DIFFERENTIATE

ZERO, FIRST, AND

SECOND-ORDER
REACTIONS
EDMUNDO FRIANEZA
JR
CYRELLE JEN RADAM
MARIA CHRISTINA
MANTIZA
3 FUNDAMENTAL TYPES OF REACTIONS
ZERO-ORDER
REACTION

FIRST-
ORDER
REACTION
SECOND-
ORDER
REACTION
 ZERO-ORDER
REACTIONS
Zero-order reaction is a chemical reaction
wherein the rate does not vary with the
increase or decrease in the concentration of the
reactants.
GRAPH OF ZERO-ORDER REACTION
The integral form of zero-order reactions can be rewritten as
[A] = -kt + [A]o
Mathematical expression:
Rate = k
 FIRST-ORDER
REACTIONS
First-order reactions are chemical
reactions of which the rate of reaction
depends on the molar concentration of
one of the reactants that involved in the
reaction.
GRAPH OF FIRST-ORDER REACTION
The integral form of first-order reactions can be rewritten as
ln[A] = -kt + ln[A]o
Mathematical expression:
Rate = k[A] or Rate= k[B]
SECOND-ORDER
REACTIONS
Second-order reactions are chemical
reactions of which the rate of reaction
depends on the molar concentration of two
of the reactants or the second power of one
reactant that involved in the reaction.
GRAPH OF SECOND-ORDER REACTION
The integral form of second-order reactions can be rewritten as
1/[A] = kt + 1/[A]o
Mathematical expression:
Rate = k[A] ² or Rate= k[A][B]
DIFFERENTIATION
OF 3 TYPES OF
REACTIONS
 ZERO-ORDER VS. FIRST-ORDER

ZERO-ORDER FIRST-ORDER

- In zero order reaction, the rate is - In first order reaction, the rate is
independent of concentration. directly proportional to concentration.
- Have a constant rate - Have a decreasing rate over time
 FIRST-ORDER VS. SECOND-ORDER

FIRST-ORDER
- First order reactions involve only
one reactant.
- The half-life of first order
reactions is constant.
SECOND-ORDER
- Second order reactions involve either
one reactant squared or two reactants.
- The half-life of second order reactions
varies with initial concentrations
 ZERO-ORDER VS. SECOND-ORDER

SECOND-
ZERO-ORDER
ORDER
- Zero order reactions have - Second order reactions show a
constant regardless of dependence on concentration, either
concentration. as the square of one reactant or the
product of two reactants.
THANKS FOR LISTENING!!

MARIA EDMUNDO CYRELLE

NOW LET’S HAVE A QUIZ!

 QUIZ
TIME!!
 01.
WHAT IS THE MATHEMATICAL
EXPRESSION OF ZERO-ORDER
REACTION?
02.
It is a chemical reactions of which
the rate of reaction depends on the
molar concentration of one of the
reactants that involved in the
reaction.
03.
Is a chemical reaction wherein
the rate does not vary with the
increase or decrease in the
concentration of the reactants.
 Answer
1. Rate = k
2. First-order reaction
3. Zero-order reaction