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Neax Chapter 3 Full
Neax Chapter 3 Full
Second law
Again, entropy is state function. It does not care about the path
But, the total change in entropy depend on the how expansion take
place
For example : in any process, the heat will transfer to the
surrounding (dqsur = - dq). For reversible changes,
The Second law : spontaneous
Entropy of process
expansion
ΔStot = 0 = ΔSsys + ΔSsurr
Phase transformation
Heat at constant pressure (q = H)
The Second law : spontaneous
Entropy of process
expansion
ΔStot = 0 = ΔSsys + ΔSsurr
Phase transformation
Heat at constant pressure (q = H)
The Second law : spontaneous
Entropy of process
Heating
The Second law : spontaneous
To be concluded in the second law
Entropy is measurement of spontanity
Entropy plays important role in thermodynamics
We will see at the third law of thermodynamics
The Third Law : “calmness”
Third law
Discuss about the motion at 0 K
Maximum work
The Third Law : “calmness”
Third law
Back to entropy
‘The entropy of all perfect crystalline substances is
zero at T = 0’
Why ? At 0 K, everything is perfectly ordered, only
one way of arrangement (W=1)
At 0 K, entropy is entropy
The Third Law : “calmness”
Third law
At standard temperature entropy is standard
entropy
Standard entropy reaction
The Third Law : “calmness”
Third law
How to express the direction of changes to another
thermodynamics parameters
Automatically taking entropy into account
Claysius inequality
‘if a system in equilibrium with the surrounding with
temperature, T and then a change is occurred …
The Third Law : “calmness”
Claysius inequality
Constant volume or pressure
In constant volume
Non expansion work
Q = U
The Third Law : “calmness”
Claysius inequality
Constant pressure
Q=H
The Third Law : “calmness”
Claysius inequality
We see, there are two forms
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