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CREATING T O M O R R O W ’ S S O L U T I O N S

E M E A I C O N S T R U C T I O N INDUSTRY I P O LY M E R I C B I N D E R S

TECHNOLOGY AT THE CONSTRUCTION SITE


TILE ADHESIVES
DEVELOPMENTS FOR A
GROWING MARKET Contents

New Demands on Tile Adhesives


Tile Types 3
Tiles have been used for over 3,500 Different Answers for Different Needs Substrates 4
years and are more popular now than Asia remains the largest tile consumer at Environmental Factors 5
ever. In 2020, 13,036 million m2 of over 56%. Ceramics will account for
tiles were laid 4.8% more than in 2015. roughly 52% of floor coverings in 2025. Answers from Construction Chemistry
Global tile consumption is expected to rise Always offering the right tile adhesive is Polymer Modification 6
by 5.6% until 2025. Of course, as the use critical for any mortar manufacturer Types of Cementitious Tile Adhesives 7
of tile increases, so does the wanting to participate on these different European Standards Classification 8
demand for tile adhesive, particularly in markets. Products have to be tailored to a Tile Grout Mortars 10 2
cementitious systems, which constitute the number of factors, including the
vast majority of applications. state of technology, the architecture, Advantages of Modern Tile Adhesives
the climate and the processing technol- Cost-Effective Installation 11
ogies in the target market. Improved Adhesion and Flexibility 12
Sustainability and Quality 13
We’re There for You.
Wherever Your Market Is. WACKER Solutions
As a globally active company and a VINNAPAS® Product Classes 14
pioneer in the dry-mix mortar industry, we Technical Service 15
would like to be your reliable part- ner, WACKER ACADEMY 16
developing just the right products for you WACKER at a Glance 17
and growing together in the
process.
VINNAPAS® is a registered
trademark of Wacker Chemie AG.
DRIVEN BY TRENDS:
THE DIVERSE NEW WORLD OF TILES
Modern tiles push traditional tile adhesives to
As design objects, their limits. Tiles with low porosity and a closed
surface – ceramic tiles, for example – do not
tiles are subject to the allow the tile and the tile adhesive to mesh, in
which case the tile will fall when subjected to
changing times. stress or shocks. Large, highly porous tiles
represent a similar scenario: major stress in this
Decorating trends pose case can cause the tile to break. 3

a variety of challenges A Sizable Trend


Large tiles are trending throughout the world – the
standard wall tile in China, for instance, is 80 x
to tile adhesives as well. 80 cm. And king-sized tiles measuring 120 x 260
cm
and just 6 mm thick were presented at the 2018
Cersaie bathroom design exhibition in Bologna.
Traditional Clay and Porcelain tiles Very Ceramic tile
This requires a tile adhesive with very high, uncom- A Variety of Materials Terracotta Tiles Highly smooth; water Very smooth;
porous; water absorption water absorption
promising adhesive strength and a long open time. Whereas traditional tiles were made of clay or absorption 0.5 – 1% 0.5%

These heavy tiles must not slip, and installers need terracotta, the materials used today cover a wide > 10%

to be able to adjust them for a considerable peri- range: from earthenware and ceramic tiles to those
od of time. At the same time, as tile size increases, reinforced with glass fiber or vitrified. That places
so does the risk of breakage. The substrate must new demands on tile adhesives too.
be particularly well prepared and as flat as possi-
ble. And the tile adhesive has to be flexible enough
to absorb shocks, vibrations, and stress arising be- Vitrified Tiles, Earthenware tiles
Mosaic Tiles Porous;
tween the tile and substrate. Smooth; water absorption 3
water absorption 1 – 10%
– 3%
Organic Materials
Modern buildings are frequently either
clad with external thermal insulation
composite systems (EIFS/ETICS) or are
made of wood. If tile is to be laid on
these surfaces, adhesive strength
becomes an issue. Insulation consists
largely of organic material, while tile
adhesives are inorganic. Polymer mod-
ification is the only way of achieving a
reliable bond. The same holds true for
wood, steel or other materials, where- by
the crucial property for a permanent bond

A REASON TO OPTIMIZE: is the flexibility of the adhesive – a


polymer-modified layer of adhesive 4

NEW SUBSTRATES
can absorb stress arising between the
substrate and the tile.

While the quality of the bond formed by a tile


adhesive depends partly on the tile, the substrate is at Bonded on Gypsum Warming Your Feet Tile on Tile
least as important: whereas most tiles used to be laid Gypsum-based building components and Tiles are the flooring of choice for modern Builders are leaving old tiles on the walls
on porous mineral substrates, today’s construction materials are environmentally underfloor heating systems. Because heat more and more often as a way of saving
installers increasingly have to work with gypsum, old friendly to manufacture and can be rapidly causes the substrate and the tile to ex- time, money and resources in renovation
and inexpensively processed. But are pand at different rates, the layer between projects. Tiles make for a nearly smooth,
tiles or even organic materials such as wood or they right for tiles? They are with the right them – the tile adhesive – must be flexible. closed surface that pushes traditional
EIFS/ETICS. These substrates place entirely adhesive: tile adhesives modified with If the adhesive layer were rigid, the tile tile adhesives to their limits. Adhesives
new demands on the tile adhesive. The same holds true, VINNAPAS® yield strong, lasting bonds, would fall off or crack. VINNAPAS® gives modified with VINNAPAS®, however,
incidentally, for underfloor heating systems. even on moving plasterboard. the tile adhesive the flexibility it needs to permanently bond tiles to tiles.
compensate for shear forces.
A VARIETY OF APPLICATIONS:
ENVIRONMENTAL FACTORS
Durable Every Step of the Way
Not All Tile Floors Are In busy locations such as airports, train stations and
other public buildings, tiles have to be particularly
Created Equal resistant to heavy foot traffic: if the tile adhesive is
not flexible enough, the tiles may develop cracks or
Every tiled surface is even break. Polymer-modified tile adhesives absorb
shocks and act as a buffer.
subject to highly specific
conditions arising from Hot, Cold, Damp, Dry …
High humidity, extreme heat or cold, and frequent
how the tile is used, the changes in temperature represent tough challenges
5
loads it must bear or for tile adhesives – both in terms of their processing
characteristics and their longevity. Polymer modification
unique aspects of the allows formulators to adjust adhesives so that they
can be processed no matter how hot or cold it is, can
local climate. Polymer resist extreme temperatures and humidity, and can
stand up to thermal movement without sustaining
modification makes it
damage.
possible to fine-tune
Standing up to Moisture
modern tile adhesives to
Polymers can be added to tile adhesives to make them
the precise application – hydrophobic for use in damp areas and under extremely
humid conditions. Joints have a unique role to play here:
always achieving a long- they have to withstand moisture if tiled surfaces in wet
and damp areas are to remain attractive and robust over
lasting, reliable result. the long term.
POLYMER MODIFICATION: When the mortar sets, the redispersed
polymer powders form a polymer

SOLUTIONS RIGHT OUT OF THE BAG film. This film increases the flexibility,
cohesion and adhesion strength of the
mortar.

Cementitious tile adhesives are by far the most common


tile adhesives in use today. The key characteristics of The polymer in the tile adhesive
these adhesives are that they contain cement and set creates a bond (polymer bridge)
hydraulically with water. between the tile and the polymer-
modified tile adhesive.

Polymer-modified tile adhesives are


generally offered as practical, all-in-one
In many of today’s applications, these traditional
6
dry-mix mortars. In addition to improved
tile adhesives do not adhere to the tile adequately. Reverse side of an earthenware tile: The
adhesion, their deformability has been
Two typical cases here are tiles that are too polymer film sets into the pores
optimized as well, which is why they are
absorbent or too smooth. preventing too much water being
often referred to as flexible adhesives.
absorbed from the tile adhesive.
By limiting the water uptake, the tile
adhesive retains a degree of flexibility
that compensates for any possible
stresses that could cause the tile to
break.
Today’s tile adhesives are upgraded or specially
modified for this reason. Water retention agents such
Reverse side of a porcelain tile:
as methyl cellulose improve wetting, while polymeric
Virtually no pores can be seen.
binders achieve adhesion even on extremely smooth
The polymer film covers the tile and
tiles or substrates.
assures adhesion.
CEMENTITIOUS TILE ADHESIVES:
THREE TYPES SIDE-BY-SIDE

Labor Intensity Labor Intensity Labor Intensity

Thick-Bed Mortar Jobsite Mix Thin-Bed Unmodified Cementitious Thin-Bed Modified Cementitious
• Components: cement, sand, water. Tile Adhesive Tile Adhesive
All of the components are mixed together on site • Components: cement, sand, water retention agent • Components: cement, sand, water retention agent
(methyl
• Thick-bed installation method cellulose, etc.), water. Dry-mix mortar is blended with (methyl cellulose, etc.), polymer, water. 7
• Material consumed: 10 kg/m2 water on site Dry-mix mortar is blended with water on site
• Thin-bed installation method • Thin-bed installation method
• Time required: 1 m2/h
• Material consumed: 3 kg/m2
• Material consumed: 3 kg/m2
• Open time: 5 minutes • Time required: 4 m2/h
• Time required: 4 m2/h • Open time: 20 – 30 minutes
• Suitable for small, porous tiles
• Open time: 5 – 10 minutes • Suitable for all tiles and substrates
• Increased logistical complexity
• Suitable for small and medium-sized earthenware tiles • Simple mixing process means very little variation in
• Mixing errors can result in variable quality
quality
• Cement is often added to improve adhesion;
• Formulations sag when applied to walls
mixing ratio can cause quality to vary • Tiles can be laid on a wall from top to bottom;
no spacers required
Open time: Open time:
5 – 10 min. Open time:
5 min.
20 – 30 min.
EUROPEAN STANDARDS
CLASSIFICATION
PERFORMANCE Performance Classes
Based on tensile adhesive strength as a function of storage conditions
• Dry storage

CLASSES • Immersion in water


• Heat-conditioning storage
• Freeze-thaw cycles

Class C1 Class C2
Minimum tensile adhesive strength Minimum tensile adhesive strength
value of 0.5 N/mm² after all tests value of 1.0 N/mm² after all tests
EN 12004-1:2017-05 classifies ceramic tile adhesives in terms of
performance in order to ensure comparability and to make it easier to C1 tile adhesives are intended for C2 tile adhesives are recommended
8
simple applications for large tiles and for floors subjected
choose. The standard draws distinctions between three categories
to relatively heavy traffic
of tile adhesives, two performance classes and a number of additional Suitable Substrates
properties. Polymer modification is the only way to meet the demands • Rigid surfaces Suitable Substrates
on Class C2 cementitious tile adhesives. • Sufficiently hardened screeds • Rigid and smooth surfaces
• Concrete • Concrete
• Masonry • Masonry
• Flat substrates • Plasterboard
• External surfaces
Suitable Tile Types • Underfloor heating
• Earthenware tiles
• Stoneware tiles Suitable Tile Types
• Small tiles • Ceramic and stoneware tiles
• Large tiles
EUROPEAN STANDARDS
CLASSIFICATION
ADDITIONAL
PROPERTIES
DIN EN 12004-1:2017-05 also names additional properties that are
helpful in certain applications. The standard establishes test mechanisms and
minimum values for each property. Polymer modification is generally the only
way of achieving these values. For applications like these,
VINNAPAS® dispersible polymer powders are offered in corresponding
product groups (see page 14).

Type S Tile Adhesives Type F Tile Adhesives Type E Tile Adhesives Type T Tile Adhesives 9
Can absorb movement between the Cure quickly and are ready for foot Have an extended open time, i.e., Make it possible to lay tiles on walls
tile and the substrate traffic in a short time. they take longer to cure. without the use of spacers.

Applications Applications Applications Applications


• Underfloor heating and large tiles • Projects with major time constraints • Highly complex patterns • All vertical installation work
• Ceramic tiles that absorb very little water • Repair work • Installation work in direct sunlight or wind • Large and heavy tiles
• Substrates subjected to dynamic loads • Public areas that cannot be blocked off for long • Large wall and floor surfaces • Building exteriors
• Flexible, suspended designs • Very porous substrate
• Waterproofing membranes, balconies and terraces
AN IMPORTANT Important properties of grout mortars that can be
improved through modification with VINNEPAS : ®

DETAIL: GROUT Abrasion Resistance


High-traffic areas, mechanical cleaning and

MORTARS mechanical stress caused by chairs or rollers are


placing new demands on floors.

Compressive and Flexural Strength


Joints must be able to withstand mechanical stress.

Shrinkage
Grout mortars must not shrink when they cure, as
this could produce cracks or gaps that would allow 10
water to penetrate.

Water Absorption
To prevent moisture from being channeled into the
floor, grouts should absorb as little water as possible.
VINNAPAS® H specialty grades are especially
Joints serve aesthetic and functional purposes: they divide
suitable here.
surfaces into visually distinct areas and absorb stress
between tiles. At the same time, they can also result in
Deformability
weakness, such as when they allow dirt or
When tiles move for reasons such as changes in
water to penetrate the substrate. This is why Europe- an
the shape of the substrate, the grout mortar has to move
standards, specifically EN 13888 and EN 12808-3, define
along with them.
quality criteria for cementitious grouts.
THINNER, FASTER,
SMARTER:
COMPARING INSTALL The Classic:
The Thick-Bed Method
ATION TECHNIQUES The thick-bed method was the state of the art for
thousands of years. The first step is to moisten the
tiles and the substrate with water, followed by the
application of a layer of mortar 15 to 30 mm thick
The choice of installation on the floor or (if laying on a wall) on the back of
technique depends on building the tile. The tile is then pressed onto the substrate
traditions, climate conditions and tamped into the mortar bed. The method
requires experienced craftsmen and consumes
and the tile adhesive used. The
large quantities of tile adhesive.
thin-bed technique is generally 11
found to be faster and more The Revolutionary:
efficient than the thick-bed
The Thin-Bed Method
technique, and, because it uses less material, it conserves The invention of modern tile adhesives is what
resources as well. With the right has made the thin-bed method possible. The
polymeric binder, formulations can be adjusted in such a way that the technique involves the use of a notched trowel for
applying tile adhesives modified with VINNAPAS®
thin-bed technique can be used for laying even challenging tiles in hot
onto extensive areas of substrate. The tiles are
climates, in direct sunlight and on a wide array of substrates. then slid gently into place to produce a uniform
adhesive bed 2 to 4 mm thick. Installation with
this method is significantly faster and reduces
material consumption to a third of past levels.
VINNAPAS® polymers
IMPROVED PROPERTIES:
improve two key properties

of tile adhesives: adhesion


ADHESION AND 12

and flexibility. The result FLEXIBILITY


Impact Strength Withstands Shear Forces
Polymer modification improves the Polymer-modified tile adhesives
is an increase in the flexibility and/or deformability of a can also compensate for the stress
tile adhesive a great deal. that arises from changes in the
mechanical strength and This allows the tile adhesive to shape of the substrate or
act as an elastic buffer that when the tiles and substrate expand in
longevity of tiled surfaces. effectively cushions shocks, response to temperature.
preventing damage to the tiles. Hammer Resistant
Drop a tool or other heavy object? Polymer-
modified tile adhesives remain flexible and
cushion impacts and shocks – and keep
the tile intact. The full video may be found
here …
SUSTAINABILIT
Y PAYS OFF Environmental Advantages of
VINNAPAS® Polymer Modification:

FOR EVERYONE Material consumption reduced


by 2/3 compared to traditional
adhesives.
Lower rates of material
consumption, longer renovation Fewer CO2 emissions generated by
cycles: quality construction is production and transport.
worth it. For the environment
too. VINNAPAS® dispersible More economical use of
polymer powders are unusually resourcesthanks to lower sand
efficient: the addition of content. 13
even just a small quantity
can significantly improve Less waste
quality in target thanks to simple paper packaging.
applications. Sustainability is one of WACKER’s
corporate objectives. We continually
Longer product life
optimize our production in terms of
energy and resource consumption.
and good, lasting results.
This applies to all of our sites throughout
the world, where we manufacture Improved quality
according to exactly the same
of life thanks to a healthy indoor
quality criteria. We follow the cradle-
to-grave principle when evaluating climate.
and developing the VINNAPAS®
portfolio – good examples of this Ideal for renovations
are our VAE-based, low-VOC grades
(installing tile on tile, etc.).
produced without the use of APEOs.
We are also working on a portfolio that
uses certified, renewable raw materials.
VINNAPAS® DISPERSIBLE POLYMER POWDERS
BEST IN CLASS SINCE 1955
WACKER was one of the first companies to manufacture dispersible polymer powders on an industrial scale. To this
day, our VINNAPAS® products are the technology and market leaders for modifying dry-mix mortars. We will keep
Over 50 years of development:
developing our portfolio – we’d be happy to work with you to meet your specific needs. Milestones of VINNAPAS® history
Talk to us!

To simplify your choice, we have summarized our


VINNAPAS® grades into six product classes.

VINNAPAS® H Class –
Excellent Hydrophobicity VINNAPAS® F Class – 14
Ensures remarkable hydrophobic Superior Flow Properties
properties in all kinds of plasters, Ensures outstanding flow properties
VINNAPAS E Class –
®
grout mortars and external thermal without the addition of synthetic
Improved Properties insulation composite systems superplasticizers or casein.
Improves properties in many applica- (ETICS/EIFS). A 2-in-1 solution suitable for self-
tions, making products easier to pro- leveling compounds and troweling
cess, more adhesive and more water compounds requiring fast processing.
resistant.

VINNAPAS® N Class –
Rheologically Neutral
Ensures a high level of
VINNAPAS® L Class –
formulation flexibility
VINNAPAS® T Class – Optimized Leveling
and a diverse range of
Highly Thixotropic Ensures smooth surfaces with
applications.
Ensures excellent thixotropic outstanding leveling properties;
properties, as required in thixo- suitable for self-leveling flooring
tropic tile adhesives and smooth- compounds, etc.
ing and/or leveling compounds.
Formulating a polymer-modified tile adhesive can be a
complex process – there is no universal formulation.
Cement and sand vary from one place to another, as
do processing conditions, substrates and tiles. Regional
market circumstances play a role as well: Which price
segment is right for the finished tile adhesive? Are there any 15
standards and laws that play a role?
In order to work with customers on optimizing products for

TECHNICAL CENTERS: local demands, WACKER took an early lead in


establishing technical centers (TCs) all over the world.

GLOBAL SUPPORT
Experts at our centers will provide you with the advice and
support you need to succeed in your market.

Knowing What a Product Can Do


Testing customer formulations according to established
standards provides reliable information on product
performance. Parameters we test include tensile adhesive
strenghth, open time and heat ageing (according to
EN 12004-1:2017), and the resistance to abrasion as well
as the compressive and flexural strenght of grout mortars
(12808-2 and EN 12808-3, respectively).
THE WACKER
ACADEMY
CONNECTING THE BEST
The global forum for learners, networkers, creators and discoverers
WACKER ACADEMY offers cutting-edge expertise for regional markets.
Participants can meet and swap experiences with colleagues from similar areas –
at 14 locations around the world.

16
CRE ATING TOMORROW’ S SOLUTIONS Silicones and Polymers
3,200 specialty products from organic
and inorganic chemistry

A Diverse Array of Products Global Knowledge And most importantly: we are there Global Market Leader
In dispersions and dispersible polymer
for Growing Markets for Local Markets wherever you need us – worldwide.
powders based on vinyl acetate-ethylene
Our product portfolio ranges from When you work with Our local specialists know your (VAE), in building-protection silicones
silicones, binders and polymer- WACKER, you markets and speak your language. and in the production of cyclodextrin
ic additives all the way up to have 100 years of chemistry expertise at Working with them, you will find and cystein.
bioengi- your disposal, with access to the research innovative solutions that win over
neered pharmaceutical actives. Round- ing findings and best practices of our experts your customers and make you more Globally Active
these out is hyperpure silicon for throughout the world. competitive. • Sites worldwide 17
semiconductors and solar applications. Our knowledge base consists of a • Headquartered in Munich
• 26 production sites in Europe,
Innovations that Improve Quality network of 23 technical centers, Follow us:
Asia and the Americas
of Life 14 training centers and our basic Find us on LinkedIn, YouTube and • 23 technical centers
As a technology leader focusing on research center. Twitter, and we’ll keep you up to date on • 14 WACKER ACADEMY training

sustainability, WACKER promotes the latest and discuss current centers


• 52 sales offices
products and ideas that offer consider able issues with you.
value-added potential to ensure
that current and future generations Employees: 14,400
enjoy a better quality of life, based on
energy efficiency and protection of the
climate and environment. Total Sales
All figures are based on fiscal 2021. € 6.21 billion
18

Wacker Chemie AG The data presented in this medium are in accordance with the present state of our knowledge but do not absolve the user from

7694e/12.22 replaces 7694e/05.22


Hanns-Seidel-Platz 4 carefully checking all supplies immediately on receipt. We reserve the right to alter product constants within the scope of technical
81737 Munich, Germany progress or new developments. The recommendations made in this medium should be checked by preliminary trials because of
conditions during processing over which we have no control, especially where other
www.wacker.com/contact companies raw materials are also being used. The information provided by us does not absolve the user from the obligation
www.wacker.com/vinnapas of investigating the possibility of infringement of third parties’ rights and, if necessary, clarifying the position. Recommendations for use do
not constitute a warranty, either wexpress or implied, of the fitness or suitability of the product for a particular purpose.
www.wacker.com

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