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HPPT 6
HPPT 6
water
Physical
Chemical
Bacteriological
Physical quality
• Colour
• Odor
• Taste
• Turbidity
Bacteriological quality
• Bacteriological water quality is defined in
terms of the absence or presence of indicator
organisms. Drinking water does not cause an
infectious disease if it is free from indicator
organisms
• Escherichia coli
• Organic matter:
• BOD: Amount of oxygen required to cause
biological decomposition of organic matter.
• Organic matter:
• BOD: Amount of oxygen required to cause
biological decomposition of organic matter.
• 0-75 Soft
• 75-150 Mod hard
• 150-300-Hard
• >300 Very hard
Ca = Ct V t M
Va
• where Ca is the concentration of the analyte,
typically in molarity; Ct is the concentration of
the titrant, typically in molarity; Vt is the volume
of the titrant used, typically in liters; M is the
mole ratio of the analyte and reactant from the
balanced chemical equation; and Va is the
volume of the analyte used, typically in liters.
Ion Chromatography
• Ion chromatography is used for water
chemistry analysis. Ion chromatographs are
able to measure concentrations of major
anions, such as fluoride, chloride, nitrate,
nitrite, and sulfate, as well as major cations
such as lithium, sodium, ammonium,
potassium, calcium, and magnesium in the
parts-per-billion (ppb) range.
• Principle of gas chromatography: The sample
solution injected into the instrument enters a
gas stream which transports the sample into a
separation tube known as the "column."
(Helium or nitrogen is used as the so-
called carrier gas.) The various components
are separated inside the column.
• Spectrophotometry is a method to
measure how much a chemical
substance absorbs light by measuring
the intensity of light as a beam of
light passes through sample solution.
The basic principle is that each
compound absorbs or transmits light
over a certain range of wavelength
Diagrammatic representation of
geochemical data
• Collins diagram
• Pie diagram
• Bilinear diagram
• Trilinear Diagram
(Hill-1940; Piper1944;)
• Hill-1940; Piper1944;
• Piper’s diagram:
• 1. The diagram consist of three distinct field
—two triangle field and a diamond shaped
field.
• 2. In the triangular field, the % epm values
of cations and anions are plotted separately.
• 3. The overall characteristics of the water is
represented in the diamond shaped field, by
projecting the position of plot in the
triangular.
• Hydrogeochemical facies of ground water
• Facies
• A=Calcium type
• B=Sodium dominant type
• C=Magnesium type
• D=Na+K type
• E= Bicarbonate type
• F= Sulphate type
• G=Chlorite type
• Field characters
• 1. Ca+Mg >Na+K (Alkaline earths exceed alkalies)
• 2. Na+K >ca+Mg (Alkalies exceed alkaline earths)
• 3. Weak acid>Strong acid
• 4. Strong acid>Weak acid
• 5. Magnesium bicarbonate type
• 6. Calcium chlorite type
• 7. Sodium chlorite type
• 8. Sodium bicarbonate type
• 9. Mixed type cation anion>50%
Advantage:
• It is useful to visually describing the difference in
major ion chemistry.
• Hydrochemical facies was developed to describe
cation and anion concentration based on subdivision
of piper diagram
• Most frequently used today
• It has the potential to represent large number of
analyses
• It is convenient for showing the mixing of two
waters from different sources
• Exercise-1 Plot the following
chemical analysis of data of
water sample in Hill-Piper
diagram and discuss chemical
characteristic of water. All the
data in ppm
Sam. Ca Mg Na K Hco3 So4 Cl TDS
No.
1 12 19 6.6 98 9 23 190
2 72 135 20 0 252 428 32 1154
3 92 108 1360 0 158 347 218 4270
4 84 60 69 0 306 246 67 717
5 41 26 58 0 54 146 66 476
6 46 26 58 0 89 155 46 469
7 72 22 47 0 23 104 32 451
8 106 33 168 1.4 136 205 280 958
9 32 0 15 0 138 105 31 439
10 127 29 356 0 136 204 625 1550
Classification of
irrigation water
Irrigation use of water
• TDS (expressed in terms of EC) (salinity
hazard)
• Relative proportion of sodium to Ca +Mg
(SAR) (Sodium hazard)
• Sodium concentration
• Boron concentration
• Relative proportion of bicarbonate to
Ca+Mg (bicarbonate hazard)
Sodium Adsorption Ratio
• 1.25-2.25 marginal
• >2.25 unsuitable
Industrial Use
• Pharmaceuticals --- purest
water
• Solubility
• Mg/l
• --------------------------------------------
• pH
Chemical addition before precipitation
• Iron in ferrous state-
change from ferrous to ferric by adding
oxidizing agent and pH is raised
• Chromium in hexavalent state
Change from hexa to trivalemt by adding reducing
agent-sulphur dioxide,Sodium bisulfite,ferrous
sulphate and then pH is raised
• Arsenic– Add Ferrous or ferric state
and increase pH.
Removal of suspended solid
• (ii)
• O-Dichlorobenzene 0.600
• Para-Dichlorobenzene 0.075
• Cis-1,2-Dichlorethylene 0.070
• 1,2-Dicholoethane 0.005
• 1.,1-Dichloroethylene 0.007
• Dichloromethane 0 .005
• 1,2-Dichlorophane 0.005
• Unfiltered runoff waters leave a thin film of sediment on the sides and
bottom of the pits which require maintenance in order to sustain the high
recharge rates. Shafts may be circular, rectangular, or of square cross-
section and may be backfilled with porous material. Excavation may
terminate above the water table level or may be hydraulic connectors and
extend below the water table. Recharge rates in both shafts and pits may
decrease with time due to accumulation of fine grained materials and the
plugging effect brought about by microbial activity (O'Hare et al., 1986).
Ditches
• A ditch could be described as a long narrow trench,
with its bottom width less than its depth. A ditch
system can be designed to suit the topographic and
geologic conditions that exist at a given site. A layout
for a ditch and a flooding recharge project could
include a series of ditches trending down the
topographic slope. The ditches could terminate in a
collection ditch designed to carry away the water that
does not infiltrate in order to avoid ponding and to
reduce the accumulation of fine material (O'Hare et
al., 1986).
Recharge Wells