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Module 5:

Food Matters
Chapter 7 Food Chemistry

© Copyright Star Publishing Pte Ltd


Chapter 7 Food Chemistry

7.1 How are substances extracted and separated


from mixtures?
7.2 What is a chemical reaction and what are its
applications in daily life?
7.3 What are acids and how can they be identified?
7.4 What are the properties of food acids?
7.5 What is neutralisation and what are its
applications in daily life?
7.6 What are the effects of untreated wastewater
on the environment?

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Objectives
Explain that substances can be extracted and
separated through the following techniques:
(i) dissolving (ii) filtration (iii) evaporation
(iv) distillation and (v) paper chromatography
Describe the applications of the various
separation techniques in homes and food
industries
Use a measuring cylinder to measure volume
of liquids / solids

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Separating Mixtures
 A mixture is one that contains two or
more different substances that are
not chemically combined
together.

 The curry gravy is a rich


food we eat usually consists of mixture of spices
mixtures of solids and liquids.

 For example, orange juice is made up


of orange pulps, sugars, water and
many other substances including
Vitamin C.
a home purification system
 The components in it can be for clean drinking water

separated using separation


techniques. © Copyright Star Publishing Pte Ltd
Separating Mixtures
Some separation
techniques are:

(a) Dissolving
(b) Filtration
(c) Evaporation
(d) Distillation
(e) Paper sugar cane juice is extracted
from sugar cane stems
chromatography
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Dissolving
 A mixture of two solids can be separated by using a solvent
which dissolves only one of them.

 For example, a mixture of salt and sand can be separated by


adding water to the mixture. Salt will dissolve in water but sand
will not.

 We can obtain sand by filtration of the mixture and salt from


evaporation of the filtrate.

separating a mixture of salt and sand

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Dissolving of solutes
Dissolving of solutes is commonly used at
home.

Some examples include:


(a) Cooking of soup
(b) Drinks sweetener
(c) Cleaning of the household

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Cooking of soup
Soup stock (flavourings) either in solid or
liquid forms, is dissolved in water to flavour
the soup.

soup stock is added to water to make soup

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Drinks sweetener
Sugar is dissolved in drinks (e.g. coffee
and tea) to make the taste better.

sugar is added to water when making tea

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Cleaning of the household
Detergent is dissolved in water to remove dirt
from clothes, and clean oily dishes and the floor.

detergent is dissolved in water

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Dissolving in the food industries
 (a) Water is added in the
production of soft drinks,
to dissolve the mixture of
sweeteners, colourings and
flavourings.

 Carbon dioxide gas is also


soft drinks contain a
dissolved in the drink to mixture of sweetened
create the “fizzy” effect flavourings and colourings

which improves the taste


of the drink.
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Dissolving in the food industries
(b) In the production of
perfumes, flower
extracts such as
lavender and rose are
dissolved in alcohol to
manufacture perfumes. perfumes are mixtures of
natural plant extracts

(c) Chlorine is dissolved


in our drinking water
and swimming pools to
kill harmful bacteria. bacteria in swimming pools are destroyed when
chlorine is added

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Filtration
 Filtration is used to separate a mixture
of an insoluble solid from a liquid.

 In the diagram on the right, the mixture


is poured into a filter funnel with a
filter paper.

 The filter paper allows the liquid to


pass through it but not the insoluble
filtration experimental set-up
solid particles of the mixture.

 In this case, sand left on the filter paper


is called the residue and the water that
passes through it and collected in the
beaker is called the filtrate.

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Filtration
 At home, filtration is used
in air-conditioners to
filter air that may contain
dust and smoke particles.

 When cooking pasta, the


fastest and easiest way to a strainer is
used to separate the
separate the pasta from the pasta from water
boiling water is to pour the
contents of the pot into a
strainer. This separates
the pasta from the water.
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Filtration
 A cup of tea can be made by using a strainer
to prevent tea leaves from entering the cup.

filtering tea from insoluble


tea leaves

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A simple filtration system

Activity Book Link


Activity 7.2
Water Purification
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Simple filtration system
A simple filtration system can be set up to
purify water.

Impurities are removed by passing the water


through a bed of sand, gravel and pebbles.

The filtered water can then undergo further


stages (e.g. chlorine and UV treatment) to
improve the water quality to be fit for drinking.

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Evaporation
 Evaporation is used to
separate a dissolved solid
from a liquid. The dissolved
solid must not decompose
when heated.

 For example, salt can be water in a salt solution


obtained from salt solution by evaporates, leaving
the salt crystals behind
evaporation.

 Solid salt will be left behind


in the evaporating dish.

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Decomposition of sugar

sugar blackens upon heating

 Sugar cannot be separated from sugar


solution by evaporation because it
decomposes and turns black upon heating.

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Obtaining salt by evaporation

Activity Book Link


Activity 7.3
Making Table Salt

piles of salt in salt pans

Evaporation is used in salt mines. When


temperatures are high, the salt water in the salt
pans are evaporated leaving the salt behind. The
salt is then piled up to dry.

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Condensation
 When the water boils in the kettle, it changes into steam.
When the steam touches a cold surface, e.g. metal pot or
spoon, it cools down and changes into water.

 The change from a gas to a liquid is called condensation.

steam from boiling water condenses on


the lid of the container

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Distillation
 Distillation is used to separate a liquid from a
solution. It can also be used to separate a liquid from
a mixture of liquids having different boiling points.

distillation experimental setup

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Distillation
Pure water can be obtained from
seawater using distillation.

Distillation
can also be used to separate a
mixture of ethanol and water.

Ethanol will be distilled first from the


mixture because of its lower boiling point
78°C) as compared to water (100°C).
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Process of distillation

Activity Book Link


Activity 7.4
Simple Distillation

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Chromatography
 Chromatography is a method of using a solvent to separate a
mixture into its components.

 Food colourings are often used to improve the appearance of our


food and drinks. Food colourings are usually a mixture of
coloured dyes.

 Chromatography can be used to test if the dyes in food


colourings are safe for consumption. Chromatography can also
be used to detect banned drugs in urine samples
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Paper chromatography
(a) A small drop of ink is placed on one end of the
chromatography paper.

(b) When this end of the chromatography paper is soaked in a


solvent, the solvent travels up the paper, carrying with it the dyes
in the ink.

Activity Book Link


Activity 7.5
Investigating the
Components of Food
Dyes

separating ink using chromatography

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Paper chromatography
(c) There are two coloured
spots formed on the chromatogram.
This shows that the ink sample
is a mixture and it contains two
different coloured dyes.

(d) The dyes that are more


soluble will move faster and
different coloured dyes
further up the chromatogram appear on the
whereas the dyes that are less chromatogram after
the ink has dissolved in the
soluble will move slower and solvent
form spots at lower positions.

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Chapter 7 Food Chemistry

7.1 How are substances extracted and separated from


mixtures?
7.2 What is a chemical reaction and what are its
applications in daily life?
7.3 What are acids and how can they be identified?
7.4 What are the properties of food acids?
7.5 What is neutralisation and what are its
applications in daily life?
7.6 What are the effects of untreated wastewater
on the environment?

© Copyright Star Publishing Pte Ltd


Objectives
Describe a chemical reaction as a process that
leads to the formation of new products
Give examples of everyday changes that
involve chemical reactions : (i) decaying of
food (ii) burning (iii) rusting (iv) cooking of
food
Give examples of everyday situations in
slowing down / preventing chemical reactions
(e.g. Preserving food, reducing amount of heat,
fuel and air supply for burning, tin plating
against rusting)
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What is a chemical reaction?
Chemical reactions happen around us and
even inside us.

Digestion of food is an example of a


chemical reaction and is an important
process before we can derive energy from
food.

All chemical reactions lead to new products


being formed.
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Chemical reactions in everyday life

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Ways to slow down chemical reactions

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Ways to slow down chemical reactions

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Ways to slow down chemical reactions

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Ways to slow down chemical reactions

© Copyright Star Publishing Pte Ltd


Chapter 7 Food Chemistry

7.1 How are substances extracted and separated from


mixtures?
7.2 What is a chemical reaction and what are its
applications in daily life?
7.3 What are acids and how can they be identified?
7.4 What are the properties of food acids?
7.5 What is neutralisation and what are its
applications in daily life?
7.6 What are the effects of untreated wastewater
on the environment?

© Copyright Star Publishing Pte Ltd


Objectives
Describe the properties of acids by their
taste and effects on litmus paper and
universal indicator
Describe acidity, neutrality and alkalinity in
terms of the pH scale (whole numbers only)
Measure the pH of various common
household substances and food using
homemade pH indicator, litmus paper,
universal indicator and a pH meter

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Properties of Acids
 Acids are present in everyday
items. Acids can be identified
by the following properties:

(a) Sour taste

Lemons, oranges and


grapefruits contain
an acid called citric acid
which gives them their sour
taste. Vinegar tastes sour
because it contains ethanoic
acid. foods containing acids

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Properties of Acids
(b) Turns blue litmus paper red

When both red and blue litmus papers are placed in an


acidic solution (e.g. lemon juice), the blue litmus paper
turns red, while the red litmus paper remains red.

blue litmus turns red in acid while red


litmus paper remains unchanged

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Properties of Acids
(c) Acids also produce colour change in universal
indicator. The table below shows the colour change
of the universal indicator when tested with some sample
substances which are acidic.

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Colour changes of the universal indicator in
different acid conditions

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The pH Scale
pH is a measure of the strength of an acidic or
alkaline solution.

The pH scale is a range of numbers from 0 to


14 that shows how acidic, alkaline or neutral a
substance is.

Neutral solutions have a pH of 7.

Acidic solutions have pH values of less than 7.


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The pH Scale
 A solutionwith a lower pH is more acidic than one with
a higher pH.

 Alkalis have pH values of more than 7.

 A solution
with a higher pH is more alkaline than one
with a lower pH.

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The pH scale

Activity Book Link


Activity 7.6
Testing for Acids

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Indicators
Indicators can be used to test for the
presence of acids and alkalis.

An indicator will change colour depending


on whether the solution tested is acidic or
alkaline.

There are many types of indicators


commonly used in the laboratory to indicate
the pH of solutions.
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Litmus indicator
 The commonly used litmus indicators
are the red and blue litmus.

 Litmus is a dye obtained from plants


and can be used as a solution or in
paper form.

 Blue litmus turn red in acidic


litmus solution and
solutions, and red litmus turn blue in litmus paper
alkaline solutions.

 In neutral solutions, both the red and


blue litmus will not change colour.

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Natural indicators
Some flowers, vegetables and berries can be
used as natural indicators.

For example, the coloured juice extracted


from the red cabbage turns pink when tested
with acidic substances and green when tested
with alkaline substances.

Other examples include extracts from grape


peels and orchid flowers.

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Natural indicators

orchid flowers are natural indicators


red cabbage juice is a natural indicator as it
changes colour in different pH

berries, grapes and are natural indicators


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Universal indicator
 The universal indicator is a mixture of several
different types of indicators. It can show a variety
of colours depending on how acidic or alkaline a
substance is.

 Each colour corresponds to a pH value. The


universal indicator is used in the form of a solution or
a paper.

 ThepH of the acid of or alkali can be determined by


comparing the colour of the universal indicator
against the colour chart.
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Universal indicator solution
and universal indicator paper

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pH meter
 A pH meter is an instrument used to measure the pH
of a substance accurately.

 A pH meter consists of a pH probe which is connected


to a datalogger.

 A pH probe is placed in a solution to determine its pH


value and the pH value of the solution is recorded on
the datalogger.

 Among the four indicators, the pH meter gives the most


accurate pH reading of a solution.
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pH meter can measure an
accurate pH reading of a solution

© Copyright Star Publishing Pte Ltd


Chapter 7 Food Chemistry

7.1 How are substances extracted and separated from


mixtures?
7.2 What is a chemical reaction and what are its
applications in daily life?
7.3 What are acids and how can they be identified?
7.4 What are the properties of food acids?
7.5 What is neutralisation and what are its
applications in daily life?
7.6 What are the effects of untreated wastewater
on the environment?

© Copyright Star Publishing Pte Ltd


Objectives
Describe the characteristic properties of
food acids on the following items that are
commonly found at home
(i) metals ( e.g. cooking utensils )
(ii) bases ( e.g. antacids )
(iii) carbonates ( e.g. baking soda,
effervescent Vitamin C tablets)

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Reaction of Food Acids with Metal
Utensils
Some common examples of acids found in food
are lemon and orange juice (citric acid), tea
(tannic acid) and soft drinks (carbonic acid).

lemons contain citric acid


soft drinks contain carbonic acid

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Acid reaction with metals
 Acids
react with some metals to produce a salt and
hydrogen gas.

 For example, when some magnesium strips are added


to a test tube of lemon juice, bubbles can be observed
to form on the magnesium strips.

 The bubbles on the magnesium strips are hydrogen gas.

 The presence of hydrogen gas can be tested using a


lighted splint. Hydrogen gas will extinguish a lighted
splint with a “pop” sound.

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Testing for hydrogen gas

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Acid reaction with metals
 Thegeneral word equation to represent the reaction of a metal
with acid is:

acid + metal  salt + hydrogen gas

rusty utensil
 Most cooking utensils are made of metal.

 Over time, these utensils may become rusty. The rust can be
removed by soaking the rusty utensils in vinegar or rubbing them
with lemon slices.

 The acid in the vinegar or lemon will react with the rust to form
a soluble substance that can be easily washed off.
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Reaction of Food Acids with Carbonates
 Acidsreact with carbonates to give off carbon
dioxide gas.

 Some examples of carbonates found in or daily life are


baking powder, egg shells, Vitamin C tablets and sea
shells.

 Forexample, when some egg shells are added to


vinegar, bubbles of gas can be observed to form on
the egg shells.

 The bubbles formed are carbon dioxide gas.


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Testing for carbon dioxide
 Thepresence of carbon dioxide gas can be tested by
bubbling it into limewater.

 Ifcarbon dioxide gas is present, the limewater will turn


chalky.

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Reaction of Food Acids with Carbonates

 Vitamin C tablets consist  Baking powder contains


of an acid and a carbonate. sodium bicarbonate (baking
When the tablet is added to soda) and an acid. During
water, the acid and baking, the baking soda and the
acid present in the baking
carbonate dissolve and react
powder react to produce
to produce carbon dioxide carbon dioxide gas. This gas
gas which results in the helps to raise the cake and
fizzy bubbling effect makes it soft.
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Reaction of Food Acids with Carbonates
The general word equation to represent the
reaction of a carbonate with acid is:

acid + carbonate  salt + carbon dioxide


+ water

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Reaction of Food Acids with Bases
 Acids react with bases to produce a salt and water.

 Basesdissolve in water to form alkalis. For


example, our stomach produces an acid which
helps us in the digestion of food.

 At
times if we eat too much and too fast, the acid
may flow backwards into our oesophagus.

 We may feel a burning sensation. This is called


acid reflux or heartburn.

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Backflow of stomach acid into
oesophagus causes heart burn

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Antacids
 Ifwe do not have regular
meals, the acids produced in
our empty stomach may cause
us to suffer from gastric pains.

 Over time, this may cause


damage to the inner walls of
the stomach. antacids neutralise
stomach acid

 Antacids, which contain a Activity Book Link


Activity 7.7
base, can be used to neutralise Properties of Acids
the excess acid. This process is
called neutralisation.

© Copyright Star Publishing Pte Ltd


Chapter 7 Food Chemistry

7.1 How are substances extracted and separated from


mixtures?
7.2 What is a chemical reaction and what are its
applications in daily life?
7.3 What are acids and how can they be identified?
7.4 What are the properties of food acids?
7.5 What is neutralisation and what are its
applications in daily life?
7.6 What are the effects of untreated wastewater
on the environment?

© Copyright Star Publishing Pte Ltd


Objectives
State that neutralisation takes place when
an acid reacts with a base and the
products are salt and water only
State some applications of neutralisation
(e.g. action of tooth paste, fabric softener
and hair conditioner, controlling of pH in
soil, neutralising industrial wastes)
Relate pH within the mouth to its effect
on dental health

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Neutralisation
 Neutralisation occurs when an acid reacts with a base to
produce a salt and water only.

 The general word equation to represent neutralisation is:

acid + base → salt + water

 For example, mixing sodium hydroxide and hydrochloric


acid produces two new substances, sodium chloride and
water.

 The word equation is:

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Neutralisation
 If sulfuric acid is used, the word equation becomes:

 Sodium chloride and sodium sulfate are salts.

 Neutralisation reactions are important because


there are many useful daily applications for them.

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Useful applications of neutralisation reactions in everyday
life

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Useful applications of neutralisation reactions in everyday
life

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Useful applications of neutralisation reactions in
everyday life

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Useful applications of neutralisation reactions in
everyday life

Activity Book Link


Activity 7.8
Neutralising Chemical
Waste

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Chapter 7 Food Chemistry

7.1 How are substances extracted and separated


from mixtures?
7.2 What is a chemical reaction and what are its
applications in daily life?
7.3 What are acids and how can they be identified?
7.4 What are the properties of food acids?
7.5 What is neutralisation and what are its
applications in daily life?
7.6 What are the effects of untreated wastewater
on the environment?
© Copyright Star Publishing Pte Ltd
Objectives
State some of the effects of phosphate
detergents (e.g. increase growth of algae
and water weeds) and acidic wastewater
on the rivers and seas
Understand the use of microbes in sewage
plants to treat the wastewater before they
are released to the rivers and seas

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Effects of Untreated Sewage on the Environment

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Effects of Untreated Sewage on the Environment

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Effects of Untreated Sewage on the Environment

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Effects of Untreated Sewage on the Environment

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What are microbes and their uses?
 Microbes such as bacteria are nature’s “recyclers”.

 They can break down bodies of dead animals and plants into
simpler substances.

 Bacteria are very useful in the treatment of waste water


because they produce enzymes to break down the waste
substances into smaller and simpler substances.

 The bacteria population is also well regulated as they grow


quickly when there is a lot of “food” for them.

 When the “food” supplies decrease, the bacteria population


will decrease rapidly.

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Microbes and their uses

magnified view of the


bacteria

scientists analysing bacterial colonies


multiplying on “waste materials” as their
source of food

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Sewage treatment
 In sewage treatment plants, microbes such as aerobic bacteria are used to
decompose the waste sewage material.

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