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2.1 Matter A B1 B2 B3 - Issue 02
2.1 Matter A B1 B2 B3 - Issue 02
Physics
Module 2.1
Certification Statement and Objectives
These Study Notes comply with the syllabus of EASA
Regulation (EU) No. 1321/2014 Annex III (Part-66) Appendix I,
its amendment, and the associated Knowledge Levels as
specified below:
Matter 2.1 1 1 1 1
Nature of matter: the
chemical elements,
structure of atoms,
molecules;
Chemical compounds;
‘States: solid, liquid and
gaseous;
Changes between
states.
These orbits make up most of the volume of the atom yet In general, we can say that the size of an atom is determined
contributes practically nothing to its substance. The other part, by its electron orbits, its substance is determined by the total
located at the centre, is extremely small compared to the atom number of protons and neutrons in its nucleus.
as a whole, yet essentially all of the real substance of the atom
can be attributed to this small speck. We call this speck the
nucleus.
When two protons get near each other, they push each What Is An Atom - Part 2 - Isotopes | Chemistry for All
other away. | FuseSchool
When an electron gets near a proton, they attract each https://youtu.be/51zQgewbjEs
other.
Two electrons will also push each other away.
Neutrons
Neutrons are particles that are neither positively nor negatively
charged. They are neutral. The neutrons together with protons
form the tightly packed nucleus at the centre of the atom.
Elements
Pure substances, made up of atoms with the same number of
protons. An element is a material that is made up of atoms of
only one kind.
Not all elements have molecules. The metals on the left-hand Chemical formulae
side and the middle part of the periodic table are solids at Each element has its own unique chemical symbol. We can
room temperature and so they exist as tightly packed arrays combine these symbols into a chemical formula, for example,
of atoms like the previous examples of silver and copper. for water. The chemical formula is another very important
concept in chemistry.
Many of the non-metals on the right-hand side of the periodic
table are gases at room temperature that exist as molecules The chemical formula for water is H2O. It shows the ratio of hydrogen
made up of two atoms each. These are called diatomic
atoms (two) to oxygen atoms (one) in one molecule of water.
molecules. Oxygen (O2), nitrogen (N2), hydrogen (H2), chlorine (Cl2)
A compound is a material that consists of atoms of two or
and some other elements from the non-metals all form diatomic
more different elements. The elements are not just physically
molecules.
mixed, but chemically bonded together at the atomic level.
‘Diatomic’ refers to a molecule made of two of the same atoms
Water (H2O), carbon dioxide (CO2) and salt or sodium chloride (NaCl)
bonded together, as in oxygen (O2). ‘Di’ means two. ‘Triatomic’ refers
are examples of compounds, while oxygen gas (O2), hydrogen gas (H2)
to a molecule made up of three of the same atoms bonded
and nitrogen gas (N2) are examples of elements.
together, like ozone (O3).
Reading a Chemical Formula - Breaking Down
Since water is such an important compound for organisms Molecules https://youtu.be/G9Ta7bg5Tlk
living on Earth, we will use that as our first example. Scientists
know that a water molecule is made up of one oxygen atom
and two hydrogen atoms. If we could see them, all water
molecules would look a little bit like this diagram of a water
molecule.
A water molecule
representation (oxygen and
hydrogen)
Oxygen (O2)
Ethanol (C2H6O)
Water (H2O)
The purpose of the comparison of hydrogen peroxide and Inhibitors are sometimes referred to as “negative catalysts”
water above was to show you that the atoms in a given since they decrease the reaction rate.
compound are always combined in a fixed ratio. In all water
molecules in the universe, there will always be one O atom What triggers a
and two H atoms bonded together. chemical reaction?
https://youtu.be/8m6RtOpqvtU
the mass number, thus: In imprecise terms, one AMU is the average of the proton rest
mass and the neutron rest mass. This is approximately
The difference between the mass number and the atomic 1.67377 x 10-27 kilogram (kg), or 1.67377 x 10-24 gram (g). The
number gives the number of neutrons (N) in a given nucleus: mass of an atom in AMU is roughly equal to the sum of the
N = A-Z. number of protons and neutrons in the nucleus.
What Is An Atom?
https://youtu.be/o-3I1JGW-Ck
Isotopes of hydrogen
Isotopes of carbon
‘s, p, d, f’ are the names given to the subshells that hold the
electrons in the shells of atoms. These orbitals have different Ionization
shapes (e.g. electron density distributions) and energies (e.g. When the atom loses electrons or gains electrons in this
1s is lower energy than 2s which is lower energy than 3s; 2s is process of electron exchange, it is said to be ionised. For
lower energy than 2p). ionisation to take place, there must be a transfer of energy
which results in a change in the internal energy of the atom.
Physicists and chemists use a standard notation to indicate the An atom having more than its normal amount of electrons
electron configurations of atoms. The notation consists of a acquires a negative charge and is called a negative ion (or
sequence of atomic orbital labels (e.g. for phosphorus the ‘anion’). The atom that gives up some of its normal electrons is
sequence 1s, 2s, 2p, 3s, 3p) with the number of electrons left with less negative charges than positive charges and is
assigned to each orbital (or set of orbitals sharing the same called a positive ion (or ‘cation’). Thus, ionisation is the process
label) placed as a superscript. by which an atom loses or gains electrons.
For example, hydrogen has one electron in the s-orbital of the Cation – A cation is a positively charged ion. Metals
first shell, so its configuration is written 1s1. Lithium has two typically form cations.
electrons in the 1s-subshell and one in the (higher-energy) 2s- Anion – An anion is a negatively charged ion. Non-metals
subshell, so its configuration is written 1s2 2s1 (pronounced typically form anions.
“one-s-two, two-s-one”). Phosphorus (atomic number 15) is as
follows: 1s2 2s2 2p6 3s2 3p3. Examples of electron arrangements
The diagrams below show some examples of electron
For atoms with many electrons, this notation can become arrangements in the shells of the respective atoms.
lengthy and so an abbreviated notation is used, since all but the
last few subshells are identical to those of one or another of Subshells are not shown.
the noble gases. Phosphorus, for instance, differs from neon
(1s2 2s2 2p6) only by the presence of a third shell. Thus, the
electron configuration of neon is pulled out, and phosphorus is
written as follows: [Ne] 3s2 3p3. This convention is useful as it is
the electrons in the outermost shell that most determine the
chemistry of the element.
On period 1 On period 3
Electron arrangement of hydrogen and helium Electron arrangement of sodium, chlorine and argon
On period 2
On period 4
Lithium, sodium and potassium have a valency of 1 because The rules above can be summarised as follows:
they combine with one hydrogen atom. Beryllium, magnesium
and calcium all have a valency of 2: they combine with two The normal valency of an atom is equal to the number of
hydrogen atoms. Note that the valences of all these atoms are outer electrons if that number is four or less. Otherwise,
equal to the number of outer electrons that these elements the valency is equal to eight minus the number of outer
have. electrons.
Boron and aluminium combine with three hydrogen atoms – The atoms with full electron shells (helium, neon, argon) are
their valences are 3 – and they have three outer electrons. chemically inert forming few compounds. The atoms don’t even
interact with each other very much. These elements are gases
Carbon and silicon combine with four hydrogen atoms. The with very low boiling points.
valency of these elements is 4. It will come as no surprise that
they both have four outer electrons. Any element with four The atoms with a single outer electron or a single missing
electrons in its outer shell is known as a semiconductor electron are all highly reactive. Sodium is more reactive than
magnesium. Chlorine is more reactive than oxygen. Generally
What about nitrogen and phosphorus? They have five outer speaking, the closer an atom is to having a full electron shell,
electrons. But they normally only combine with three hydrogen the more reactive it is. Atoms with one outer electron are more
atoms. Their valences are 3. Note that three is five less than reactive than those with two outer electrons, etc. Atoms that are
eight. These atoms are three electrons short of a full shell. one electron short of a full shell are more reactive than those
that are two electrons short.
Please note that both nitrogen and phosphorus can also have a
valency of 5. Some atoms are capable of having more than
one valency. That will confuse the issue so we will talk of
normal valency.
Mideast Aviation Academy 1-30 Issue 02 – Revision 00
© Copyright 2021 FOR TRAINING PURPOSE ONLY May 2021
Module 2.1
Atoms with only a few electrons in its outer shell are good
electrical conductors. Atoms with eight, or close to eight
electrons in their outer shells are poor conductors (or good
insulators). This is why atoms with four electrons in its outer
shell are semiconductors.
Conductors
In a conductor, electric current can flow freely, in an insulator it
cannot. Metals such as copper typify conductors, while most
non-metallic solids are said to be good insulators, having
extremely high resistance to the flow of electrical charge
through them.
Insulators
Most solid materials are classified as insulators because they
offer very large resistance to the flow of electric current. Metals
are classified as conductors because their outer electrons are
not tightly bound, but in most materials, even the outermost
electrons are so tightly bound that there is essentially zero
electron flow through them with ordinary voltages. Some
materials are particularly good insulators and can be
characterised by their high resistivities
The simplest molecules are formed from two atoms and and combine to form where hydrogen is
examples of their formation are shown below. The electrons electronically like helium and chlorine like neon or argon.
are shown as dots and crosses to indicate which atom the
electrons come from, though all electrons are the same. The Example 4 – two atoms of hydrogen (1) combine with
diagrams may only show the outer electron arrangements for one atom of oxygen (2.6) to form the molecule of the
atoms that use two or more electron shells. Examples of small compound we call water H2O
covalent molecules are…
we call methane CH4. Example 9 – two atoms of carbon (2.4) combine with four
atoms of hydrogen (1) to form ethane C2H4.
Ionic bonds are formed by one atom transferring electrons to In terms of electron arrangement, the sodium donates its outer
another atom to form ions. Ions are atoms, or groups of atoms, electron to a chlorine atom forming a single positive sodium
which have lost or gained electrons. ion and a single negative chloride ion. The atoms have
become stable ions, because electronically, sodium becomes
The atom losing electrons forms a positive ion (a cation) and is like neon and chlorine like argon.
usually a metal. The overall charge on the ion is positive due
to excess positive nuclear charge (protons do not change in Na (2.8.1) + Cl (2.8.7) Na+ (2.8) Cl– (2.8.8)
chemical reactions).
In terms of electron arrangement, the magnesium donates its In terms of electron arrangement, the aluminium donates its
two outer electrons to two chlorine atoms forming a double three outer electrons to three fluorine atoms forming a triple
positive magnesium ion and two single negative chloride ions. positive aluminium ion and three single negative fluoride ions.
The atoms have become stable ions, because electronically, The atoms have become stable ions, because electronically,
magnesium becomes like neon and chlorine like argon. aluminium becomes like neon and also fluorine.
Mg (2.8.2) + 2Cl (2.8.7) Mg2+ (2.8) 2Cl – (2.8.8) Al (2.8.3) + 3F (2.8.7) Al3+ (2.8) 3F– (2.8)
One combines with two to form One combines with three to form
Many ionic compounds are soluble in water, but not all. Metals are good conductors of electricity because these ‘free’
electrons carry the charge of an electric current when a
The solid crystals do not conduct electricity because the ions potential difference (voltage) is applied across a piece of
are not free to move to carry an electric current. However, if metal.
the ionic compound is melted or dissolved in water, the liquid
will now conduct electricity, as the ion particles are now free. Metals are also good conductors of heat. This is also due to
the free moving electrons. Non-metallic solids conduct heat
Properties of Ionic Substances | Chemistry for All | The energy by hotter more strongly vibrating atoms, knocking
Fuse School against cooler less strongly vibrating atoms to pass the
https://youtu.be/AGD5pIXXt4o particle kinetic energy on. In metals, as well as this effect, the
‘hot’ high kinetic energy electrons move around freely to
transfer the particle kinetic energy more efficiently to ‘cooler’
atoms.
Brownian motion is named after the botanist Robert Brown, However, gases that are contained in a fixed volume cannot
who first observed this in 1827. He used a microscope to look expand - and so increases in temperature result in increases
at pollen grains moving randomly in water. At this point, he in pressure.
could not explain why this occurred.
Kinetic particle theory
What is Brownian motion? | Chemistry for All | The The kinetic particle theory explains the properties of the
Fuse School different states of matter. The particles in solids, liquids and
https://youtu.be/NHo6LTXdFns gases have different amounts of energy. They are arranged
differently and move in different ways.
Brownian Motion
https://youtu.be/EZgbcQtnXME
Liquids expand for the same reason, but because the bonds
between separate molecules are usually less tight they
expand more than solids. This is the principle behind liquid-in-
glass thermometers. An increase in temperature results in the
expansion of the liquid which means it rises up the glass.
Mideast Aviation Academy 1-52 Issue 02 – Revision 00
© Copyright 2021 FOR TRAINING PURPOSE ONLY May 2021
Module 2.1
Examples of acids: are vinegar (ethanoic acid) and lemon Sodium hydroxide, NaOH
juice (citric acid) Ammonia, NH3NH4OH
Calcium hydroxide, Ca(OH)2
Some common acids used in and around aircraft:
On the scale:
pH scale