Professional Documents
Culture Documents
A01 Begriffe en
A01 Begriffe en
Basics for
20
Analytical Training
15 Process Gas Analysis
Udo Deptolla CO2
10
CO
Technical terms and symbols
5 O2 Important parameter
Measuring units etc.
0
0, 0,8 1
6
1,2 1,4 1,6 1,8 2
© Company name - 1 -
01-04-06 -
© Company name - 2
A01-2
Remarks:
Name Symbol Notes
A01-3
2 Sample gas line
A01-4
2.1 Outlet to atmosphere
for Gas / Vapor
A01-5
3.8 Three way stop cock
A01-6
3.13 Solenoid valve
4 Filter
4.1 Gas filter, general
elektrostatic
T diffusion thermic
A01-7
5 Safety equipment
A01-8
6.5 Impingement separator
6.8 Electrical
1 Way 2 Way
Sample gas cooler
A01-9
6.12 Ad- resp. Absorption tower
A01-10
7.3 Piston pump
7.8 Compressor
© Company name - 11
7.9 Fan
A01-11
8 Flow meter
8.1 Rotameter
8.1 Rotameter A+
with upper and lower
Alarm limit
A-
A01-12
9.3 Overpressure- Immersion pipe
in the gas inlet
A01-13
11 Measuring point selector switch
13 Analyzer cabinet
Analyzer central compartment
© Company name - 14
x °C
A01-14
Measuring Units
© Company name - 15
A01-15
Measuring Units in Vol % or g / m³ ?
P
*
C = 0,12 * v * M * ( g / m³ )
T
*
Equation is strictly valid only for
ideal gases. It is however a
M = molecular weight of the measuring component sufficient approximation for real
gases at the usual measuring gas
P = total pressure of the measuring gas in mbar pressures and temperatures
T = absolute temperature of the measuring gas in Kelvin
10 Vol% 124,66 g / m³
A01-16
Measuring Units in Vol % or g / m³ ?
1 Volumenteil 1 vpm
=
1 000 000 Volumenteil
Mol - Gewicht
Weight of 1l Gas = V [ cm³ ] x[g / cm³ ] =
Mol - Volumen
p x V=R x T
8,314 Pa x m³
R= ( Gasconstant )
RxT Mol x °K
Mol - Volume = p p = 101325 Pa
A01-17
Measuring Units in Vol % or g / m³ ?
A01-18
Conversion of g/ m³ in vpm and mg C3 in mg C3H8
Mol - gewicht: CO = 28 1 g / m³ X
=
1,25 x 10³ g / m³ 100 Vol %
28 g : 22,4*103 cm³ = 1,25 x 10 -3 g / cm³
30 mg C / m³ = X mg C3H8 / m³
36 mg C / m³ = 44 mg C3H8 / m³
44 mg C3H8 / m³ x 30 mg C / m³
© Company name - 19
X= == 36,667
36,667 mg
mg C
C33H
H88 // m³
m³
36 mg C / m³
A01-19
Conversion of mg C3H8 in vpm
30 mg C / m³ = ? mg C3H8 / m³
36 mg C / m³ = 44 mg C3H8 / m³
44 mg C3H8 / m³ x 30 mg C / m³
X= = 36,667 mg C3H8 / m³
36 mg C / m³
A01-20
Standardisation of pollutant concentration
At emission monitoring systems ( i. e. in germany 13. BImSchV and the 17. BImSchV )
the require a standardization of the pollution concentration to
Reference - Parameter.
That means the raw gas concentration which delivers our Analyzers
must be corrected.
Reference values
Referenceparameter :
Vol % O2
Oxygen quantity
Depends of the fuel
Temperature 0 °C
Equation :
A01-21
Measuring Units in Vol % or g / m³ ?
1 Vol % = 1 / 100 Volumen = 10 000 ppm = 10 4 ppm
1 ppt ( part per trillion ) is 1 Part of 1 000 000 000 000 Parts 1 Nanogramm 0,000 000 001
( t = trillion, amerikanisch für Billion ) per Kilogramm ( 10 - 9 )
1ppq ( part per quadrillion ) is 1 Part of 1 000 000 000 000 000 Parts 1 Picogramm 0,000 000 000 001
( q = quadrillion, amerikanisch für Billiarde ) per Kilogramm ( 10 - 12 )
© Company name - 22
A01-22
Gas Parameters
Tox=1Ca MAK UEG OEG [Vol
lfd.Nr Formel Bezeichnung Komp Nr MolG MolV Exp Kor 1 ppm =? mg/m³ 1 g/m³ = ? ppm
n=2 TRK * Vol % %]
1 CH3CHO Acetaldehyd 207 44,05 22,40 1 1 0 50 4,0 57,0 1,967 508,51
2 CH3COCH3 Aceton 208 58,08 22,40 1 1 0 1000 2,5 13,0 2,593 385,67
3 C2H2 Acetylen 109 26,04 22,22 0 1 0 2,3 78,0 1,172 853,30
4 C3H3N Acrylnitril 242 53,10 22,40 2 0 0 * 6,0 2,8 28,0 2,371 421,85
5 C3H4O2 Acrylsäure 289 112,14 22,40 2 0 0 * 1,7 5,3 26,0 5,006 199,75
6 CH2O2 Ameisensäure 247 46,03 22,40 1 0 0 5 10,0 45,5 2,055 486,64
7 C3H6O2 Ameisensäureethylester 249 74,08 22,40 1 0 0 100 2,7 16,5 3,307 302,38
8 C2H4O2 Ameisensäuremethylester 291 60,05 22,40 1 0 0 100 5,0 23,0 2,681 373,02
9 NH3 Ammoniak 110 17,03 22,08 1 1 1 50 15,4 33,6 0,771 1296,54
10 C6H7N Anilin 221 93,13 22,40 1 0 0 2 1,2 11,0 4,158 240,52
11 Ar Argon 504 39,94 22,39 0 0 0 1,784 560,59
12 ASH3 Arsenwasserstoff 314 77,95 22,40 1 0 0 0,05 4,5 68,0 3,480 287,36
13 C4H8O2 Äthylacetat 271 88,10 22,40 1 0 0 400 2,1 11,5 3,933 254,26
14 C2H5Cl Äthylchlorid 243 64,52 22,40 1 0 0 1000 3,6 14,8 2,880 347,18
15 C6H6 Benzol 203 78,12 22,00 2 1 0 * 8,0 1,2 8,0 3,551 281,62
16 Br2 Brom 601 79,92 22,40 1 0 0 0,1 3,568 280,28
17 HBr Bromwasserstoff 317 80,92 22,40 1 0 0 5 3,613 276,82
18 C4H6 Butadien 1 3- 111 54,09 22,40 1 1 0 * 5,0 1,4 16,3 2,415 414,12
19 C4H10 Butan 106 58,20 21,50 1 1 0 1000 1,4 9,3 2,707 369,42
20 C4H10 Butan ISO- 112 58,12 21,78 1 1 0 1000 1,4 9,3 2,669 374,74
21 C4H10O Butanol ISO- 223 74,12 22,40 1 1 0 100 1,4 11,3 3,309 302,21
22 C4H10O Butanol N- 222 74,12 22,40 1 1 0 100 1,4 11,3 3,309 302,21
23 C4H10S Butanthiol 254 99,19 22,40 1 0 0 0,5 4,428 225,83
24 C4H8 Butylen 2- 114 56,11 22,00 0 1 0 1,6 10,0 2,550 392,09
25 C4H8 Butylen 1- 113 56,11 22,00 0 1 0 1,6 10,0 2,550 392,09
26 Cl2 Chlor 302 70,90 22,06 1 0 0 0,5 3,214 311,14
27 C6H5Cl Chlorbenzol 224 112,56 22,40 1 1 0 50 1,3 9,3 5,025 199,00
28 ClO2 Chlordioxid 303 67,45 22,40 1 0 0 0,1 3,011 332,10
29 CHCl3 Chloroform 225 118,90 22,40 1 0 0 10 5,308 188,39
30 ClF3 Chlortrifluorid 315 92,46 22,41 1 0 0 0,1 4,126 242,38
31 HCl Chlorwasserstoff 311 36,46 22,45 1 0 0 5 1,624 615,74
32 HCN Cyanwasserstoff 300 27,03 22,07 1 1 0 10 5,4 46,6 1,225 816,50
33 C6H12 Cyclohexan 226 84,16 22,40 1 1 0 300 1,2 8,3 3,757 266,16
© Company name - 23
A01-23
Gas Parameters
Tox=1Ca MAK UEG OEG [Vol
lfd.Nr Formel Bezeichnung Komp Nr MolG MolV Exp Kor 1 ppm =? mg/m³ 1 g/m³ = ? ppm
n=2 TRK * Vol % %]
35 C6H10O Cyclohexanon 228 98,15 22,40 1 1 0 50 1,3 9,4 4,382 228,22
36 D2O Deuterium Oxyd 118 20,00 22,40 0 0 0 0,893 1120,00
37 C4H2 Diacetylen 115 50,06 22,40 0 1 0 2,3 78,0 2,235 447,46
38 B2H6 Diboran 316 27,67 22,41 1 0 0 0,1 1,235 809,90
39 C2H4Cl2 Dichloräthan 1,1- 229 98,96 22,40 1 1 0 400 5,6 16,0 4,418 226,35
40 C2H4Cl2 Dichloräthan 1,2 230 98,96 22,40 1 1 0 20 6,2 16,0 4,418 226,35
41 CH2Cl2 Dichlormethan 213 84,93 22,40 1 1 0 100 14,0 25,0 3,792 263,75
42 C3H6Cl2 Dichlorpropan 1 2- 231 112,99 22,40 1 1 0 75 3,4 14,5 5,044 198,25
43 C4H11N Diethylamin 232 73,14 22,40 1 1 0 10 1,7 10,1 3,265 306,26
44 C4H10O Diethyläther 233 74,12 22,40 1 1 0 400 1,7 48,0 3,309 302,21
45 C2N2O2 Diisocyanat 119 84,00 22,40 1 0 0 3,750 266,67
46 C2H7N Dimethylamin 234 45,08 22,40 1 1 0 10 2,8 14,4 2,013 496,89
47 C2H6O Dimethyläther 235 46,07 22,40 1 1 0 ? 3,0 18,6 2,057 486,22
48 C3H7ON Dimethylformamid 275 73,09 22,40 1 1 0 20 2,2 16,0 3,263 306,47
49 C7H8N2O4 Dinitrotoluol 276 182,14 22,41 1 0 0 1,5 8,128 123,04
50 C4H8O2 Dioxan 1 4- 236 88,11 22,40 1 1 0 180 1,9 22,5 3,933 254,23
51 N2O Distickstoffmonoxid 212 44,02 22,25 1 0 0 1,978 505,45
52 C4H6O Divinyläther 237 70,09 22,40 0 1 0 ? 1,7 36,5 3,129 319,59
53 C2H4O2 Essigsäure 238 60,05 22,40 1 1 0 10 4,0 17,0 2,681 373,02
54 C4H6O3 Essigsäureanhydrid 239 102,09 22,40 1 1 0 5 2,0 10,2 4,558 219,41
55 C2H6 Ethan 104 30,07 22,16 0 1 0 2,7 14,7 1,357 736,95
56 C2H5OH Ethanol 206 46,07 22,40 1 1 0 1000 3,5 15,0 2,057 486,22
57 C2H6S Ethanthiol 255 62,13 22,40 0 0 0 2,774 360,53
58 C2H4 Ethen 107 28,05 22,24 0 1 0 2,3 32,4 1,261 792,87
59 C2H4Cl2 Ethylenchlorid 117 98,97 22,40 1 1 0 20 6,2 16,0 4,418 226,33
60 C2H4O Ethylenoxid 246 44,05 22,40 2 1 0 * 2,6 100,0 1,967 508,51
61 F2 Fluor 600 38,00 22,40 1 0 0 0,1 1,696 589,47
62 HF Fluorwasserstoff 305 20,01 22,40 1 0 0 3 0,893 1119,44
63 CH2O Formaldehyd 240 30,04 22,40 1 1 0 1 7,0 73,0 1,341 745,67
64 F Frigen 209 0,00 0,00 1 0 0 1000
65 F11 Frigen 11 215 137,38 22,40 1 0 0 1000 6,133 163,05
66 F113 Frigen 113 219 187,39 22,40 1 0 0 1000 8,366 119,54
67 F114 Frigen 114 250 170,93 22,40 1 0 0 1000 7,631 131,05
© Company name - 24
A01-24
Gas Parameters
Tox=1Ca MAK UEG OEG [Vol
lfd.Nr Formel Bezeichnung Komp Nr MolG MolV Exp Kor 1 ppm =? mg/m³ 1 g/m³ = ? ppm
n=2 TRK * Vol % %]
71 F13 Frigen 13 245 104,47 22,40 0 0 0 4,664 214,42
72 F13B1 Frigen 13 B1 217 148,93 22,40 1 0 0 1000 6,649 150,41
73 CHFCl2 Frigen 21 277 122,00 22,40 1 0 0 10 5,446 183,61
74 F22 Frigen 22 218 86,48 22,40 1 0 0 500 3,861 259,02
75 F23 Frigen 23 248 70,01 22,40 0 0 0 3,125 319,95
76 F502 Frigen 502 220 121,29 22,40 1 0 0 1000 5,415 184,68
77 C4H8O Furan 280 72,00 22,40 2 1 0 * 0,2 2,3 14,3 3,214 311,11
78 C5H4O2 Furylmethanol 241 96,10 22,40 1 1 0 50 1,8 16,3 4,290 233,09
79 He Helium 500 4,00 22,42 0 0 0 0,178 5605,00
80 C7H16 Heptan N- 201 100,21 22,40 1 1 0 500 1,1 6,7 4,474 223,53
81 C6H14 Hexan N- 200 86,18 22,40 1 1 0 50 1,0 8,1 3,847 259,92
82 N2H4 Hydrazin 252 32,05 22,40 2 1 0 * 0,1 4,7 100,0 1,431 698,91
83 CO2 Kohlendioxid 101 44,01 22,26 1 0 0 5000 1,977 505,79
84 CO Kohlenmonoxid 100 28,01 22,40 1 1 0 30 10,9 76,0 1,250 799,71
85 COS Kohlenoxidsulfid 313 60,07 22,41 1 1 0 10 11,9 29,0 2,680 373,06
86 C7H8O Kresol O- N- P- 253 108,14 22,40 1 1 0 5 1,0 ? 4,828 207,14
87 Kr Krypton 501 83,70 22,40 0 0 0 3,737 267,62
88 C4H2O3 Maleinsäureanhydrid 288 98,06 22,40 1 1 0 0,2 1,4 7,1 4,378 228,43
89 CH4 Methan 102 16,04 22,36 0 1 0 4,4 16,5 0,717 1394,01
90 CH3OH Methanol 205 32,04 22,40 1 1 0 200 5,5 44,0 1,430 699,13
91 CH4S Methanthiol 256 48,11 22,40 1 1 0 0,5 3,8 21,8 2,148 465,60
92 C3H6O2 Methylacetat 257 74,08 22,40 1 1 0 200 3,1 16,0 3,307 302,38
93 CH3Br Methylbromid 258 94,94 22,40 1 1 0 5 8,6 20,0 4,238 235,94
94 CH2Br2 Methylenbromid 286 173,86 22,40 0 0 0 7,762 128,84
95 CH3Cl Monochlormethan 287 50,49 22,40 1 1 0 50 7,1 18,5 2,254 443,65
96 Ne Neon 502 20,18 22,43 0 0 0 0,900 1111,50
97 O3 Ozon 503 48,00 22,40 1 0 0 0,1 2,143 466,67
98 C5H12 Pentan N- 260 72,15 22,40 1 1 0 1000 1,4 7,8 3,221 310,46
99 COCl2 Phosgen 306 98,92 22,40 1 0 0 0,1 4,416 226,45
100 PH3 Phosphorwasserstoff 307 34,00 22,40 1 0 0 0,1 **) 1,518 658,82
101 C3H4 Popadien 116 40,06 22,40 0 0 0 1,788 559,16
102 C3H8 Propan 105 44,10 22,00 1 1 0 1000 1,7 10,9 2,005 498,87
103 C3H8O Propanol 2- 261 60,10 22,40 1 1 0 400 2,0 12,0 2,683 372,71
© Company name - 25
104 C3H6 Propen 108 42,08 21,96 0 1 0 2,0 11,1 1,916 521,86
105 C3H40 Propylenoxid 259 56,07 22,40 2 1 0 * 50 1,9 24,0 2,503 399,50
A01-25
Gas Parameters
A01-26
Concentration Units ( Conversion factors )
c
v= x 2,241 [ Vol % ]
M
c = v * M * 0,446 [ g / m³ ]
Coversion factors :
The factors for converting from g / m³ to ppm and ppm to mg / m³ are given.
The data related to the standard status of the substance defined by : p = 1013 mbar and Tn = 273,4 K.
The molucular mass and also the molecular weight is given in this table..
1. example: g / m³ in ppm
conzentration [ g/m³ ] * mol volume * 1000 Note: When converting from mg / m³ to ppm, the values
ppm =
molecular mass given in table must be divided by 1000.
2. example: ppm in g / m³
A01-27
Conversion of weight-% in Mol-% and Volume-% for Gas- composition
Gas composition :
10 weight.% H2, 60 weight.% N2 und 30 weight.% SO2
1 Mol 22,4 l
Total - volume
Volume [ l ]
of the processgas
component
112
+ 47,94 + 10,53 170,47 l
[ Vol % ]
A01-28
Concentration units in connection with the FID
mg CnHm / m³
A01-29
FID concentration units Conversion of ppm in mg org. C / m³ and mg / CnHm
C3 = 3 *12 = 36 Molwght.
org. C
H8 = 8 * 1 = 8
c = 0,01 * 36 * 0,446
44
c = 161 mg org. C / m³
c = 0,01 * 44 * 0,446
c = 196 mg C3H8 / m ³
© Company name - 30
A01-30
Conversion of ppm in mg org. C / m³ and mg CnHm / m ³
with consideration of the Response Factors ( RF ):
Question : What is the correct FID setting in mg org. C / m³ or mg CnHm / m ³ , if the analyzer must
measure Benzene ( C6 H6 ) and you have a test- gas with 100 ppm Propane ( C 3H8 )
for calibration and you will including the Response- Factor for Benzene with
1,06.
A01-31
Response - Factor ( RF )
The Response - Factor take in consideration various sensivities against the different kinds
of Hydrocarbons. I. e. the defined sensivity for Propane is 1 and now it will compared
with the setting of other Hydrocarbons.
The construction of the measuring chamber has great influence to the Responnse- Factors.
Every producer of FID- Analyzer has quite different values for the RF.
Ideal is the value 1 for all kinds of Hydro Carbons.
Remarks :
Refer to the response factors from the TÜV reports of the respective analyzer.
Keep in mind tat the response factors are a approximate figures, which can
differ slightly, depending on the type of analyzer and operating conditions.
A01-32
Concentration units in connection with the FID
0 1,7 Vol %
100 % LEL : 1,7 Vol % = x... % LEL : 0,8 Vol %
x = 47 % LEL related to Propane
A01-33
Condensation
in the
gas feed line
© Company name - 34
A01-34
Water or acid condensate ?
A01-35
Humidity content Common Parameter
A01-36
Dew point Defination
Dewpoint
If the temperature fall down the relative air humidity rise up.
The point where 100 % saturation is reached is the dewpoint.
At deeper temperature exist condensate.
A01-37
Water content = f ( Temperature )
t = Dewpoint [ °C ]
t ps fs VD / V ps = Partial pressure [ mbar ]
°C mbar g/m³ Vol % fs = Humidity [ g / m ³ ]
VD / V = relative Vapor content [ Vol % ]
-20 1,03 0,88 0,1
-10 2,6 2,14 0,26
0 6,11 4,85 0,6 Condensate per day: ?
Cooler Temperature 1 0,65 5,2 0,65
2 7,05 5,56 0,7
Flow : 60 l / h
3 7,59 5,96 0,75
4 8,13 6,36 0,8
Dewpoint : 60 °C
5 8,72 6,8 0,86 Cooler temperature : 3 °C
10 12,28 9,4 1,21
130,2 - 5,96 = 124,24 g / m ³
Average 20 23,38 17,29 2,31
dewpoint 30 42,42 30,36 4,19 24 h x 60 l / h = 1440 l
for coal fire 40 73,74 51,14 7,28
50 123,32 82,98 12,2 1000 1440
=
60 199,2 130,2 19,7 124,24 X
70 311,5 198,1 30,7
80 473,4 293,3 46,8 X= 1440 x 124,4
90 700,9 423,5 69,2 1000
100 1013,3 597,7 100
© Company name - 38
A01-38
Dewpoint - Diagram
600 100
90
500
80
70
400
60
300 50
40
200
30
20
100
10
0 0
© Company name - 39
A01-39
Acid - Dewpoint
Dewpoint - line
0 1 2 3 4
© Company name - 40
A01-40
What
is necessary for an
optimized Combustion ?
© Company name - 41
A01-41
Minimum of Air Requirement for Combustion
Typical waste gas mixture of convential boiler plants :
Nitrogen ( N2 )
Carbon dioxid ( CO2 )
Oxygen ( O2 )
Water vapor ( H2O )
Carbon monoxid ( CO )
Sulfur dioxid ( SO2 )
Hydrogen ( H2 )
Nitrogen oxides ( NO, NOx ( NO+NO2 ) )
The
air factor
is an important variable for the evaluation and monitoring
of combustion processes and is closely connected
with the efficiency of combustion control.
© Company name - 42
A01-42
Air Factor
A01-43
Combustion Diagramm
O2- and CO2- content of dry flue gases for different fuels Waste gas composition as a function of the
as a function of the air factor ( theoretical values ). air factor ( coal )
Vol % Vol %
22
20
e = Blaste- furnace coke
20
d = Coal
18 c = Tar oil
b = Fuel oil
a = Piped gas 15
16
c
b CO2
a
14 d
e
12 10
10
CO
8
5 O2
6
2 0
© Company name - 44
A01-44
Why air- exceed at combustion?
In experience
the burning process is always running with exceed air.
losses 5700 WE
Combustion with exceed air :
To minimize the losses, an exact knowledge of the exceed air is absolute necessarry!!!!!!
A01-45
Gas compound for different burner status
79 Vol% N2
Complete burning
Für = 2 10,5 Vol% CO2
of carcbon C ( e.g. coke )
10,5 Vol% O2
79 Vol% N2
Complete burning
Für = 1 10,5 Vol% CO2
© Company name - 46
of carbon ( CH4 )
10,5 Vol% H2O
A01-46
Air Factor
Type of firing
Fuel type
Boiler construction
The air factor cannot not be measured directly but must calculated from the balance
of materials in the combustion process, i. e. from the composition from the fuel and the
combustions products. In principle it doesn't matter which combustion product component
of the flue gas ( CO, CO2 or O2 ) is used for the calculation.
Oxygen ( O2 ) is the most usefull measured component in this connection because its
concentration in the flue gas can be clearly correlated with
the combustion status .
Carbon monoxide ( CO ) measurement gives an exact information about the point of minimum
losses.
A01-47
Boiler losses ( ideal )
Losses
CO
O2
ideal
O2
CO Boiler- losses
ideal
=1
© Company name - 48
A01-48
Boiler losses ( real )
Losses
CO
O2
ideal
=1
© Company name - 49
A01-49
Boiler losses - Incenerator -
Losses
CO Boiler- losses
O2
Boiler- losses
ideal real
real O2
CO CO
ideal
=1
© Company name - 50
A01-50
Dead - time and Pressure - drop
in Sample gas tubes
© Company name - 51
A01-51
Dead time in gas tubes for Air under Standard pressure
Estimated values of the dead time Tt (seconds) per metre measuring line for inner dia-
meters d (mm) and flow rate Q I/h
d [mm]
4 6 8 10 12 14 16 18 20 22 24
Q [ l/h ]
A01-52
Dead time and pressure drop in gas tubes for Air under
Standard pressure
8 1 60 25 0,005 0,005
5 300 5 1 ... 2 3 ... 6
10 600 2,4 3....6 6....12
6 1 60 13,8 1....2 2....4
5 300 2,7 5....10 10....20
10 600 1,3 20....40
4 1 60 6,1 5....10 10....20
5 300 1,2 30....60 50....110
10 600 0,6 145....290 210....410
Example : Tube lenght : 30 m Dead time : 30 x 0,12 = 3, 6 Sekunden
Inner diameter : 4 mm
Flow : 300 l / h Pressure drop : 30 x 6 = 180 mbar
Note : If you considered a complete analyzer system, you must add also the dead time
© Company name - 53
of the gas conditioning system and the dead time of the analyzer.
The pressure increase with higher temperature and also with rough surfaces .
A01-53
How to remove
Interfering components
© Company name - 54
A01-54
Remove interfering components
Why ?
A01-55
Remove interfering components
Attention !
Removing of one gas- components out of the process gas will cause
an error, because the concentration of the other components
will be increased ( Volume error )
A01-56
Remove interfering components
Universalfilter, drying tower und washing bottle
Application
Gasdrying
Water vapor Universal filter Calcium chloride. 200 90 1.4 · 10 -1 SO2 - HCI - NH3
( CaCl2 )
Drying Tower Calcium chloride. 250 110 1.4 · 10 -1 S02 - HCI: NH3
( CaCl2 )
Phosphorpentoxid. 100 30 2 10 -5 C 2 H2
P205 in Form von all Olefines
Sicapent oder ( CnHm )
Granusic 200 90
Washing bottle Sulfuri - acid 96% 750 cm³ 190 3 10 -3 Olefines NH3 - Cn Hm
© Company name - 57
A01-57
Remove interfering components
Ceramic filter
Oil mist and Universal filte Activated carbon NH3 - SO2 - Cl2.-
vapors Olefine ( CnHm )
Carbon dioxide (CO2 ) Universalfilter Soda lime CO2 - SO2 - Cl2 - H2O
Molecular Sieve ( MS ) For the gases you can get also molecular sieve. It depends of the MS- type
which component can remove.
A01-58
Pure
Pure gas
gas and
and Test
Test Gas
Gas
© Company name - 59
A01-59
Pure gas and Test gas
Special gases
A01-60
Purity datas for gas
Nitrogen without CO
Oxygen without HnCm
A01-61
Typical purities of pure gases
Purity, Vol %
carrier gas [ ppm ]
O2
H2O
CnHm
Ar
CO
Halogenated HC
A01-62
Bottles for Test gas
Synthetic Air
( 80 Vol % N2, 20 Vol % O2 )
Pure gas
+ Steel bottles
Standard mixture
Steel- and
Pure gas
Aluminium bottles
A01-63
Bottle - Certification
Analysis - Certification
A01-64
Gas - manufacturing
A01-65
Bottle preparation before filling
Bottle preparation
Specialm cleaning of the initial product
analytical supervision
analytical selection
A01-66
Restriction at manufacturing of gas compositions
Physikal Restriction
Liquids with a great vapor pressure or vapors dürfen can only filled
in a gas bottle up up to a defenite pressure. Under this condition you
have the guarentee that the component doesn't condensate.
Condensation caused a great error.
Chemical Restriction
Safety Restriction
A01-67
Tested gas compositions
CO CO2 SO2 O2 NO
CO yes yes inquire yes
A01-68
Marking of gas bottles
• Mindeststreckgrenze
• Tara- Gewicht ( mit Ventil, ohne Kappe
• Kennbuchstaben für Wärmebehandlung
ohne Verschlußmutter )
• Fassungsraum
Netto- Gewicht
• Prüfüberdruck
• Erstmalige Prüfung
• Leergewicht ( ohne Ventil u. Anstrich
• TÜV- Zeichen
• Bauart-Zulassungszeichen
• Datum ( Monat / Jahr ) o. Jahr d. nächsten
• Herstellerwerk
Prüfung.
• Herstellernummer
• Gasart
© Company name - 69
A01-69
Suitability - test for gas tubes
Purge valve
Polyvinyl ( PVC ) 27
Rubber 40
A01-70
Technics
Technics
© Company name - 71
A01-71
© Company name - 72
A01-72
© Company name - 73
A01-73
© Company name - 74
A01-74
© Company name - 75
A01-75
© Company name - 76
A01-76
© Company name - 77
A01-77