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1A Introduction
1A Introduction
1A Introduction
ENGINEERING
Syllabus
2
Atomic Structure
3
Atomic Structure
4
The structure of an Atom
Any substance, solid, liquid or gaseous is made up of
molecules and molecules are made up of atoms.
5
The structure of an Atom
FIGURE 1-1 The Bohr model of an atom showing electrons in orbits and
around the nucleus, which consists of protons and neutrons. The “tails” on the
electrons indicate motion.
6
The structure of an Atom
7
The structure of an Atom
-
-
-
+
-
-
-
8
The structure of an Atom
Nucleus -
-
-
+
-
-
-
-
-
-
Nucleus -
-
-
+
-
-
-
-
-
-
- + -
Electrons
- - -
- - - Valence electrons
13 electrons.
The structure of an Atom
Outermost orbit
- - -
- - -
Nucleus
- + -
- Electrons
- -
- Valence electrons
- -
- +14 -
- Electrons
- -
- Valence electrons
- -
Silicon Atom
A silicon atom consists of 14 protons and 14 neutrons
inside the nucleus and 14 revolving electrons.
These 14 electrons are distributed among different
16 shell.
The structure of Silicon (Si) Atom
+14
-
2
Silicon Atom:-
The first shell contains 2 electrons ( 2n2 = 2 since n=1 first
shell)
17
The structure of Silicon (Si) Atom
-
- - -
- +14 -
- - 2 -
- 8
Silicon Atom
The first shell contains 2 electrons ( 2n2 = 2 since n=1 first shell)
The second shell contains 8 electrons ( 2n2 = 8 since n=2 second
shell)
18
The structure of Silicon (Si) Atom
Outermost orbit
- - -
- - -
Nucleus
- +14 -
- Electrons
- 2 -
- Valence electrons
- - 8
Silicon Atom
The first shell contains 2 electrons ( 2n2 = 2 since n=1 first
shell)
The second shell contains 8 electrons ( 2n2 = 8 since n=2
second shell)
19
While third shell which is called as valence shell contains 4
The structure of Germanium (Ge) Atom
- Nucleus
+32
- 2
Germanium Atom
The first shell contains 2 electrons ( 2n2 = 2 since n=1 first
shell)
20
The structure of Germanium (Ge) Atom
-
- - - Nucleus
- +32 -
- 2
- -
- 8
Germanium Atom
The first shell contains 2 electrons ( 2n2 = 2 since n=1 first shell)
The second shell contains 8 electrons ( 2n2 = 8 since n=2 second
shell)
21
The structure of Germanium (Ge) Atom
- -
- -
- -
-
- - -
- - Nucleus
- - +32 - -
- - Electrons
- - 2 -
-
- 8 -
-
- -
- 18
Germanium Atom
The first shell contains 2 electrons ( 2n2 = 2 since n=1 first shell)
The second shell contains 8 electrons ( 2n2 = 8 since n=2 second
shell)
22 The third shell contains 18 electrons ( 2n2 = 18 since n=3 third
The structure of Germanium (Ge) Atom
-
- -
- - Outermost orbit
- -
-
- - -
- - Nucleus
-
Germanium Atom 4
The first shell contains 2 electrons ( 2n2 = 2 since n=1 first shell)
The second shell contains 8 electrons ( 2n2 = 8 since n=2 second shell)
The third shell contains 18 electrons ( 2n2 = 18 since n=3 third shell)
And the outermost shell contains 4 valence electrons.
23
Silicon as well as Germanium atoms contains 4 electrons in the
valence shell.
If there are 4 electrons in the outermost orbit the semiconductor
material is called as Tetravalent semiconductor or pure or Intrinsic
semiconductor
24
Ionization
25
Ionization
When in equilibrium, an atom is electrically neutral, as the
number of protons is exactly equal to the number of electrons.
26
Ionization
When in equilibrium, an atom is electrically neutral,
as the number of protons is exactly equal to the
number of electrons.
27
Ionization
When in equilibrium, an atom is electrically neutral,
as the number of protons is exactly equal to the
number of electrons.
29
Ionization
When in equilibrium, an atom is electrically neutral,
as the number of protons is exactly equal to the
number of electrons.
But if the electrons from the outermost orbit (valence
electron) is extracted, then the atom does not remain
electrically neutral.
Since it has lost one electron, it has lost some negative
charge. So the atom becomes positively charged and
called as positive ion.
On the other hand, addition of an electron to an atom
will convert it into negative ion.
The process of conversion from an electrically neutral
30 to an ion is called as Ionization.
Concept of energy levels
Energy levels increases as
- we away from the nucleus
Shell 1
Lowest energy -
- - Valence orbit shell
has highest energy level
- - - + - - -
nucleus - -
-
-
Each electronic orbit has an energy level associate with it.
The electrons in the inner orbits are more closely bound to the
nucleus and posses less energy.
As we move towards the valence shell, the binding force
between nucleus and electrons reduces and the electrons posses
31 higher energy.
Free electrons
Energy levels increases as
- we away from the nucleus
Shell 1
Lowest energy -
- - Valence orbit shell
has highest energy level
- - - + - -
-
The valence electrons are very loosely bound with the nucleus .
If an external energy is given to them, they can easily break
away from the nucleus and become free.
Such electron which are free from the force of attraction of
nucleus are called as free electrons
32
Free electrons
Energy levels increases as
- we away from the nucleus
Shell 1
Lowest energy -
- - Valence orbit shell
has highest energy level
- - - + - -
-
These free electrons posses an energy which is higher than that
of valence electrons.
The electric current flows due to these free electrons and they
are said to be in the conduction band.
The energy level of conduction band is higher than that of
33
valence shell
Energy Bands
Energy levels increases as
- we away from the nucleus
1st Band -
- - Valence orbit shell
2nd Band has highest energy level
- - - + - -
Valence band
nucleus - - - Free electron
-
Energy -
conduction
Conduction band
Band
Forbidden energy gap
EG
Valence Band Valence band
conduction
Conduction band
Band
• The electrons in the first shell will require the highest amount of
energy for their extraction. Therefore the first shell is said to have
lowest amount of energy associate with it
On the other hand, the valence electrons require the lowest amount
of energy for their extraction. Hence valence shells are said to have
35
the highest amount of energy.
Energy Bands
Energy
conduction
Conduction band
Band
Forbidden energy gap
EG
Valence Band Valence band
Valence Band :
The valence band corresponds to the valence electrons present
conduction
Conduction band
Band
Forbidden energy gap
EG
Valence Band Valence band
conduction
Conduction band
Band
Forbidden energy gap
EG
Valence Band Valence band
No electrons can normally exist in the forbidden gap. For any given type of
material the forbidden gap may be large, small or even nonexistent.
39
Let us understand conductor, insulators and semiconductors
based on their energy band diagram
Conductors
Conductors are materials which allows the current to flow very easily.
This is due to the large number of free electrons present in the
conductors.
From the energy band diagram of conductors shown in figure, for
metals like copper, aluminium etc. there is no “forbidden gap” present
between the valence and conduction band.
Therefore even at room temperature, a large number of free electrons
are present and available for conduction.
Conduction
Band
Conduction band
Bands
overlap
Valence band
Valence
Band
40
Let us understand conductor, insulators and semiconductors
based on their energy band diagram
Insulators
The energy band diagram of an insulator is shown in figure
The forbidden gap between the conduction band valence band
is extremely wide.
Normally the valence electrons cannot jump that far and enter
into the conduction band. Therefore conduction those not takes
place and these materials are known as insulators
Conduction
Band Conduction band
Large
forbidden EG = 6 eV
gap
Valence
41 Valence band Band
Let us understand conductor, insulators and semiconductors
based on their energy band diagram
Semiconductors
Semiconductor have the conduction properties which are in
between those of conductors and insulators.
We can say that semiconductors are neither conductors nor
insulators. Forbidden gap is very narrow as compared to that of
the insulator.
The forbidden gap for Silicon EG = 1.1 eV
For Germanium EG = 0.72 eV
Conduction Conduction band
Band
small
forbidden EG = 1 eV
gap
Valence
Valence band Band
42
Let us understand conductor, insulators and semiconductors
based on their energy band diagram
Conduction
Conduction Band Conduction
Band Band
Bands Large
small
43
Why silicon is more widely used semiconductor
material
The valence electrons in germanium are in the fourth shell
while those in silicon are in the third shell, i.e. closer to the
nucleus.
This means that the germanium valence electrons are at higher
energy levels than those in Silicon.
Hence germanium valence electrons will need smaller amount
of additional energy to escape from the atom.
Due to this, the germanium produces more number electron
hole pairs than silicon.
Hence the leakage current is more in germanium than that of
silicon.
This property make germanium more unstable at high
temperatures, therefore silicon is more widely used material
44 than germanium.
Types of Semiconductors
The semiconductors are classified into two categories
as:
45
Intrinsic Semiconductors
Intrinsic means pure, so intrinsic semiconductors are
the semiconductors in their purest possible form.
46
Extrinsic Semiconductors
Extrinsic means impure, so we can obtain the extrinsic
semiconductors from intrinsic ones by adding
impurities to them.
Impurity is nothing but some other material. The
process of adding impurities is called as “ doping”
Due to doping, the conductivity of the semiconductor
increases.
Extrinsic semiconductor are of two types:
n- type semiconductor
p- type semiconductor
The type of extrinsic semiconductor (n or p) depends
47 on the type of impurity ( or dopant ) being used
Intrinsic Semiconductors two dimensional
representation
We know that in a silicon or germanium atom there
are four valence electrons
Si
48
Intrinsic Semiconductors two dimensional
representation
Si
49
Intrinsic Semiconductors two dimensional
representation
We know that in a silicon or germanium atom there are four
valence electrons
In an intrinsic Si or Ge crystal these four valence electrons are
bound to four adjacent atoms
Si Si Si
Covalent Bond
Si Si Si
Si Si Si
50
Intrinsic Semiconductors two dimensional
representation
Each one of the four valence electrons in each atoms forms a
bond with a valence electrons from the adjoining atom as
shown. This bond is nothing but sharing of electrons. These
bonds are Known as covalent bond
Si Si Si
Covalent Bond
Si Si Si
Si Si Si
51
Intrinsic Semiconductors two dimensional
representation
Si Si Si
Covalent Bond
Si Si Si
52
Conduction in intrinsic semiconductor
53
Conduction in intrinsic semiconductor
54
FIGURE Electron-hole pairs in a silicon crystal. Free electrons are being
generated continuously while some recombine with holes.
55
Generation of electron-hole pairs at increased
temperature
At increase in temperature many valence electrons
will absorb the thermal energy, breaks the covalent
bonds and go into the conduction band
Thus they becomes free for conduction. When an
electron break a covalent bond and becomes free, a
vacancy is created in the broken covalent bond.
Free electron
Si Si Si Si
hole
56
Generation of electron-hole pairs at increased
temperature
This vacancy is called as “hole”. Thus corresponding to every
free electron, hole is created.
Therefore the number of free electrons are generated due to
increased in temperature is exactly equal to the number of holes.
As the free electrons and holes are generated in pairs they are
called as thermally generated electron hole pair.
Free electron
Si Si Si Si
hole
57
Generation of electron-hole pairs at increased
temperature
The electrons and holes both can operate as charge carriers. The
holes is said to have a positive charge as it is nothing but absence
of an electron.
Si Si Si Si
hole
58
Recombination
Free electron
Si Si Si Si
hole
59
Recombination
Free electron
Si Si Si Si
hole
60
FIGURE Hole current in intrinsic silicon.
61
Electron and hole current
Electron Current
As we apply voltage across a piece of intrinsic semiconductor
material, the thermally generated free electrons in the
conduction band are attracted towards the positive end
Si Si Si
62
Electron and hole current
Hole Current
Si Si Si
63
Electron and hole current
Hole Current
Si Si Si
64
Electron and hole current
Hole Current
Si Si Si
Si Si Si
65
Electron and hole current
Hole Current
Si Si Si
Si Si Si
66
Electron and hole current
Hole Current
Si Si Si
Si Si Si
Total current
The flow of an electric current is due to the movement of
electrons in the conduction band and movement of holes in the
valence band.
Total current = electron current + hole current
Si Si Si
68
FIGURE Electron current in intrinsic silicon is produced by the
movement of thermally generated free electrons.
69
Semiconductors have a negative temperature
coefficient of resistivity
Electron flow
h - e
h - e
h - e
Semiconductor slab
External DC source
71
Extrinsic Semiconductors
Doping Process
In the process of doping, impurities are added to the pure
Silicon or Germanium.
The impurities are the material used to dope the intrinsic
semiconductor materials. These materials can be of two types:
72
Donor impurity
73
Acceptor impurity
74
n-type semiconductor
Si Si Si
Fifth valence electron
Of Arsenic
(Extra Free electron)
Si As Si
Covalent Bond
Si Si Si
76
FIGURE Pentavalent impurity atom in a silicon crystal structure. An antimony
(Sb) impurity atom is shown in the center. The extra electron from the Sb atom
becomes a free electron.
77
majority and minority carriers in the n-type semiconductor
A large number of free electrons are present along with a small
number of thermally generated holes in an n-type semiconductor.
e
e - e - e - e -
- e e h
- -
h e - e -
e
- N-type material e
-
- e - e
78
P-type semiconductor
Si Si Si
Hole created due to
Incomplete bond
Si Ga Si
Si Si Si
80
FIGURE 1-16 Trivalent impurity atom in a silicon crystal structure. A boron (B)
impurity atom is shown in the center.
81
majority and minority carriers in the p-type
semiconductor
Conventional current
Electron flow
e - + +
+ +
e - + +h
+ h + +
P-type material
+ +
82
p-n junction
- - - + + +
- - - + + +
- - + +
n-type P-type
semiconductor semiconductor
83
p-n junction
junction
- - - + + +
- - - + + +
- - + +
n-type p-type
semiconductor semiconductor
84
p-n junction
junction
- - - + + + Cathode
Anode
- - - + + +
- - + +
n-type p-type
semiconductor semiconductor
85
p-n junction
- - - + + + cathode
Anode
- - - + + +
- - + +
N-type p-type
semiconductor semiconductor
junction
Anode cathode
n-type p-type
semiconductor semiconductor
87
Diffusion
Anode cathode
88
formation of the depletion region
Note that no external voltage is applied between the
terminals of the p-n junction, hence the p-n junction is
said to be unbiased.
junction
- - + + cathode
Anode
- - + +
- - + +
89
formation of the depletion region
Note that no external voltage is applied between the
terminals of the p-n junction, hence the p-n junction is
said to be unbiased.
The free electrons from “n” side will diffuse into the p
side and recombine with the holes present there.
junction
- - + + cathode
Anode
- - + +
- - + +
90
formation of the depletion region
Each electron diffusing into the “p” side will leave
behind a positive immobile ion on the n-side.
When electron combine with a hole on the p-side, an
atom which accepts this electron, losses its electrically
neutral status and become a negative immobile ion as
shown in figure
junction
- - + + cathode
Anode
- - + +
- - + +
91
formation of the depletion region
Note that no external voltage is applied between the
terminals of the p-n junction, hence the p-n junction is
said to be unbiased.
junction
- + cathode
Anode
n-type
semiconductor
92
formation of the depletion region
Note that no external voltage is applied between the
terminals of the p-n junction, hence the p-n junction is
said to be unbiased.
junction
- - - + + + cathode
Anode
- - - + + +
- - - + + +
P-type n-type
semiconductor semiconductor
93
formation of the depletion region
Note that no external voltage is applied between the
terminals of the p-n junction, hence the p-n junction is
said to be unbiased.
The free electrons from “n” side will diffuse into the p
side and recombine with the holes present there.
junction
- - - + + + cathode
Anode
- - - + + +
- - - + + +
P-type n-type
semiconductor semiconductor
94
formation of the depletion region
Note that no external voltage is applied between the
terminals of the p-n junction, hence the p-n junction is
said to be unbiased.
The free electrons from “n” side will diffuse into the p
side and recombine with the holes present there.
junction
- - - + + + cathode
Anode
- - - + + +
- - - + + +
P-type n-type
semiconductor semiconductor
95
formation of the depletion region
Each electron diffusing into the “p” side will leave
behind a positive immobile ion on the n-side.
When electron combine with a hole on the p-side, an
atom which accepts this electron, losses its electrically
neutral status and become a negative immobile ion as
shown in figure
junction
- - - + + + cathode
Anode
- - - + + +
- - - + + +
P-type n-type
semiconductor semiconductor
96
formation of the depletion region
Each electron diffusing into the “p” side will leave
behind a positive immobile ion on the n-side.
When electron combine with a hole on the p-side, an
atom which accepts this electron, losses its electrically
neutral status and become a negative immobile ion as
shown in figure
junction
- - - + + + cathode
Anode
- - - + + +
- - - + + +
P-type n-type
semiconductor semiconductor
97
formation of the depletion region
Each electron diffusing into the “p” side will leave
behind a positive immobile ion on the n-side.
When electron combine with a hole on the p-side, an
atom which accepts this electron, losses its electrically
neutral status and become a negative immobile ion as
shown in figure
junction
- - - + + + cathode
Anode
- - - + + +
- - - + + +
P-type n-type
semiconductor semiconductor
98
formation of the depletion region
Each electron diffusing into the “p” side will leave
behind a positive immobile ion on the n-side.
When electron combine with a hole on the p-side, an
atom which accepts this electron, losses its electrically
neutral status and become a negative immobile ion as
shown in figure
junction
- - - + + + cathode
Anode
- - - + + +
- - - + + +
P-type n-type
semiconductor semiconductor
99
formation of the depletion region
Each electron diffusing into the “p” side will leave
behind a positive immobile ion on the n-side.
When electron combine with a hole on the p-side, an
atom which accepts this electron, losses its electrically
neutral status and become a negative immobile ion as
shown in figure
Negative immobile ions junction Positive immobile ions
- - - + + + cathode
Anode
- - - + + +
- - - + + +
P-type n-type
semiconductor semiconductor
100
formation of the depletion region
Due to this recombination process, a large number of
positive ions accumulate near the junction on the n-
side and a large number of negative immobile ions
will accumulate on the p-side near the junction
- - + + cathode
Anode
- - + +
- - + +
P-type n-type
semiconductor semiconductor
Depletion
region
101
formation of the depletion region
The negatively charged ions on the p-side will start
repelling the electrons which attempts to diffuse into
the p-side and after some time the diffusion will stop
completely.
At this point the junction is said to have attained an
equilibrium.
Negative immobile ions Positive immobile ions
junction
- - + + cathode
Anode
- - + +
- - + +
P-type n-type
semiconductor semiconductor
Depletion
region
102
width of the depletion region
Practically the width of depletion region is very small
of the order of 0.5 to 1 micron where 1 micron is
equal to 1X10-6 meter.
Thus the depletion region is very thin as compared to
the width of p and n region.
Negative immobile ions Positive immobile ions
junction
- - + + cathode
Anode
- - + +
- - + +
P-type n-type
semiconductor semiconductor
Depletion
region
103
Barrier potential or junction potential
Due to the presence of immobile positive and
negative ions on opposite sides of the junction, an
electric field is created across the junction. This
electric field is known as the “barrier potential”.
The polarities of barrier potential are decided by the
type of immobile ions present on the two sides of the
junction.
- + Barrier potential or
Junction potential
- - + + cathode
Anode
- - + +
- - + +
P-type n-type
104 semiconductor Depletion semiconductor
region
Barrier potential or junction potential
Barrier potential is measured in volts. The barrier
potential for silicon is about 0.6 Volt whereas its value
for the Germanium is 0.2 Volt.
- + Barrier potential or
Junction potential
- - + + cathode
Anode
- - + +
- - + +
P-type n-type
semiconductor Depletion semiconductor
105
region
penetration of depletion region
P N
Equal penetration
On both side
106
penetration of depletion region
P N
More penetration
On p-side
107
penetration of depletion region
P N
More penetration
On n-side
108
penetration of depletion region
Both sides are equally doped P-side is lightly doped n-side is lightly doped
J J
J
P N P N P N
Thus the depletion region always penetrates more on the side which is lightly
109 doped as compared to the other