Hazardous Waste Management

in United Phosphorous Limited

Jhagadia Unit.

Presented by:-Kishor Khile

Roll no:-16CH60R74
Overview Of UPL
 Project Detail
Name of Company UPL LTD Unit -5 located at Jhagadia ,Dist.-
Bharuch ,Gujarat, India.
Screening Category Manufacturing of pesticides, intermediate products
and speciality chemicals.
UNIT-5 Glyphosate plant
Tri Phenyl Phosphite Plant ,
PCl3 Plant (Phosphorus Trichloride) ,
Caustic Chlorine Plant ,
Phosphorus Oxychloride Plant ,
Phosphorous Plant
Plot Area 866373 sq.m
Production 42167.68 MTM
By Product 41800.83 MTM
End use of Product Agro chemicals
Man Power Company Employee-500
Contract basis-620
Water Consumption 4928.83 m3/day
 Hazardous Waste Detail
S.N Type of Waste Source Of Generation Consent Quantity
(MT/Yr)
1 Phosphorus Distillation Glyphosate Plant 584
Residue
2 Used Oil Plants 8100 Liters
3 Discarded Containers/ Raw Material Drums 36500 Nos.
Barrels/ Liners
4 Process Distillation During process & 3920
Residue (Organic) cleaning of reactors
5 Inorganic Solid Waste During process 100
6 Batteries During maintenance 145 Nos
of equipments
7 Asbestos Plants 4
8 Off Specification During Process 14
Products Disturbance
9 Spent Resins/Catalyst Plants 5
10 Incinerator/Furnace ---- 22
Ash
 Hazardous Process Byproduct
S.N Hazardous Component Severity Treatment
1 Sodium Cyanide High Cyanide Oxidation
2 Chloroethanol High incineration
3 Diethyl Phosphite and High Liquid liquid
trimethylphosphate extraction
4 Triethyl phosphite High Distillation under
vaccum
 Sodium Cyanide Treatment
 First Stage:-
NaCN + 2NaOH + Cl2 <---> NaCNO + H20
 Second Stage:-
2NaCN0 + 4NaOH + 3Cl2 <---> 6NaCl + 2CO2 + N2 + 2H20
 Dimethyl methylphosphonate and
trimethylphosphate Treatment
 DDVP(2,2-dichlorovinyl dimethyl phosphate) product often contains by-product
include undesirable
tri methylphosphate (TMPO) ,
methanol,
dimethyl methylphosphonate (DMMP),
dimethyl hydrogen phosphite (DMHP).
 The DDVP and water may be counter currently contacted in an extractor. The
extract phase contains TMPO, methanol, DMMP and DMHP.
 This provides an economical and effective method for reducing the TMPO level
below 1000 ppm.
 Operating Condition:-
pH:- 2.0 to 11.0 (preferably 3.0 to 7.0)
Weight ratio (DDVP/H2O) :- 1/10 to 10/1
Temperature :-5° C. to 95° C.(preferably 20° C. to 30° C.)
Pressure:- 0.1 to 10 atmospheres (preferably 1 atm)
 Gaseous Hazardous waste
S.N Component Treatment
1 NOx Selective catalytic reduction
2 HCl Caustic Scrubber
CS2
HC vapour
3 Cl2 Water Scrubber + Alkali
Scrubber
4 PM Water Scrubber
5 NH3 Ammonia scrubber
 Conclusion
 Hazardous material generated through various sources properly treated
by various method.
 Emission of hazardous and pollutant gases treated and maintained below
standard emission limit.
 Reference
 http://www.uplonline.com
 Environmental Clearance Compliance Report by UPL Limited, Unit # 05, Jhagadia,
Gujarat