Reaction of inorganic

compounds

Jerry

1
Fe is acid
3+

2
Hydrolysis
Hydrolysis reaction

3
4
5
6
Amphoteric hydroxides

Amphoteric means showing both acidic and basic properties. Aluminium

hydroxide is an example of this - it will react with both acids and bases.

7
Ligand substitution reactions
Water replaced by NH3

Because NH3, and H20 ligands are similar in size and both are uncharged,
ligand exchange occurs without a change in charge or co-ordination
number.
Ammonia is a better ligand than water.

8
Copper
Change in ligand

9
Shape of [CuCl4] 2-

10
Chelation

11
12
13
Exercice

14
Enthalpy in the solution

15
Lattice enthalpies and bonding

This distortion means there are more electrons than expected concentrated between the Zn
and Se nuclei, and represents a degree of electron sharing or covalency which accounts for
the lattice enthalpy discrepancy (difference). The Se2- ion is said to be polarized.

16
Why do chemical reactions take place
Feasible or spontaneous

Definition: Describe reactions which could take place of their own accord.

Entropy or randomness

系统的混乱程度

17
The Gibbs free energy change
two factors govern the feasibility of a chemical reaction

the enthalpy change 系统倾向于能量最底

the entropy change 系统倾向于更混乱

Gibbs free energy

G positive, not feasible

G negative, feasible

18
Thank you

19