Product training

Table of contents

1 silicone oil

2 Silicone oil secondary processed products

3 Applications in different industries

1

Silicone raw materials

natural gas charcoal

Chlorine

Silica
Methyl
chloride
powder

Methanol

hydrochloric acid silica

1

Deeply processed products

Silicone raw materials siicone monomers Silicone intermediates

107 glue RTV

Ring-opening polymerization polymerization dehydration

hydrolysis

DMC D4 Silicone Filler + adhesive

Silicon metal
catalyst Raw rubber HTV

synthesis Methyl chloride

Silane Filler + vulcanizing agent

Methyl chloride Silicone oil

Hydrolysis, polymerization, cross-linking

Silicone

Alkoxylation
A silane coupling agent

by-product
Vapor phase silica
1

R
X

The difference between R and X leads to a variety of silicone oils

1

Silicone oil is usually divided into two categories: general silicone oil and modified silicone oil.

Modified silicone oil series

General silicone oil series

reactive silicone oil Non-reactive silicone oil

•Amino-modified silicone oil

•Epoxy silicone oil • Polyether modified silicone oil

•Methyl silicone oil
• Carboxyl-modified silicone oil - Alkyl modified silicone oil
• Methyl hydrogen silicone oil
•Alcohol-modified silicone oil •Higher fatty acid ester modified silicone oil
-Methyl phenyl silicone oil
•Methacryloyl-modified silicone oil •Higher alkoxy modified silicone oil
•Hydroxy silicone oil (107 glue)
• Mercapto-modified silicone oil •Higher fatty acid modified silicone oil
•Vinyl silicone oil
•Phenol-based modified silicone oil •Fluorocarbon-based modified silicone oil

•Methyl styrene silicone oil

 Basic properties of silicone oil

number Basic features Specific performance

1 Good heat resistance -Si-O-Si- bond energy is 108k cal/mol and can be used for a long time at -60~220ÿ; after the introduction of phenyl group, the low and high temperature resistance is
improved

2 Good Oxidation stability and weather resistance Silicone oil only begins to be oxidized at 200°C. Adding antioxidants can significantly extend the high-temperature gelation time of silicone
oil.

It has good dielectric properties and its electrical properties change very little with changes in temperature and cycle number. For example, the dielectric constant is 2.76; the volume resistivity varies
3 Good electrical insulation with
temperature rises and falls

The main chain is composed of polar silicon-oxygen chains, and the side chains are non-polar alkyl groups oriented outward, effectively preventing the entry of water molecules. Silicone oil to water
4. Good hydrophobicity interface
Tension is about 42 dynes/cm

5. Small viscosity-temperature coefficient It is the material with the best viscosity-temperature characteristics among various liquid lubricants.

The viscosity will change greatly when the pressure increases, but it is lower than that of ordinary mineral oil. For example, at 2000 atmospheric pressure, the viscosity of oil increases by 50 to 5000
6 High compression resistance times.
The viscosity of 100c s silicone oil can only be increased by 10 times.

Surface tension is generally 20.8~21.1 dynes/cm; water is 72 dynes/cm, ethanol is 22.3 dynes/cm, and mineral oil is 30~35
7 Low surface tension dynes/cm.
centimeter. Has good defoaming properties, isolation properties from other materials and lubrication properties

No adverse reactions to rubber, plastics, coatings, etc.; it is a Newtonian fluid with little viscosity change under high shear; introduce chlorophenyl or replace it with trifluoropropyl
8. Goodlubricity
Methyl, which improves lubrication properties

9 Non-toxic,odorless andphysiologicallyinert It is one of the most inactive compounds known and has no rejection reaction with animal
bodies.

The silicon-oxygen bond is not resistant to strong acid and alkali; insoluble in water or aqueous solvents; aromatic, aliphatic and chlorinated hydrocarbons are the best solvents; also soluble in
10 Chemical Properties ether,
Esters, higher alcohols and ketones
1

Characteristics and uses of silicone oil

Types of organic base Silicone oil varieties feature use

Electrical insulation materials, heat transfer media, demoulding

Surface properties Electrical insulation Heat resistance
Methyl Dimethyl silicone oil agents, cosmetic raw materials, brightener raw materials
Other features
Materials, defoaming agents, fiber oil agents, etc.

Cosmetic raw materials, heat carrier, polymerization

Methyl, phenyl Methylphenyl silicone oil Heat resistance and cold resistance Compatibility
chemical additives

Methyl, hydrogen atom Methyl hydrogen silicone oil Reactivity Hydrophobic agent, waterproof agent

Water solubility, water dispersibility, surface activity Foam stabilizer, antistatic, defoaming agent,
Polyether-based polyether silicone oil
sex Leveling agents, cosmetic raw materials

Lubricity, mold release, cosmetics

Long chain alkyl alkyl silicone oil Lubricity, paintable release properties
material

Fabric smoothing softener, plastic modification

Epoxy hydrocarbon based epoxy silicone oil Reactivity, smoothness, softness
agent
1

Comparison table of methyl silicone oil viscosity and weight average molecular weight

Viscosity cst, Viscosity cst,

weight average Weight average
Similar viscosity liquid
25°C molecular weight Similarviscosityliquid
25°C molecular weight

0.65 162 water 10,000 62,700 syrup

5.0 770 water 30,000 91,7000 Honey

10 1,250 60,000 116,500 hot asphalt

20 2,000 edibleoil 100,000 139,000

50 3,780 300,000 204,000

100 5,970 paint 600,000 260,000 milkshake

350 13,650 mineral oil 1,000,000 308,000

500 17,250 ketchup 2,500,000 423,000

1,000 28,000 engine oil 4,000,000 460,000 jelly

5,000 49,350 maltose 20,000,000 550,000 putty

1

Comparison table of weight average molecular weight of 107 gel

Viscosity cst, 25 °C Weight average molecular weight Viscosity cst, 25°C weight average molecular weight

1000 25,000 1,000,000 200,000

5000 50,000 5,000,000 500,000

10000 63,000 11,000,000 800,000

30000 91,700 15,000,000 900,000

80000 116,500 20,000,000 1,000,000

100,000 140,000
 2

Secondary processed products of silicone oil

 2

Silicone grease silicone paste

2

Types and properties of base oil

Type of base oil Performance and use Type of base oil Performance and use

Dimethicone Lightly lubricates and seals long chain alkyl silicone oil Plastic and steel-steel lubrication

Low phenyl silicone oil For low temperature lubrication Fluorocarbon-based silicone oil high temperature resistance and chemical lubrication

Medium and high phenyl silicone oil For high temperature lubrication Amino silicone oil Ceramic lubrication
 2

lotion

Oil
Oil droplets are surrounded by molecules

such as emulsifiers and dispersed in water

Water

Hydrophilic group

lipophilic group
2

(virtual capsule)

(oil droplets)

(emulsifier molecule)

(lipophilic group)
(Hydrophilic group)

Particle size, m color

50-1 cream

1.0-0.1 blue white

0.1-0.05 translucent

<0.05 transparent
 2

Main types of defoaming agents

Main types of defoaming agents

Alkali-resistant defoaming agent Acid-resistant defoaming agent Paint defoaming agent Papermaking defoaming agent

Cement mortar defoaming agent Oilfield industrial defoaming agent Cleaning defoaming agent High-efficiency fermentation defoaming agent

Water treatment defoamer For High temperature lubrication Cationic system defoamer High viscosity foam defoamer
 2

Main types of release agents

Main types of release agents

form Application areas

Oil type Used for demoulding and anti-adhesive treatment situations where water or solvent is present. Apply directly.

Solvent-based solvents are used for shell mold casting, die-casting, and molding of rubber and plastic
products.

Emulsion type Latex tire industry

It is suitable for high-temperature and high-pressure forming, especially for the forming of curved
rubber
Ointment type hoses; it can also be used as a release agent for the spinneret holes during the melt spinning process
of
polyester, nylon and other synthetic fibers.

Easy to use, mainly used for molding thermoplastics such as PE, PP, ABS, PS, etc., as well as anti-sticking
Aerosol type
of synthetic fiber melt spinning spinnerets.

Powder type Powder coating

 3

Applications in different industries

Fiber·Textile Industry Daily chemical industry

Waterproofing agent for umbrellas, raincoats, tents, Wash and conditioner (shampoo, hair dye, conditioner,

bags, leather, leather shoes, etc. mousse, hair oil, gel, etc.)

Fiber treatment agent (spinning oil agent) Skin care agents (hand cream, lotion, etc.)

Finishing agent after printing and dyeing (soft, smooth, hydrophilic, anti- Makeup products (foundation, powder, lipstick, etc.)

wrinkle, anti-pilling, fluffy, crisp)

Toothpaste (anti-caries, anti-allergy)
Fabric finishing agent (soft, smooth, hydrophilic, anti-wrinkle, anti-pilling,

waterproof, fluffy, crisp) Low foaming detergent (washing powder, laundry detergent)

Printing and dyeing defoaming agent fabric softener

Antifouling treatment agent Cleaning polish (furniture, cars, floors, tiles)

Antibacterial, anti-mildew and anti-odor treatment agent

High-speed polyester sewing thread (lubrication, high temperature resistance, anti-

static
3

Light industry·Chemical industry Rubber and plastic industry

Paint leveling agent, defoaming agent Release agent for rubber, plastic and other molding processing

Defoaming in fermentation processes, polymerization processes, etc. Through internally added improvers (lubrication, toughening, anti-scratch, flame

retardant, etc.)

Leather treatment: soft, waterproof

Polyurethane foam stabilizer

Papermaking and paper products industry

Electrical and electronic industry Coating agents for various release papers

Foam inhibitor in papermaking process

Heat resistance, stable electrical characteristics

Softener for facial tissues

Transformer insulation medium

Paper waterproofing agent

Lubrication of accessory sleeves

polish for printed matter

Thermal conductive media and damping materials for instrumentation and electrical appliances
3

Food and agricultural industry Machinery and Automotive Industry

Release agent for bread, cakes, biscuits, candies, etc. Lubricants for mechanical equipment

Release agents for machining processes

Food defoaming agent for tofu, fried dough sticks, French fries and other foods
Car brake fluid, clutch working fluid

Lubricants for food manufacturing equipment

Anti-shock and damping oil for instruments and buffers

Pesticide spreading agent, plant growth promoter, insecticide

Compressor working oil

Waterproofing agent for rice fields and ditches

Diffusion pump vacuum oil

Breathable film for grain storage, anti-fog treatment agent for agricultural film
machining cutting fluid
3

Medical industry National defense industry

Hydrophobic agent, condensing agent, antistatic agent, lubricant, release instrument oil

agent, defoaming agent

Gyro oil, damping oil, sensor oil, gyro instrument oil

Family planning materials (condom lubrication)

Simethicone (used for gastrointestinal flatulence, gastroscopy, colonoscopy) shock absorber fluid

brake fluid

Silicone oil filling after vitrectomy (for retinal detachment)

heat transfer oil

Methyl silicone colic relief drops (methyl silicone oil emulsion)

Insulating cooling oil, buffer oil, transformer oil, insulating

Lubrication of needle tips and inner wall processing of syringes for drug injection impregnating oil and heat sink oil
Thanks!