Balance atoms other than H and O:
oxidized
Write the half-reactions:
x2 Mn+7 + 3e - → Mn+4
x3 CN - → CN+1 + 2e-
-5 -3
+ 2OH-
Balance atoms other than H and O:
1, 2, 3, 5, 6, 8, 14,
17, 19, 24, 27, 33,
37, 41, 43, 51, 53,
59, 68, 71, 82, 96.