Distilasi

• Dibenzo(a.h)anthracene is a polycyclic aromatic

hydrocarbon (PAH) compound with the structural
formula shown below.

• Estimate its properties based on its structural formula

 deisobuthanizer
• Cairan hidrocabon yang dihasilkan dari NGL
(natural gas liquid) dipisahkan kedalam ,
propane (C3), Isobuthane (CH4), normal
buthane (nC4) dan produk gasoline ( C5+ ).
Tahapan pertama yaitu memisahkan terlebih
dahulu antara isobutane dengan normal
buthane. Seperti gambar dibawah ini
0.001 gasoline (C5+)
 Proses deethanizer
• Aliran gas dari proses demethanizer dialirkan ke
dalam distilator yang bertujuan untuk
menghilangkan kandungan ethane dalam gas. Gas
umpan meiliki komposisi seperti dalam tabel
dengan tekanan 2790 kpa dan temperatur 19.97 C.
Tekanan pada boiler sebesar 2792 kpa, pada
condenser sebesar 2725 kpa dengan presure drop
pada boiler sebesar 35 kpa. Hitung jumlah stage
minimum dan sebenarnya, reflux minimum dan
lokasi optimum umpan, serta diameter distilator,
 SEPERATION STYRENE
• The organic phase (S21) contains around 70 mol% of styrene, 27.5 mol% of ethylbenzene, 2.2
mol% of toluene, and minor amounts of benzene and other components. For modeling of the
liquid–liquid separator use a Three-Phase Separator. The flow of the vapor phase is zero in this
case; therefore, the vapor stream is hidden. As it results from the thermodynamic analysis of this
mixture, its separation to poor components is not very easy. Owing to low relative volatility of
ethylbenzene to styrene and toluene to ethylbenzene, a large number of theoretical stages can be
expected and large reflux ratios are required. For details on the specification of a distillation
column in Aspen HYSYS,. Use a partial condenser in the first distillation column. The number
of theoretical stages can be set to 30, and the theoretical feed stage can be the 13th stage. Set
both the condenser and the reboiler pressure to 5 kPa (pressure drop in the column is not taken
into account).As initial specifications of the column, use the distillation rate that equals the molar
flow of toluene in the feed stream (S21) and the reflux ratio. After convergence of the column
using initial specifications, define new specifications: mole fraction of styrene and toluene in the
bottom product of 0.999 and mole recovery of styrene and ethylbenzene in the bottom product of
0.999. With these specifications, the reflux ratio reaches values of around 17; however, the
distillation rate is only around 1 kmol⋅h−1 so the reflux flow rate is not very high. Separation of
the styrene–ethylbenzene mixture is simulated in two columns. In the first column, 80 mol% of
styrene with the purity of 99.9% is recovered. To achieve these requirements, a column with 60
theoretical stages and a reflux ratio of 7 has to be used. The column pressure is 5 kPa. The
second column with 40 theoretical stages and a reflux ratio of 6.8. provides styrene recovery of
99.5 and purity of 99.9 mol%. Total styrene recoveryis 99.1%, and its purity is 99.9%. If