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Photoelectric Effect
Photoelectric Effect
The zinc plate is given a negative charge (which in turn means the metal and the gold leaf in
the box are negatively charged).
The negatively charged metal repels the negatively charged gold leaf, causing it to rise up. UV
light is then shone onto the zinc plate.
The energy of the light causes electrons to be lost from the zinc plate via the photoelectric
effect.
As the zinc plate, the metal and the gold leaf lose their negative charge, the gold leaf is no
longer repelled and so falls back down.
There are many more experiments that can be done using different metals
and a wide range of frequencies of incident light.
It is also possible to measure the kinetic energies of the photoelectrons
after they have been emitted from the surface of the metal.
The electroscope experiment is simple, but it was revolutionary.
This effect was first observed by German physicist Heinrich Hertz in 1887.
Phillip Lenard one of the students of Hertz carried out an experiment to
investigate on photoelectric effect.
Key observations
Lenard and other scientists at that time made the following key observations. Some surprising
observations were noticed in these experiments.
Photoelectrons were emitted only if the incident radiation was above a certain frequency
(called the threshold frequency f0) for each metal. No matter how intense the incident
radiation (how bright the light) , not a single electron would be emitted if the frequency
was less than the threshold frequency.
The photoelectrons are emitted with a variety of kinetic energies ranging from zero to
some maximum value. This value of maximum kinetic energy increases with the frequency
of the radiation, but is independent of the intensity of the incident radiation.
More photoelectrons are emitted as the intensity of light increases, but only if the
frequency of the light used is above the threshold value i.e. the number of photoelectrons
emitted per second is directly proportional to the intensity of the radiation.
If the incident radiation was above the threshold frequency, emission of photoelectrons
was instantaneous.
But they couldn’t explain these conclusions if EM radiation only acts as a wave...
Wave theory says that for a particular frequency of EM wave, the energy carried
should be proportional to the intensity of the beam.
This means that if an EM wave were shone on to a metal, each free electron on
the surface of the metal would gain a bit of energy from each incoming wave.
Gradually, each electron would gain energy until its energy equalled the work
function and it could leave the metal.
If the EM wave had a lower frequency (i.e. was carrying less energy) it would
take longer for the electrons to gain this energy, but it would happen eventually.
However, electrons are never emitted unless the wave is above a threshold
frequency — so wave theory can’t explain the threshold frequency.
The higher the intensity of the wave, the more energy it should transfer to each
electron — the kinetic energy of the electrons should increase with intensity.
The number of photoelectrons emitted per second should not depend on
intensity.
It takes a certain minimum amount of energy, called the work function, to
eject a single electron from a particular surface.
If the light falling on the surface is very faint, sometime may elapse before
the total energy absorbed by the surface equals the work function.
Hence, for faint illumination, we expect a time delay between when we
switch on the light and when photoelectrons appear.
If the EM radiation were a simple wave, several minutes would be required
for sufficient energy to be deposited to the metal surface to eject an
electron.
Once EM radiation falls on a material, electrons are ejected without delay.
Einstein’s Postulates and the Photoelectric Effect
The idea that light is quantized is now widely understood and accepted. But at the
time of Einstein’s paper, it was a truly revolutionary idea. In his 1905 paper, Einstein
framed three postulates about light quanta and their interaction with matter:
Light of frequency consists of discrete quanta, each of energy. Each photon
travels at the speed of light.
Light quanta are emitted or absorbed on an all-or-nothing basis. A substance can
emit 1 or 2 or 3 quanta, but not 1.5. Similarly, an electron in a metal cannot
absorb half a quantum but only an integer number.
A light quantum, when absorbed by a metal, delivers its entire energy to one
electron.
Note: These three postulates—that light comes in chunks, that the chunks cannot
be divided, and that the energy of one chunk is delivered to one electron— are
crucial for understanding the new ideas that will lead to quantum physics.
Explanation of photoelectric effect from Particle (photon) model
According to the photon model, when EM radiation hits a metal, the metal’s surface is
bombarded by photons.
If one of these photons collides with a free electron, there is a one-to-one interaction
between the photon and the surface electron.
The electron gains energy equal to (as all of the photon’s energy is transferred to the
electron).
This idea could be used to explain the conclusions from the photoelectric effect, meaning
that the photoelectric effect supported the particulate (particle-like) nature of EM radiation.
If the energy gained by an electron (on the surface of the metal) from a photon is greater
than the work function, the electron is emitted.
If the energy is lower, the electron will just shake about a bit, then release the energy as
another photon.
The metal will heat up, but no electrons will be emitted.
So for electrons to be released. The value of is the threshold frequency when as this is the
minimum requirement for electrons to be emitted.
Note: The threshold frequency is the minimum frequency of the incident
electromagnetic radiation that will release an electron from the metal surface and the
threshold wavelength is the longest wavelength of incident radiation that will release an
electron from the metal surface
The energy transferred from EM radiation to an electron is the energy it absorbs from
one photon, .
The kinetic energy it will be carrying when it leaves the metal is minus any energy
losses.
The minimum amount of energy an electron can lose is the work function energy.
These energy losses are the reason the electrons emitted from a metal have a range of
kinetic energies.
The intensity of radiation is the power transferred by the radiation over a given area.
In the photon model, this is the number of photons that hit a given area every second.
Increasing the intensity just means more photons per second on an area — each
photon has the same energy as before.
The kinetic energy of the electrons is independent of the intensity, as they
can only absorb one photon at a time and the energy of each photon has
not changed.
Providing the incident radiation is above the threshold frequency of a
metal, the number of photoelectrons emitted every second (the rate of
emission) is directly proportional to the intensity of the radiation.
This is because each collision liberates an electron, so if more collisions
occur in a given time, more photoelectrons must be released in that time.
Once EM radiation falls on a material, electrons are ejected without delay.
As soon as an individual photon of a sufficiently high frequency transfers its
energy to just one electron, that electron immediately has enough energy
to escape and the electron is ejected.
Einstein’s photoelectric equation
Energy from a photon is used to release a photoelectron and give the
photoelectron kinetic energy.
Conservation of energy means that energy from the photon equals the
threshold energy plus kinetic energy of the photoelectron.
The work function of a material is the minimum energy needed to release a
photoelectron from a material. The work function has the symbol.
Applying the conservation of energy when energy, , is transferred from the photon to a
photoelectron:
Hence
Considering to the general equation for a straight line graph, and rearranging
to match we get .
We can see that the gradient of this graph must equal to Planck constant h and
the y-axis intercept equal to ,where is the work function of the metal.
Different metals
Every metal has a different work function, so the threshold frequency for each
metal is different
In each case a graph of maximum kinetic energy against frequency will have
same gradient but of different intercept.
The explanation for the experimental observations of
photoelectric effect can be summarised as:
Light travels as photons, with a photon's energy proportional to the frequency.
When a photon encounters an electron, it transfers all its energy to the electron
(the photon ceases to exist).
If an electron gains sufficient energy - more than the work function - it can
escape the surface of the metal as a photoelectron.
Brighter illumination means more photons per second, which will mean a
greater number of photoelectrons emitted per second.
If an electron does not gain sufficient energy from an encounter with a photon
to escape the metal surface, it will transfer the energy gained from the photon
to the metal as a whole before it can interact with another photon. Thus, if the
photon energy is too low, no photoelectrons are observed.
Numerical
• The Photoelectric Effect for a Silver Surface
• The work function for a silver surface is. Find the minimum frequency that light
must have to eject electrons from this surface.
• Reasoning
• The minimum frequency is that frequency at which the photon energy equals
the work function of the metal, so the electron is ejected with zero kinetic
energy. Since, the work function expressed in joules is
• The work function for zinc is 4.3 eV. Explain why photoelectric emission is observed when
ultraviolet light of wavelength in the order of 200 nm is shone onto a zinc plate but not when a
60 W filament lamp is used.
• Solution:
• A photon of the ultraviolet light has energy:
• This is greater than the 4.3 eV work function for zinc. This means that each photon will have
sufficient energy to remove an electron from the surface of the zinc and photoemission will
occur.
• The threshold frequency for zinc is given by:
•
• The shortest wavelength (highest frequency) visible light is 400 nm (at the blue end of the
visible spectrum).
• The frequency of the blue end of the visible spectrum is:
• Calculate Ek (max)
•
• Now calculate
• (e)Predict how Figure would be affected if the intensity of light incident on the
surface were increased. [1]
• There will be no change
CAIE Past papers
• (a)With reference to the photoelectric effect, state what is meant by the
threshold frequency.
[2]
• Minimum frequency for electron(s) to be emitted (from surface)
• reference to frequency of electromagnetic radiation/ photon
• or
• frequency causing emission of electron(s) from surface with zero kinetic
energy
• reference to frequency of electromagnetic radiation/ photon
• (b) Electromagnetic radiation of wavelength λ is incident on a metal surface.
Electrons of maximum kinetic energy EMAX are emitted.
• (i) On Fig., sketch the variation with 1/λ of EMAX. [2]
• (i) Without any calculation, suggest why no value is given for EK for radiation of
wavelength 650 nm. [1]
• either wavelength is longer than threshold wavelength
• or frequency is below the threshold frequency
• or photon energy is less than work function
• (ii) Use data from Fig. 7.1 to determine the work function energy of the surface.
[3]
• (c) Radiation of wavelength 240 nm gives rise to a maximum photoelectric
current I. The intensity of the incident radiation is maintained constant and the
wavelength is now reduced.
• State and explain the effect of this change on
• (i) the maximum kinetic energy of the photoelectrons, [2]
• photon energy larger
• so (maximum) kinetic energy is larger
• (ii) the maximum photoelectric current I. [2]
• fewer photons (per unit time)
• so (maximum) current is smaller
• May/June 2011, 9702/41
• 8 (a) (i) Show that the momentum p of a photon of electromagnetic radiation
with wavelength λ is given by
• (ii) Use the expression in (a)(i) to show that a photon in free space that has a
momentum of 9.5 × 10–28Ns is a photon of red light. [1]
• wavelength = (6.63 10–34) / (9.5 10–28) = 700 10–9 m so red
• (b) A beam of red light of intensity 160Wm–2 is incident normally on a plane
mirror, as shown in Fig. 8.1. The momentum of each photon in the beam is 9.5
× 10–28Ns.
• All of the light is reflected by the mirror in the opposite direction to its original
path. The cross-sectional area of the beam is 2.5 × 10–6m2
• (i) Show that the number of photons incident on the mirror per unit time is 1.4
× 1015 s–1. [2]
• (ii) Use the information in (b)(i) to determine the pressure exerted by the light beam on
the mirror. [3]
• (c) The beam of red light in (b) is now replaced with a beam of blue light of the same
intensity.
• Suggest and explain whether the pressure exerted on the mirror by the beam of blue
light is less than, the same as, or greater than the pressure exerted by the beam of red
light.
• photons have greater momentum or fewer photons per unit time
• greater photon momentum but smaller number of photons (per unit time)
• so pressure is the same 9702/41 October/November 2023
• 8 (a) State what is meant by a photon. [2]
• packet / quantum of energy of electromagnetic radiation
• (b) When the surface of a metal plate is illuminated with electromagnetic
radiation, electrons are sometimes emitted from the metal.
• (i) State the name of this phenomenon. [1]
• photoelectric effect
• (ii) It is observed that this phenomenon occurs only when the frequency of the
electromagnetic radiation is greater than a certain minimum value, regardless of
the intensity of the radiation. Explain how this observation provides evidence for
the existence of photons. [3]
• electron needs a minimum energy to escape or electron emitted if energy in
packet is enough
• energy must be absorbed in packets that are related to frequency
• intensity relates to number of packets (not to energy in packet)
• electron absorbs only a single whole packet
• (c)Fig. 8.1 shows the variation of the maximum kinetic energy of the emitted
electrons in (b) with the frequency of the incident radiation.
• State the name of the quantity represented by:
• (i) the gradient of the line in Fig. 8.1 [1]
• Planck constant
• (ii) the y-intercept of the extrapolated line in Fig. 8.1. [1]
• – work function (energy)
• 9702/42 October/November 2023
• (a) A photon has an energy of 3.11 × 10–19 J. Calculate the momentum of the
photon. [2]
• Ns
• (b) A laser beam has a power of 350mW. The light from the laser has a
wavelength of 640nm.
• (i) Determine the number of photons emitted by the laser in a time of1.0s [2]
• ii) The laser beam is incident normally on a surface that absorbs all of the
photons. Show that the force F exerted on the surface by the laser beam is
given by where P is the power of the laser beam and c is the speed of light.[2]
• Use of and to complete the algebra and arrive at the final equation:
• (c) Light of a single wavelength is incident on the surface of different metals.
The work function energy of the metals is given in Table 7.1.
• (i) Explain the term threshold wavelength. [1]
• maximum wavelength (of electromagnetic radiation) that causes electrons to
be emitted (from surface of metal)
• (ii) For the metals in Table 7.1, calculate the value of the largest threshold
wavelength. [2]
• The graph of against should be a straight line, a fact that Millikan's results
confirmed. Einstein's relation was verified.
• Furthermore, the stopping potential for a given frequency of light was
independent of the intensity of the light.
• One of Millikan's graphs is shown in Fig.
He found that whatever the metal all
graphs had the same slope and from
the above equation it is seen to be h/e.
• Knowing e, h can be calculated and the
value obtained agrees with that found
from black body radiation experiments.
• The threshold frequency and the work
function are characteristic for each
metal and may also be deduced from
the graph.
• The values of are in good agreement
with those found from thermionic
emission.