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    Kelly da Rosa
    The document presents the results of an electrochemical characterization study. It includes: 1) Graphs showing the relationship between peak current and scan rate for the redox reaction of Fe(CN)6-3/-4, demonstrating a linear relationship. 2) Graphs of the peak potential versus log of the scan rate, again demonstrating a linear relationship consistent with a diffusion-controlled process. 3) Cyclic voltammograms of Fe(CN)6-3/-4 at different scan rates. 4) Additional results characterizing caffeine using a modified glassy carbon electrode, including determination of the linear range and limits of detection.

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    Result A Dos

    Uploaded by

    Kelly da Rosa
    4 views8 pages
    The document presents the results of an electrochemical characterization study. It includes: 1) Graphs showing the relationship between peak current and scan rate for the redox reaction of Fe(CN)6-3/-4, demonstrating a linear relationship. 2) Graphs of the peak potential versus log of the scan rate, again demonstrating a linear relationship consistent with a diffusion-controlled process. 3) Cyclic voltammograms of Fe(CN)6-3/-4 at different scan rates. 4) Additional results characterizing caffeine using a modified glassy carbon electrode, including determination of the linear range and limits of detection.

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    Result a Dos

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    The document presents the results of an electrochemical characterization study. It includes: 1) Graphs showing the relationship between peak current and scan rate for the redox reaction of Fe(CN)6-3/-4, demonstrating a linear relationship. 2) Graphs of the peak potential versus log of the scan rate, again demonstrating a linear relationship consistent with a diffusion-controlled process. 3) Cyclic voltammograms of Fe(CN)6-3/-4 at different scan rates. 4) Additional results characterizing caffeine using a modified glassy carbon electrode, including determination of the linear range and limits of detection.

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    4 views8 pages

    Result A Dos

    Uploaded by

    Kelly da Rosa
    The document presents the results of an electrochemical characterization study. It includes: 1) Graphs showing the relationship between peak current and scan rate for the redox reaction of Fe(CN)6-3/-4, demonstrating a linear relationship. 2) Graphs of the peak potential versus log of the scan rate, again demonstrating a linear relationship consistent with a diffusion-controlled process. 3) Cyclic voltammograms of Fe(CN)6-3/-4 at different scan rates. 4) Additional results characterizing caffeine using a modified glassy carbon electrode, including determination of the linear range and limits of detection.

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    of 8

    RESULTADOS

    Aluna: KELLY DA ROSA


    Orientadora: CRISTIANE LUISA JOST
    Co-orientador: ADRIANO LIMA
    CARACTERIZAÇÃO ELETROQUÍMICA
    GCE
    SOLUÇÃO DE K4(Fe(CN)6)(II) /(III) – 5 mmol KCl 0,1 mol.L-1
    90 90

    80 80

    70 70

    ipa / mA
    ipa / mA

    60 60 Equation y = a + b*x
    Plot B
    Equation y = a + b*x
    Weight No Weighting
    Plot B
    Intercept 40,73007 ± 2,73665
    50 Weight No Weighting 50
    Slope 538,83879 ± 44,10507
    Intercept 17,53914 ± 2,00309
    235,11842 ± 8,54121 Residual Sum of Squares 128,38697
    Slope
    Residual Sum of Squares 26,36578 Pearson's r 0,97423
    40 Pearson's r 0,99476 40 R-Square (COD) 0,94913
    R-Square (COD) 0,98955 Adj. R-Square 0,94277
    Adj. R-Square 0,98825

    30 30
    0,10 0,15 0,20 0,25 0,30 0,35 0,00 0,02 0,04 0,06 0,08 0,10

    u 1/2
    / (V s ) -1 1/2 u / V s-1
    2,00
    Equation y = a + b*x
    Equation y = a + b*x
    B
    90 Plot B
    Plot
    1,95 No Weighting Weight No Weighting
    Weight
    Intercept 140,57187 ± 3,01787
    Intercept 2,32689 ± 0,01486
    Slope 52,23544 ± 2,19077
    1,90 Slope 0,36646 ± 0,01078
    80 Residual Sum of Squares 35,02118
    Residual Sum of Squares 8,48595E-4
    Pearson's r 0,99304
    Pearson's r 0,99655
    R-Square (COD) 0,98612
    1,85 R-Square (COD) 0,99312
    Adj. R-Square 0,98439
    Adj. R-Square 0,99226 70
    log ipa / mA

    ipa / mA
    1,80
    60
    1,75

    1,70 50

    1,65
    40
    1,60

    30
    1,55 -2,0 -1,8 -1,6 -1,4 -1,2 -1,0
    -2,0 -1,8 -1,6 -1,4 -1,2 -1,0
    log u log u
    100
    0,35
    80

    60
    0,30
    40

    Ep vs. Ag/AgCl / V
    20
    0,25
    Epa GCE
    I/mA

    0
    Ipa
    Epc GCE
    Ipc
    -20 0,20

    -40
    0,15
    -60

    -80
    0,10
    0,10 0,15 0,20 0,25 0,30 0,35 -2,2 -2,0 -1,8 -1,6 -1,4 -1,2 -1,0 -0,8

    u1/2/(Vs-1)1/2 log (v/Vs-1)


    100

    Current (µA) 50

    -50

    -100

    -150

    -0,2 0,0 0,2 0,4 0,6


    Potential (V)
    TESTE CAFEÍNA CGE – MODIFICADO
    OURO
    Determinação da faixa de trabalho da cafeína
    5
    4

    30,8 mmol.L-1 3

    ipa / mA
    i / mA

    2
    2

    1
    1
    0,7 mmol.L-1
    0
    0

    0,9 1,0 1,1 1,2 1,3 1,4 1,5 1,6 1,7 1,8 0 5 10 15 20 25 30 35

    E vs Ag / AgCl / V [MEL] / mmol.L-1


    TESTE CAFEÍNA CGE – MODIFICADO
    OURO
    Faixa Linear
    2,0 de Trabalho
    Equation y = a + b*x
    1,8 Plot Mean
    Weight No Weighting
    Intercept -0,70207 ± 0,10058
    1,6 Slope 0,12433 ± 0,00691
    Residual Sum of Squares 0,01124
    1,4 Pearson's r 0,99539
    R-Square (COD) 0,99081
    Adj. R-Square 0,98775
    1,2
    ip / mA

    1,0

    0,8

    0,6

    0,4

    0,2
    8 10 12 14 16 18 20
    [MEL] / mmol.L-1
    TESTE CAFEÍNA CGE – MODIFICADO
    OURO
    A Título de Curiosidade – Faixa Exponencial de Trabalho

    1
    ipa / mA

    0,1

    0,01
    1 10
    [MEL] / mmol.L-1

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