MAJOR PROJECT

END-SEMESTER REVIEW
MANUFACTURING OF ADVANCED
ANTI-CORROSION MATERIALS FOR NAVAL
INDUSTRY
GROUP DETAILS
ROLL PRN
NAME
NUMBER NUMBER

25 PRAJWAL GHADGE 12010609

26 JEETSING GIRASE 12010428

33 VEDANT KALE 12010608

 CONTENT

01 02 03 04
Problem Literature review Corrosion Prevention of
statement corrosion

05 06 07 08
Probable Experimental Results & References
solutions work Conclusion
PROBLEM STATEMENT
The corrosion problem in the naval industry and the lack of
economical and organic solutions to it

01
Persistent corrosion undermines naval infrastructure integrity.

02
Corrosion compromises naval vessels' operational readiness.

03 Inadequate anti-corrosion materials/most of them being expensive

and non-sustainable hinder naval industry efficiency.

04 Addressing corrosion is paramount for prolonging naval equipment lifespan.

 LITERATURE REVIEW
Sr.N Processing
Paper Title Author Raw Material Parameters
o Time

Synthesis and characterization AhmedA.Al-Amiery, FatinA.

of a novel eco-friendly Binti Kassim , AbdulAmir H.
1 Mild steel , Plants Temp- 30-60°c 4 days
corrosion inhibition for mild Kadhum & Abu Bakar
steel in 1M hydrochloric acid Mohamad

Plant Extracts as Green

Corrosion Inhibitors for Alan Miralrio , Araceli
2 Diff type of metals Temp 45°c Pressure 1atm 7 days
Different Metal Surfaces and Espinoza Vázquez
Corrosive Media:

‘Green’ synthesis of metals and

Jagpreet Singh , Tanushree
their oxide nanoparticles:
3 Dutta ,, Ki‑Hyun Kim3, Mohit Bacteria , Yeast , Plants Pressure 1 atm 8 days
applications for environmental
Rawat , Pallabi Samddar
remediation

Use of Saraca ashoka extract as

Akhil Saxena , Dwarika Prasad
4 green corrosion inhibitor for Ms Sarca ashoka Temp- 75°c 2-4 days
Rajesh Haldhar Gurmeet Singh
mild steel in 0.5 M H2SO4
 LITERATURE REVIEW
Sr.No Paper Title Paper abstract

Almeida, Morcillo, and Rosales' study in Materials and Corrosion in 2000

focuses on the atmospheric corrosion of mild steel in marine atmospheres. Their
Almeid
1 research delves into the corrosion behavior of mild steel exposed to marine
a, E. et al.
environments, providing insights into the mechanisms and factors influencing
the degradation of steel structures in marine atmospheres.

Anupama, Ramya, and Joseph's study delves into the inhibitive interaction of
Anupama, Plectranthus amboinicus leaf extract with mild steel in hydrochloric acid through
K.K. et electrochemical measurements and theoretical calculations. Published in
2
al. Measurement in 2017, their research sheds light on the corrosion inhibition
capabilities of Plectranthus amboinicus leaf extract, offering valuable insights into the
protective properties of natural extracts against corrosion in acidic media.
This study by Zhu et al. focuses on the characterization of metal pitting corrosion using
scanning acoustic microscopy (SAM) and binary image processing. Published in
Z Corrosion Science in 2020, the research demonstrates the application of SAM and
3 hu, Y. image analysis techniques to quantify and visualize the pitting corrosion on metal
et al. surfaces, providing valuable insights into the understanding and monitoring of this type
of localized corrosion.
CORROSION IN NAVAL INDUSTRY

01 Electrochemical reactions with seawater trigger corrosion, compromising metal

integrity in naval vessels.

02 Salt-laden air and moisture create conducive environments for corrosion on exposed metal
surfaces.

03 Galvanic corrosion arises from the interaction of dissimilar metals in

the presence of an electrolyte like seawater.

04 Microbial activity in marine environments accelerates corrosion through biofouling and microbial-induced
corrosion (MIC).

.
PREVENTION OF CORROSION

01 Protective coatings like paints and corrosion-

resistant materials shield surfaces from corrosive
elements.

02 Cathodic protection systems, such as

sacrificial anodes, mitigate corrosion by
diverting corrosive currents.

03 Regular maintenance and inspection regimes

identify and address corrosion early, preventing
extensive damage.
 PROBABLE SOLUTIONS

Source: Betel leaves Source: Oak tree Bark Source: Pine tree bark Source: Citrus peels

Integrity
Hydroxychavicol Tannin Lignin Pectin
 PROBABLE SOLUTIONS

Source: Ashoka Source: Tamarind tree

tree Bark Bark

Tannin Quercetin
EXPERIMENTAL WORK

01 Extracting the corrosion inhibitors from the above 6 samples and converting it into
powder form.

02 Applying it over mild steel pieces and engulfing it in water and then removed it and
submerged it in corrosive medium.

03 After 2-3 months of resting underwater, it was removed and underwent

testing and analysis using four main techniques.
• Immersion test
• Characterization techniques
• Weight loss measurements
• Coating Hardness/ adhesion test
 BEFORE EXTRACTION

SETUP

FINAL
DURING EXTRACTION
 The coating process was done by using a brush and it was then dried in
an oven for about 24 hours at a temperature of 25 °C.
The prepared powder was then mixed with epoxy raisin and hardener in
very specific ratio of 1:2 to form a viscous mixture for an easier
application.
The coating specimens are kept in the corrosive medium for 14 days for
further analysis
SAMPLE

INHIBITOR
 Corrosive medium Constituent

Water= 311.52 ml
Sarca ashoka 0.5 M H2SO4
H2SO4 =8.68 ml

Tamarindus indica 3.5 M NaCl Nacl= 3.5 gm Water = 100 ml

Water = 311.52 ml
Piper betle 0.5 M HNO3 HNO3 = 8.68 ml

Water = 100 ml
Quercus nigra 3.5 M HCl HCl = 3.5 gm

Water = 311.52 ml
Pinus pinaster 0.5 M HF HF = 8.68 ml

Water = 100 ml
Citrus Peels 3.5 M Citric Acid Citric Acid = 3.5 gm
01
Tca

Before After
Corrosion Inhibition Corrosion Inhibition

02 a

Before After
Corrosion Inhibition Corrosion Inhibition
03
Mild Steel (Blank)

Before After
Corrosion Inhibition Corrosion Inhibition
RESULTS & CONCLUSION

01 The simplest way of measuring the corrosion rate of a metal is to immerse the sample
in the test medium ( water ) and measure the loss of weight of the material as a
function of time.
02 Four glass beakers of 250 ml capacity were labeled A to D, each containing water solution.

03 After 144 hours, the specimens were taken out and they were again
cleaned and weighed.

04 From the initial and final Thus the loss in this obtained and corrosion rate (CR) is found from the formula
given below.
 CORROSION RATE (CR) = Weight loss x 534 /Density x Area x Time

Density of Mild Steel = 7.65 g/cm3

The Inhibition efficiency (IE) was calculated using = W0 -

W1/W0 x 100

W0 = Weight loss without inhibitor

W1 = Weight loss with inhibitor
 SAMPLES IN WATER: TIME DURATION 1 MONTH

Corrosion rate Inhibition

Sample w1 w2 w1-w2
(mm/yr) efficiency %

Tamarindus indica on
60 59.3 0.7 0.66 1.44
Mild steel

Saraca ashoka on Mild

60 59.5 0.5 0.47 1.69
steel

Piper betle on Mild steel 60 59.2 0.8 0.76 1.21

Quercus nigra on Mild

60 59.5 0.5 0.47 1.66
steel

Pinus pinaster on Mild

60 59.2 0.8 0.76 1.33
steel

Citrus peels on Mild

60 59.0 1 0.95 1.13
steel
 SAMPLES IN CORROSIVE MEDIUM: TIME DURATION 1 MONTH

Corrosion rate Inhibition

Sample w1 w2 w1-w2
(mm/yr) efficiency %

Tamarindus indica on
59.3 57.6 1.7 2.26 2.86
Mild steel

Saraca ashoka on Mild

59.5 58.3 1.2 1.6 3.24
steel

Piper betle on Mild steel 59.2 57.0 2.2 2.93 2.48

Quercusnigra on Mild
59.5 58.4 1.1 1.46 3.12
steel

Pinus pinaster on Mild

59.2 57.8 1.4 1.86 2.62
steel

Citrus peels on Mild steel 59.0 56.4 2.6 3.46 2.28

SAMPLES IN WATER: TIME DURATION 1 MONTH

SAMPLES IN CORROSIVE MEDIUM: TIME DURATION 1 MONTH

EIS GRAPHS OF SAMPLES AFTER DIPPED IN CORROSIVE MEDIUM
 REFERENCES

01 https://www.southampton.ac.uk/engineering/resea 04 https://rasayanjournal.co.in/admin/php/upload/612_pdf
rch/projects/corrosion_control_for_naval_ships.p .pdf
age

Raja, Pandian Bothi, and Mathur Gopalakrishnan Seth

02 https://www.sciencedirect.com/science/article/abs 05 uraman. "Natural products as corrosion inhibitor for m
/pii/S030094402030151X etals in corrosive media—a review." Materials letters
62.1 (2008): 113-116.

03 https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6 06 Tan, Bochuan, et al. "Insight into anti-corrosion natur

337343/ e of Betel leaves water extracts as the novel and eco-f
riendly inhibitors." Journal of Colloid and Interface S
cience 585 (2021): 287-301.
THANK YOU