CHEMISTRY

MDCAT
UNIT-3
MCQ-1
At constant temperature when the pressure of
gas is increased three times then its volume
becomes
2V
A.
3
B. 3V
V
C. 3
D. 5V
MCQ-2
A mono-atomic substance can store energy only
in the form of

A. Translational motion
B. Rotational motion
C. Vibrational motion
D. Rotational and vibrational motion
MCQ-3
Volume of a gas at STP is 10 dm3 at what
temperature its volume will become 30dm3,
keeping pressure constant

A. 3°C
B. 819°C
C. 819K
D. 3K
MCQ-4
A gas initially at 27°C is heated upto 327°C, its
average K.E will be

A. Doubled
B. Four times
C. 300 times
D. 327 times
MCQ-5
Under high pressure which of the following gas
show more ideality in character

A. N2
B. CO2
C. NH3
D. SO2
MCQ-6
In a closed flask of one dm3, 2.0g of hydrogen
gas is heated from 27°C to 327°C. Which of the
following is incorrect

A. The pressure of the gas increases

B. The kinetic energy of gas molecules increases
C. The rate of collision increases
D. The number of moles of the gas increases
MCQ-7
The compressibility factor, Z i.e. the extent to which a real gas
deviates from ideal behaviour is given by (for one mole)

PV
Z=
A. RT 2

RT
Z=
B. PV
PV
Z=
C. RT
PT
Z=
D. RV
MCQ-8
The constant ‘a’ in Van der Waal’s equation is
maximum for

A. Helium
B. Hydrogen
C. Oxygen
D. Ammonia
MCQ-9
All the collisions between the particles of gases
are elastic in nature. What is meant by “Elastic
Collisions”

A. The velocity of the molecules changes

B. No change in mass during the collisions
C. No change in the kinetic energy
D. No change in potential energy during the
Collisions
MCQ-10
The number of molecules in 22.4 dm3 of H2 gas
at 0oC and 1 atm are

A. 60.2 × 1023
B. 6.02 × 1025
C. 6.02 × 1023
D. 60.2 × 1022
MCQ-11
In the equation , ‘b’ represents
the

A. Excluded volume
B. Actual volume
C. Excluded pressure
D. Excluded volume per mole
MCQ-12
Which of the following is the correct equation
to calculate relative molecular mass of a gas

A. M = mPRT/V
B. M = mPR/VT
C. M = PV/mRT
D. M = mRT/PV
MCQ-13
The actual volume of gas molecules is
considered negligible at following pressures.

A. 2 atm
B. 4 atm
C. 6 atm
D. 8 atm
MCQ-14
CHCl3 exist in liquid state due to

A. Dipole-dipole and London dispersion forces

B. Dipole induced dipole forces
C. Dipole–dipole forces
D. Hydrogen bonding
MCQ-15
Propanone is miscible in water due to

A. Both are polar molecules

B. Hydrogen bonding between them
C. Dipole-dipole attraction between them
D. All of these
MCQ-16
Which one of the following arrangements usually
represents the correct order of increasing interactions?

A. Hydrogen bonding, London forces, Dipole – Dipole

B. London force, Hydrogen bonding, Dipole – Dipole
C. London forces, Dipole – Dipole, Hydrogen bonding
D. Dipole – Dipole, London forces, Hydrogen bonding
MCQ-17
Vapour pressure of water is 4.579 torr at 0oC
and 9.209 torr at 10oC, so increase in vapour
pressure from 0oC to 10oC is 4.630 torr. What
will be the change in vapour pressure from 90oC
to 100oC

A. 4.630 torr
B. < 4.630 torr
C. > 4.630 torr
D. V.P remain same at all Temperature
MCQ-18
At 1atm pressure, a liquid 1 has the boiling point
less than a liquid 2, what can we predict about both the
liquids

A. Liquid 1 has high vapour pressure than the liquid 2

B. Liquid 1 has the weak intermolecular forces of
attraction than the liquid 2
C. Liquid 1 is more volatile than the liquid 2
D. All of the above
MCQ-19
The strength of hydrogen bonding is

A. 20 times less than a covalent bond

B. 20 times less than a ionic bond
C. 20 times more than a covalent bond
D. 20 times more than a ionic bond
MCQ-20
The strongest H-bond is

A. F---H
B. O----H
C. N----H
D. O----F
MCQ-21
When water freezes at 0oC its density decreases
due to

A. Change of bond angles

B. Cubic structure of ice
C. Empty space present in the structure of ice
D. Change of bond length
MCQ-22
Correct order of boiling points of the given
liquids is

A. H2O > HF > HCl > NH3

B. H2O > HF > NH3 > HCl
C. HF > H2O > HCl > NH3
D. HF > H2O > NH3 > HCl
MCQ-23
Ice is less dense than water at

A. 0oC
B. 4oC
C. -4oC
D. 2oC
MCQ-24
In crystal lattice of ice, each O-atom of water
molecule is attached to

A. Four H-atoms
B. Two H-atoms
C. One H-atom
D. Three H-atoms
MCQ-25
Which line in the following structure represents
hydrogen bonding?

A. 1
B. 2
C. 3
D. 4
MCQ-26
Metallic conduction involves the relatively free
movement of their-------------throughout the
metallic lattice:

A. Atoms
B. Electrons
C. Ions
D. Molecules
MCQ-27
According to Watson and Crick’s model of DNA,
the DNA molecule consists of a double helix.
What type of forces are responsible to keep two
strands of DNA together?

A. Hydrogen bonding
B. van der Waal’s forces
C. Ionic bonding
D. Dipole-induces dipole forces
MCQ-28
CO2 and SO2 both are tri-atomic molecules but
heat of vaporization of SO2 is greater than that
of CO2 due to

A. High electronegativity of S
B. Greater size of SO2
C. SO2 is polar and CO2 ­is non polar
D. SO2 is more acidic than CO2
MCQ-29
Which of the following is not a molecular solid?

A. Bromine
B. Sulphur
C. Phosphorus
D. Carbon dioxide
MCQ-30
Lattice energy decreases with the increase in
size of ion because oppositely charged ions

A. Have close packing

B. Have low empty spaces
C. Becomes less tight
D. Have strong electrostatic forces
MCQ-31
When an element exist in more than one
crystalline forms, it is known as

A. Anisotropy
B. Isomorphism
C. Allotropy
D. Polymorphism
MCQ-32
Which one has the highest melting point and
boiling point

A. Ionic crystal
B. Molecular crystal
C. Covalent crystal
D. Metallic crystal
MCQ-33
Coinage metals are Cu, Ag & Au and they have
________ crystal system

A. Cubic
B. Hexagonal
C. Tetragonal
D. Trigonal
MCQ-34
In crystal structure of NaCl, the arrangement of
Cl- ions is

A. Face centered cubic

B. Body centered cubic
C. Simple Cubic
D. Hexagonal
MCQ-35
Cubic crystal system has the following unit cell
dimensions

A. a = b = c and α = β = γ = 90°
B. a = b ≠ c and α = β = γ = 90°
C. a ≠ b ≠ c and α = β = γ = 90°
D. a = b ≠ c and α =β = 90°, γ = 120°
MCQ-36
Which is incorrect about structure of iodine

A. Face-centered cubic
B. Metallic appearance
C. I – I (g) > I ­– I (s) Bond length
D. I – I (g) < I ­– I (s) Bond length
MCQ-37
Which of the following is an example of polar
molecular solid

A. Naphthalene
B. Dry ice
C. Iodine
D. Sugar
MCQ-38
In the structure of NaCl, each sodium ion is
surrounded by chloride ions

A. 4
B. 6
C. 5
D. 8
MCQ-39
Which one the following have highest lattice
energy?

A. NaCl
B. KCl
C. KBr
D. LiCl
MCQ-40
The lattice energy is also called as

A. Energy of affinity
B. Bond energy
C. Crystal energy
D. Potential energy
MCQ-41
The number of molecules in 0.0112m3 of
methane at 0oC and pressure of 760mm Hg is

A. 6.02 × 1020
B. 6.02 × 1023
C. 3.01 × 1012
D. 3.01 × 1023
MCQ-42
The root mean square velocity is expressed as
1
3  2

A.  RT 
2 

1
 3RT  2

B. 
 M 


1
 2RT  2

C. 
 M



1
 8RT  2

D. 
 M 

MCQ-43
Absolute zero is unattainable temperature,
current attempts have resulted in the lowest
temperature of

A. 10–1 K
B. 10­–2 K
C. 10–5 K
D. 10–7 K
MCQ-44
Which of the following molecules have
maximum root mean square velocity at 25°C

A. CO2
B. H2S
C. NH3
D. SO2
MCQ-45
The density of methane at 2atm pressure at
27°C is

A. 26 gdm–3
B. 1.3 gdm–3
C. 0.26 gdm–3
D. 0.13 gdm–3
MCQ-46
Which has greater enthalpy of vapourization

A. F2
B. Cl2
C. Br2
D. I2
MCQ-47
Which one is the most accurate method for the
measurement of vapour pressure

A. Barometric method
B. Dilatometric method
C. Manometric method
D. Optical rotation method
MCQ-48
Carbon atom in diamond is

A. sp hybridized
B. sp2 hybridized
C. sp3 hybridized
D. dsp2 hybridized
MCQ-49
The heat of vaporization of H2O, C2H5OH and CS2
are 40.6 kJ/mol, 38.6kJ/mol and 28.6kJ/mol
respectively. The order of decreasing
intermolecular forces in these liquids is

A. H2O > C2H5OH > CS2

B. H2O > CS2 > C2H5OH
C. CS2 > C2H5OH > H2O
D. CS2 > H2O > C2H5OH
MCQ-50
The different substances are given along with
their boiling points in the following table

Select the substance having weakest

intermolecular forces
A. HF
B. C2H5OH
C. NH3
D. C2H5OC2H5