Lecture One of Analytical Chemistry 1

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Classification of Chemistry

Biochemistry
Physical General
Chemistry Chemistry

Chemistry

Organic Analytical
Chemistry Chemistry

Inorganic
Chemistry
Contents Analytical Chemistry 1
1- Introduction to analytical chemistry:
- Definitions, classifications of analytical techniques, Qualitative and

quantitative analysis.
2-Basic tools of analytical chemistry:
- Molecular mass, moles and equivalents.
-Methods of expressing the concentrations( molarity normality,
weight /weight , volume/volume and weight/ volume ratios, ppm
and ppb.
- Dilution of solutions.
3- Volumetric methods analysis: Definitions, tools, types and
4- Acid – base titrations in aqueous medium :
-Arhenius, Pronsted and Lewise definitions.
-PH of acids, base and salt solutions.
-- Buffer solutions.
- Acid- base indicators.
5- Titration curves
2- Gravimetric analysis:
-Chemical precipitation method
-- controling partical size
-- solubility product
Analytical chemistry

Analytical Chemistry Is the branch of chemistry that deals with

the analysis of substances present in the sample qualitatively and

quantitatively. In order to accomplish this analysis we must know the

physical and chemical properties of these substances.

In other words analytical chemistry deals with the separation,

Identification and determination of substances in a sample. It also

includes coverage of chemical equilibrium and statistical treatment of

data
Analytical chemistry broken down into two general areas
: of analysis
Qualitative and Quantitative analysis and each one of
these two types can be either classical or instrumental as
.we will see

Analytical chemistry

Classical Analysis Instrumental Analysis


Classical Analysis

Qualitative Analysis Quantitative Analysis

Volumetric Gravimetric
Solid Tests Wet tests Analysis analysis
Solid tests

colour Smell of
Colour of the original Solubility
Colour change in
solution mixture
heating
Wet tests

Acidic Basic
Radicals Radicals
Volumetric analysis
In volumetric analysis, a chemical called a titrant is added
to a solution of unknown concentration called analyte
( titrand ) together with an indicator that will mark the
time at which all of the analyte has been reacted .At this
point, the analyst can determine how much analyte is
originally present from the amount of titrant added. Some
time called titrimetric analysis because all experiments
under this type of analysis are completed by titration
reactions. .
Unknown
concentration solution

Titrand
Standard
solution

Titrant

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