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11 - Atoms and Radioactivity
11 - Atoms and Radioactivity
A simple model
of the atom
Electron shells*
► Electrons orbit the nucleus at certain fixed levels only,
called shells. There is a limit to how many electrons each
shell can hold - for example, no more than 2 in the first
shell and 8 in the second.
► It is an atom s outermost electrons which form the
chemical bonds with other atoms, so elements with similar
electron arrangements have similar chemical properties.
For questions 4 and 5, you will need data from the table of elements on the Q
opposite page.
1. An atoms contains electrons, protons, and neutrons. Which of these particles
a. are outside the nucleus b. are uncharged
c. have a negative charge
e. are much lighter than the others?
d are nucleons
Isotope essentials !
Different versions of the same element are called isotopes.
Their atoms have different numbers of neutrons in the nucleus.
For example, lithium is a mixture of two isotopes: lithium-6 (with
3 protons and 3 neutrons in the nucleus) and lithium-7 (with 3
protons and 4 neutrons).
11.02 – Nuclear Radiation (1) 11 – Exam
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Questions
Ionizing radiation
► Ions are charged atoms (or groups of atoms). Atoms
become ions when they lose (or gain) electrons.
Nuclear radiation can remove electrons from atoms
in its path, so it has an ionizing effect. Other forms
of ionizing radiation include
ultraviolet and X-rays.
► If a gas becomes ionized,
it will conduct an electric
current. In living things,
ionization can damage or
destroy cells (see the
▲If an atom loses (or gains)
next spread). an electron, it becomes an ion
11.02 – Nuclear Radiation (1) 11 – Exam
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Questions
type of radiation alpha particles (a) beta particles (p) gamma rays (y)
each
particle is
2 protons + 2 each particle is an electromagnetic waves
neutrons (it is identical to electron (created when similar to X-rays
a nucleus of helium-4) the nucleus decays)
relative charge +2 -1 0
compared with
charge on proton
Mass high, compared with betas low -
Speed up to 0.1 x speed of light up to 0.9 x speed of light speed of light
ionizing effect strong weak very weak
penetrating effect not very penetrating: penetrating, but stopped very penetrating: never
stopped by a thick sheet by a few millimeters of completely stopped,
of paper, or by skin, or by aluminium or other though lead and thick
a few centimeters of air metal concrete will reduce
intensity
effects of fields deflected by magnetic and deflected by magnetic not deflected by
electric fields and electric fields magnetic or electric
fields
11.02 – Nuclear Radiation (1) 11 – Exam
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Questions
Radiation dangers
► Nuclear radiation can damage or destroy
living cells, and stop organs in the body
working properly.
► It can also upset the chemical instructions
in cells so that these grow abnormally and
cause cancer. The greater the intensity of
the radiation, and the longer the exposure
time, the greater the risk.
► Radioactive gas and dust are especially
dangerous because they can be taken
into the body with air, food, or drink. Once
absorbed, they are difficult to remove, and ▲Where
their radiation can cause damage in cells background
deep in the body. radiation comes
11.03 – Nuclear Radiation (2) 11 – Exam
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Questions
Radiation dangers
► Alpha radiation is the most harmful
because it is the most highly ionizing.
► Normally, there is much less risk from
radioactive sources outside the body.
► Sources in nuclear power stations
and laboratories are well shielded,
and the intensity of the radiation
decreases as you move away from
the source.
► Beta and gamma rays are potentially
the most harmful because they can
penetrate to internal organs. Alpha
particles are stopped by the ▲Where background
skin. radiation comes from (average
11.03 – Nuclear Radiation (2) 11 – Exam
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Questions
Background radiation
► There is a small amount of radiation around us all the time
because of radioactive materials in the environment. This is
called background radiation. It mainly comes from natural
sources such as soil, rocks, air, building materials, food and
drink - and even space.
► In some areas, over a half of the
background radiation comes from
radioactive radon gas (radon-222)
seeping out of rocks - especially
some types of granite. In high risk
areas, houses may need extra
underfloor ventilation to stop the gas
collecting or, ideally, a sealed floor
to stop it entering in the first place. Background Radiation
11.03 – Nuclear Radiation (2) 11 – Exam
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Questions
Cloud chamber
► This is useful for studying alpha particles because it makes
their tracks visible. The chamber has cold alcohol vapour in the
air inside it. The alpha
particles make the vapour
condense, so you see a trail
of tiny droplets where each
particle passes through.
► At one time, cloud chambers
were widely used in nuclear
research, but they have since
been replaced by other devices.
11.03 – Nuclear Radiation (2) 11 – Exam
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Questions
Alpha decay
► Radium-226 (atomic number 88) decays by alpha emission.
The loss of the alpha particle leaves the nucleus with 2
protons and 2 neutrons less than before.
► So the mass number drops to 222 and the atomic number to
86. Radon has an atomic number of 86, so radon is the new
element formed:
Radioactive Decay
11.04 – Radioactive Decay (1)
11 – Exam
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Questions
Alpha decay
► The decay process can be
written as a nuclear equation:
Ra → Rn + 2α
► During alpha decay:
the top numbers balance on both sides of the
equation (226 = 222 + 4), so the mass number is
conserved (unchanged)
the bottom numbers balance on both sides of the
equation (88 = 86 + 2), so charge is conserved
a new element is formed, with an atomic number 2
less than before. The mass
number is 4 less than before.
Nuclear Equations
11.04 – Radioactive Decay (1)
11 – Exam
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Questions
Nuclear essentials !
Atoms of any one element all have the same number of
protons in their nucleus.
Elements exist in different versions, called isotopes. For
example, lithium is a mixture of two isotopes: lithium-6 (with
3 protons and 3 neutrons in the nucleus) and lithium-7 (with
3 protons and 4 neutrons).
Any one particular type of atom, for example lithium-7, is
called a nuclide. However the word isotope' is commonly
used instead of nuclide.
Radioactive isotopes have unstable nuclei. In time each
nucleus decays (breaks up) by emitting an alpha or beta
particle and, in some cases, a burst of gamma radiation as
well.
11.04 – Radioactive Decay (1)
11 – Exam
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Questions
Beta decay
► Iodine-131 (atomic number 53) decays by beta emission. When this
happens, a neutron changes into a proton, an electron, and an
uncharged, almost massless relative of the electron called an
antineutrino. The electron and antineutrino leave the nucleus at high
speed. As a proton has replaced a neutron in the nucleus, the atomic
number rises to 54. This means that a nucleus of xenon-131 has
been formed:
11.04 – Radioactive Decay (1)
11 – Exam
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Questions
Beta decay
► The decay process can be written as a nuclear equation:
I → Xe + β + ( = antineutrino)
► During this type of beta decay:
the top numbers balance on both sides of the equation
(131 = 131 + 0 + 0), so the mass number is conserved
the bottom numbers balance on both sides of the
equation (53 = 54 - 1 + 0), so charge is conserved
a new element is formed, with an atomic number 1 more
than before. The mass number is unchanged.
Alternative names !
Atomic number ≡ proton number
Mass number ≡ nucleon number
11.04 – Radioactive Decay (1)
11 – Exam
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Questions
Gamma emission
► With some isotopes, the emission of an alpha
or beta particle from a nucleus leaves the
protons and neutrons in an ‘excited’
arrangement. As the protons and neutrons
rearrange to become more
stable, they lose energy. This
is emitted as a burst of
gamma radiation.
Gamma emission by itself
causes no change in mass
number or atomic number.
11.04 – Radioactive Decay (1)
11 – Exam
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Questions
Related topics: nuclei and isotopes 11.01; alpha, beta, and gamma
radiation 11.02; more on beta decay 11.10
11.05 – Radioactive Decay (2)
11 – Exam
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Questions
Fission
► Natural uranium is a dense radioactive metal consisting mainly
of two isotopes: uranium-238 (over 99%) and uranium-235
(less than 1%).
► The diagram below shows what can happen if a neutron
strikes and penetrates a nucleus of uranium-235. The nucleus
becomes highly
unstable and splits
into two lighter
nuclei, shooting out
two or three
neutrons as it does
so.
11.06 – Nuclear Energy
11 – Exam
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Questions
Fission
► The splitting process is called fission, and the fragments
are thrown apart as energy is released. If the emitted
neutrons go on to split other nuclei... and so on, the result is
a chain reaction, and a huge and rapid release of energy.
► A chain reaction.
A neutron causes
a uranium-235
nucleus to split,
producing more
neutrons, which
cause more
nuclei to split...
and so on.
11.06 – Nuclear Energy
11 – Exam
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Questions
Fission
► For a chain reaction to be maintained, the uranium-235 has
to be above a certain critical mass, otherwise too many
neutrons escape. In the first atomic bombs, an uncontrolled
chain reaction was started by bringing two lumps of pure
uranium-235 together so that the critical mass was
exceeded. In present- day nuclear weapons, plutonium-239
is used for fission.
Nuclear Fission
reaction
11.06 – Nuclear Energy
11 – Exam
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Questions
11.06 – Nuclear Energy
11 – Exam
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Questions
Nuclear waste*
► After a fuel can has been in a reactor for three of four years, it
must be removed and replaced. The amount of uranium-235 in
it has fallen and the fission products are building up. Many of
these products are themselves radioactive, and far too
dangerous to be released into the environment. They include
the following isotopes, none of which occur naturally.
Strontium-90 and iodine-131, which are easily absorbed
by the body. Strontium becomes concentrated in the
bones; iodine in the thyroid gland.
Plutonium-239, which is produced when uranium-238 is
bombarded by neutrons. It is itself
a nuclear fuel and is used in
nuclear weapons. It is also highly
toxic. Breathed in as dust, the
smallest amount can kill.
11.06 – Nuclear Energy
11 – Exam
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Questions
Nuclear waste*
► Spent fuel cans are taken to a reprocessing plant
where unused fuel and plutonium are removed. The
remaining waste, now a liquid, is sealed off and stored
with thick shielding around it.
► Some of the isotopes have
long half-lives, so safe
storage will be needed for
thousands of years. The
problem of finding
acceptable sites for long-
▲The steel flasks on
term storage has still not
been solved. this train contain waste
from a nuclear reactor
11.06 – Nuclear Energy
11 – Exam
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Questions
Fusion in a star
► The Sun is a star. Like most other stars, it gets its
energy from the fusion of hydrogen into helium. Deep
in its core, the heat output and huge gravitational pull
keep the hydrogen hot and compressed enough to
maintain fusion. It has enough hydrogen left to keep
it shining for another 6 billion years.
Hydrogen !
Hydrogen is the most plentiful element in the
Universe. The Sun is 75% hydrogen. There is also lots
of hydrogen on Earth, though most has combined with
oxygen to form water (H20).
11.07 – Fusion Future
11 – Exam
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Questions
Fusion in a star
Fusion in a star
► Formation* Scientists think that the Sun formed about 4500
million years ago in a huge cloud of gas (mainly hydrogen) and
dust called a nebula. There, gravity slowly pulled the material
into blobs. In the centre, one blob grew bigger than all the rest.
Around it, smaller blobs would become planets and moons.
◄ The Great Nebula in
the constellation of
Orion. Stars form in
huge clouds of gas
and dust like this.
The gas is mainly
hydrogen.
Great Nebula
11.07 – Fusion Future
11 – Exam
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Questions
Q
1. Splitting very heavy nuclei to form lighter ones. Joining very light nuclei to
form heavier ones,
a. Which of the above statements describes what happens during
nuclear fusion?
b. What process does the other statement describe?
2. * What advantages will power stations with fusion reactors have over
today's nuclear power stations?
3. * Why have fusion reactors have been so difficult to develop?
4. Nuclear reactions are taking place in the Sun's core, a
a. * What substance does the Sun use as its nuclear fuel?
b. What is the name of the process that supplies the Sun with its energy?
?
c. * What substance is made by this process?
5. * A nebula is a huge cloud of gas and dust in space,
a. Why does material in a nebula collect in blobs?
b. Why, if a blob is large enough, will it eventually start to shine as a star?
Related topics: gravity 2.09; power stations 4.05; energy resources 4.07-
4.08; atoms 11.01; nuclear energy 11.06
11.08 – Using Radioactivity
11 – Exam
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Questions
Nuclear essentials
!
Elements exist in different versions, called isotopes. For
example, lithium is a mixture of two isotopes: lithium-6 (with
3 protons and 3 neutrons in the nucleus of its atoms) and
lithium-7 (with 3 protons and 4 neutrons).
Radioactive isotopes have unstable nuclei. In time each
nucleus decays (breaks up) by emitting an alpha or beta
particle and, in some gases, a burst of gamma radiation as
well. In a radioactive sample, the number of nuclei decaying
per second is called the activity.
Gamma rays are very penetrating, beta particles less so, and
alpha particles least of all. All three types of radiation
damage or destroy living cells if absorbed.
11.08 – Using Radioactivity
11 – Exam
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Questions
Tracers
► Radioisotopes can be detected in very small (and safe)
quantities, so they can be used as tracers - their
movements can be tracked. Examples include:
Checking the function of body organs. For
example, to check thyroid function, a patient drinks a
liquid containing iodine-123, a gamma emitter. Over
the next 24 hours, a detector measures the activity of
the tracer to find out how quickly it becomes
concentrated in the thyroid gland.
Tracking a plants uptake of fertilizer from roots to
leaves by adding a tracer to the soil water.
Detecting leaks in underground pipes by adding a
tracer to the fluid in the pipe.
11.08 – Using Radioactivity
11 – Exam
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Questions
Tracers
► For tests like those above, artificial radioisotopes with short
half-lives are used so that there is no detectable radiation
after a few days.
► In a hospital, a gamma camera like the one in the
photograph above may be used to detect the gamma rays
coming from a radioactive tracer in a patient’s body. The
camera forms an image similar that produced by X-rays.
Carbon dating
► There is carbon in the atmosphere (in carbon dioxide) and
in the bodies of animals and plants. A small proportion is
radioactive carbon-14 (half-life 5730 years). Although
carbon-14 decays, the amount in the atmosphere changes
very little because more is continually being formed as
nitrogen in the upper atmosphere is bombarded by cosmic
radiation
from space.
11.08 – Using Radioactivity
11 – Exam
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Questions
Carbon dating
► While plants and animals are living, feeding, and breathing,
they absorb and give out carbon, so the proportion of carbon-
14 in their bodies stays constant. But when they die, no more
carbon is taken in and the proportion of carbon-14 is gradually
reduced by radioactive decay.
► By measuring the activity of a sample,
the age of the remains can be estimated.
This is called carbon dating. It can be
used to find the age of organic materials
such as wood and cloth.
► However, it assumes that the proportion ▲Using carbon
of carbon-14 in the atmosphere was the dating, scientists have
same hundreds or thousands of years discovered that these
remains of a
ago as it is today.
mammoth are 15 000
11.08 – Using Radioactivity
11 – Exam
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Questions
Dating rocks
► When rocks are formed, some radioisotopes become trapped
in them. For example, potassium-40 is trapped when molten
material cools to form igneous rock. As the potassium-40
decays, more and more of its stable decay product, argon-40,
is created.
► Provided none of this argon gas has escaped, the age of the
rock (which may be hundreds of millions of years) can be
estimated from the proportions of potassium-40 to argon-40.
Igneous rock can also be dated
by the proportion of uranium to
lead isotopes - lead being the
final, stable product of a series
of decays that starts with
uranium. Dating Rocks
11.08 – Using Radioactivity
11 – Exam
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Questions
Nucleus
Rutherford’s nuclear model
► Thin gold foil was bombarded with alpha
particles, which are positively charged.
Most passed straight through the gold
atoms, but a few were repelled so
strongly that they bounced back or were
deflected through large angles. Electrons
► Rutherford concluded that the atom
▲Rutherford's
must be largely empty space, with its model of the atom
positive charge and most of its mass electrons orbit a
concentrated in a tiny nucleus at the central nucleus. (If
the nucleus were
centre.
correctly drawn to
► In his model, the much lighter electrons
scale, it would be too
orbited the nucleus rather like the small to see.)
planets around the Sun. Rutherford's Model
11.09 – Atoms & Particles (1)
11 – Exam
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Questions
an electron
gains energy...
an electron
gains energy...
▲ When the electron drops back to a lower level... ▲ How an atom gives off light
11.10 – Atoms & Particles (2)
11 – Exam
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Questions
Fundamental particles
► A fundamental particle is one which is not made up of
other particles. An atom is not fundamental because it
is made up of electrons, protons, and neutrons. But
are these fundamental?
► To answer this and other questions, scientists carry out
experiments with particle accelerators. They shoot
beams of high-energy particles (such as protons) at
nuclei, or at other beams, and detect the particles
emerging from the collisions.
► In collider experiments, new particles are created as
energy is converted into mass. However, most of these
particles do not exist in the atoms of ordinary matter.
11.10 – Atoms & Particles (2)
11 – Exam
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Questions
Fundamental particles
► One of the giant detectors
surrounding part of the Large
Hadron Collider at CERN near
Geneva. Hadrons are a family of
particles which includes protons
and neutrons. In the collider,
beams of protons are
accelerated by electromagnets
round a circular path 27 km long,
then made to collide head-on.
The Higgs particle !
A major success at CERN, in 2012, was the discovery of the Higgs
particle. Long predicted by the standard model, this fundamental
particle is required to explain why most particles have mass.
11.10 – Atoms & Particles (2)
11 – Exam
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Questions
Fundamental particles
► The present theory of particles is called the standard model.
According to this model, electrons are fundamental particles.
However, neutrons and protons are made up of other
particles called quarks, as shown in the chart on the next
page.
► In ordinary matter, there are two
types of quark, called the up
quark and the down quark for
convenience. Each proton or
neutron is made up of three
quarks. The quarks have
fractional charges compared
with the charge on an electron.
11.10 – Atoms & Particles (2)
11 – Exam
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Questions
Fundamental particles
fundamental particles of Proton Neutron
ordinary matter This is made up of 2 up This is made up of 2 down
electron quarks and 1 down quark quarks and 1 up quark
relative
charge
Up quark
(u)
Down
quark (d)
Total relative charge + 1 Total relative charge 0
[1]
ii. Beta particles are___________.
11 – Further Questions 11 – Exam
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Questions
[3]
b. State where these particles are
11 – Further Questions 11 – Exam
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3. Questions
Proton number 26
Mass number 59
Radiation emitted Beta and Gamma
a. Calculate: ?
i. the number of neutrons in the nucleus;
[1]
ii. the total number of charged particles in a
single atom of iron-59.
[1]
b. Iron-59 and iron-56 are both isotopes of iron.
11 – Further Questions 11 – Exam
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Questions
[1]
b. Phosphorus-32 is a beta-emitter with a half-life of 14 days.
i. What is a beta particle?
[1]
ii. The proton number of phosphorus-32 atom is 15.
11 – Further Questions 11 – Exam
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Questions
[3]
ii. Describe two methods which
could be used to measure the
activity of a leaf. [2]
11 – Further Questions 11 – Exam
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Questions
[2]
c. Eventually the level of radiation from the technetium-99m
11 – Further Questions 11 – Exam
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Questions
?
the graph how you arrived
at your answer. [2]
d. Give a reason why
caesium-137 could cause
longer-term problems than
iodine-131. [2]
11 – Further Questions 11 – Exam
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Questions
[1]
b. Give one non-medical use for a radioactive
tracer.
11 – Further Questions 11 – Exam
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Questions
[1]
11 – Further Questions 11 – Exam
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Questions
Use the list below when you revise for your IGCSE examination. You can either photocopy
it or print it from the file on the CD accompanying this book.
The spread number, in brackets, tells you where to find more information.
Core Level
The particles in an atom and the charges on them.
(11.01)
The meanings of atomic number (proton number) and mass number (nucleon
number).
(11.01)
What isotopes are.
(11.01)
What a nuclide is.
(11.01)
Representing nuclides in symbol form. For example: Li
(11.01)
What radioactive materials are.
11 – Further Questions 11 – Exam
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Questions
How the emission of an alpha or beta particle changes an atom into one of a
different element.
(11.04)
The random nature of radioactive decay.
(11.05)
How the rate of radioactive decay changes with time.
(11.05)
The meaning of half-life.
(11.05)
Working out a half-life from a radioactive decay curve or other data.
(11.05)
Extended Level
As for Core Level, plus the following:
How alpha and beta particles are deflected by electric and magnetic fields.
(11.02)