ITM Vocational University, Vadodara

Infrared
Spectroscopy

Faculty’s Name – Pavan Karkare

Batch Name – B.Sc(IC)_Batch 2019-22
Session No – I

Infrared Spectroscopy
03/18/2
 ITM Vocational University, Vadodara

Learning Outcomes

 Infrared spectroscopic instrumentation.

 The working knowledge of spectroscopic
instruments.
 Additionally, it prepares graduates with knowledge
and experience in analytical chemistry for industrial
applications, laboratory analysis and research
studies.

Infrared Spectroscopy
03/18/2
 ITM Vocational University, Vadodara

Introduction

 For all the compounds having covalent bond

 The absorption of infrared radiations can be
expressed either in terms of wavelength (λ) or in
wave number (v).
 In terms of wavelength (λ) the IR region lies
between 2.5 μm to 25 μm ( 1 μm = 10⁻4 cm , 1nm
= 10⁻⁹cm ).

Infrared Spectroscopy
03/18/2
 ITM Vocational University, Vadodara

Near IR IR Far IR

14000 cm¯¹ 4000 cm¯¹ 600 cm¯¹ 200 cm¯¹

 The relationship between wavelength and wave number
is as follows:

1
Wave number v =
Wavelength (cm)

Thus it has unit cm¯¹.

Operating Systems
03/18/2
 ITM Vocational University, Vadodara

EMR Spectrum

Operating Systems
03/18/2
 ITM Vocational University, Vadodara

Principal

 “vibrational-rotational spectroscopy”
 Covalent Bond
 In plane - Out plane
 Rotaion of Bond & Streching of Bond
 Change of Bond length/ Bond angle

Infrared Spectroscopy
03/18/2
 ITM Vocational University, Vadodara

References

 G. H. Jeffery, J. Bassett, J. Mendham and R. C. Denney, Vogel’s

textbook of qualitative chemical analysis, John Wiley & Sons, 1989.
 H. H. Willard, L. L. Merritt, J. Dean and F. A. Settoe, Instrumental
methods of analysis, 7th Ed. Wadsworth publishing company Ltd.,
Belmont, USA, 1988.
 G. D. Christian, Analytical Chemistry, 6th Ed. John Wiley & Sons, New
York, 2004.
 S. M. Khopkar, Basic concepts of Analytical Chemistry, New age,
international publisher, 2009.
 P. S. Kalsi, Spectroscopy of organic compound, New Age international
publishers. 6. R. M. Silverstain, G. C. Bassler and T. C. Morrill,
Spectroscopic identification of organic compounds, John Wiley,
1991.

Infrared Spectroscopy
03/18/2
 ITM Vocational University, Vadodara

Infrared Spectroscopy
03/18/2