Professional Documents
Culture Documents
Zuhriyyah Ratih Ardyani Seminar Online Jerman
Zuhriyyah Ratih Ardyani Seminar Online Jerman
Zuhriyyah Ratih Ardyani Seminar Online Jerman
15 K
Thermodynamic Laboratory Chemical Engineering Department Institut Teknologi Sepuluh Nopember Surabaya
BACKGROUND
BACKGR OUND
OBJEC TIVE
OBJECTIVE
Correlated the experimental data by NRTL an UNUQUAC models Obtain the equilibria data for liquid-liquid system of eugenol + isopropanol + water at 303.15, 313.15 and 323.15 K
BACKGR OUND
OBJEC TIVE
Hence,
so :
Generat function
RESEARCH METHODOLOGY
MATERIAL & VARIABLE MATERIAL : 1. Eugenol (Indesso Aroma, p.a.) 2. Isopropanol (MERCK, p.a.) 3. Aquabidestilata Temperature Variable: 303,15 K 313,15 K 323,15 K
APPARATUS
GC ANALYSIS
GC ANALYSIS
Sample Analysis Calibration Curve Area Ratio for Quantitative Prepare Method for The System
CORRELATION MODEL
NRTL MODEL
START
Input R , T, xiexp
END
NRTL
UNIQU AC
COMPO SITION
UNIQUAC MODEL
START
Input R , T, xiexp
NRTL
END
UNIQU AC
COMPO SITION
EQUILIBRIUM COMPOSITION
START
Input aij,aji,R,T,ri,qi,zi Trial ia, ib,
END
NRTL
UNIQU AC
COMPO SITION
EXPERIMENT RESULT
Experiment Data
Parameter
PARAMETER RESULT
Experiment Data
Parameter
CORRELATION RESULT
LLE of eugenol(1) + isopropanol(2) + water(3) system at 303.15 K, ( ) experimental tie line, (----) UNIQUAC tie line
LLE of eugenol(1) + isopropanol(2) + water(3) system at 303.15 K, ( ) experimental tie line, (----) NRTL tie line
303.15 K
313.15 K
323.15 K
CORRELATION RESULT
LLE of eugenol(1) + isopropanol(2) + water(3) system at 313.15 K, ( ) experimental tie line, (----) UNIQUAC tie line
LLE of eugenol(1) + isopropanol(2) + water(3) system at 313.15 K, ( ) experimental tie line, (----) NRTL tie line
303.15 K
313.15 K
323.15 K
CORRELATION RESULT
LLE of eugenol(1) + isopropanol(2) + water(3) system at 323.15 K, ( ) experimental tie line, (----) UNIQUAC tie line
LLE of eugenol(1) + isopropanol(2) + water(3) system at 323.15 K, ( ) experimental tie line, (----) NRTL tie line
303.15 K
313.15 K
323.15 K
CONCLUSION
Correlation with UNIQUAC gives slightl better results than the NRTL equation
The equations of NRTL & UNIQUAC fit the experimental data satisfactorily (RMSD is less than 10%) LLE of the eugenol + isopropanol + water system at 303.15, 313.15, & 323.15 K has been measured
CONCL USION
SUGGE STION
SUGGESTION
Use mathematical program such as Matlab or Fortran for improvin accuracy of data correlation
CONCL USION
SUGGE STION
THANK YOU..